纺织学报 ›› 2017, Vol. 38 ›› Issue (12): 106-111.doi: 10.13475/j.fzxb.20161201206

• 染整与化学品 • 上一篇    下一篇

光催化除甲醛苎麻织物的低温复合制备

  

  • 收稿日期:2016-12-09 修回日期:2017-08-28 出版日期:2017-12-15 发布日期:2017-12-18

Low temperature bonding preparation of functionalized ramie fabrics for formaldehyde photocatalytic degradation 

  • Received:2016-12-09 Revised:2017-08-28 Online:2017-12-15 Published:2017-12-18

摘要:

为解决在无黏结剂条件下纳米光催化材料在纺织品上复合牢度低的问题,采用低温复合处理技术,将TiO2纳米颗粒均匀负载于苎麻织物上,并通过扫描电子显微镜、傅里叶红外光谱仪、透气性测试仪、万能拉伸仪和甲醛测试系统等测试方法对织物性能进行表征。结果表明:TiO2纳米颗粒可通过低温复合处理技术均匀固定于苎麻织物上,织物在-10 ℃低温浴配合400 N/cm 的压力下每次浸渍10 min,浸扎处理3 道后除甲醛效果最佳;处理后织物表面羟基量增多,织物保持了原有透气性且断裂强力和断裂伸长未受到处理影响;处理后织物在120 min内实现了87.14%甲醛去除率。

关键词: 甲醛光催化降解, 低温处理, 苎麻织物, 二氧化钛纳米颗粒

Abstract:

In order to solve the problem that nano photocatalytec materials have low bonding strength on textiles under adhesive-free condition, low temperature bonding treatment was adoptted to uniformly load TiO2 nanoparticles (TiO2 NPs) on ramie fabrics. The properties of the treated ramie fabrics were evaluated by a scanning electron microscope, a Fourier transform infrared spectroscope, a porosimeter, a universal tensile test machine and a formaldehyde test system. The results show that TiO2 NPs can be evenly fixed on the ramie fabrics. The sample treated in the bath at - 10°C for 3 cycles (10 min/cycle, 400 N/cm) shows the highest formaldehyde elimination rate. After the treatment, hydroxyl groups on the fabric surface are increased while the air permeability, tensile stress and elongation of the fabrics are maintained. Within 120 min, about 87.14% formaldehyde can be eliminated by the treated fabrics.

Key words: formaldehyde photocatalytic degradation, low temperature treatment, ramie fabric, titania nanoparticle

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