纺织学报 ›› 2019, Vol. 40 ›› Issue (02): 114-118.doi: 10.13475/j.fzxb.20180708905

• 染整与化学品 • 上一篇    下一篇

层层自组装多糖微胶囊的制备及其缓释型纯棉织物修饰应用

刘菲1,2, 李秋瑾1,2,3(), 巩继贤1,2, 李政1,2, 刘秀明1,2,3, 张健飞1,2,4   

  1. 1.天津工业大学 纺织科学工程学院, 天津 300387
    2.天津工业大学 先进纺织复合材料教育部重点实验室,天津 300387
    3.东华大学 生态纺织教育部重点实验室, 上海 201620
    4.山东省生态纺织协同创新中心, 山东 青岛 266071
  • 收稿日期:2018-07-30 修回日期:2018-11-05 出版日期:2019-02-15 发布日期:2019-02-01
  • 通讯作者: 李秋瑾
  • 作者简介:刘菲(1994—),女,硕士生。主要研究方向为复合材料与功能材料。
  • 基金资助:
    国家重点研发计划资助项目(2017YFB0309800);天津市应用基础及前沿技术研究计划资助项目(15JCYBJC18000)

Polysaccharide microcapsules via layer-by-layer assembly for cotton fabric as sustained release vessel

LIU Fei1,2, LI Qiujin1,2,3(), GONG Jixian1,2, LI Zheng1,2, LIU Xiuming1,2,3, ZHANG Jianfei1,2,4   

  1. 1. School of Textile Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China
    2. Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, China
    3. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China
    4. Collaborative Innovation Center for Eco-Textiles of Shangdong Province, Shandong, Qingdao 266071, China
  • Received:2018-07-30 Revised:2018-11-05 Online:2019-02-15 Published:2019-02-01
  • Contact: LI Qiujin

RichHTML

3

PDF (PC)

179

摘要：

为制备生物相容性功能纺织材料,采用层层自组装技术将带有不同电荷的海藻酸钠(Alg)、壳聚糖(Chi)、透明质酸(HA)组装到碳酸钙模板上,利用乙二胺四乙酸(EDTA)去除模板,得到Alg/ Chi/ HA生物多糖微胶囊;利用超景深三维显微镜、扫描电子显微镜、红外光谱、综合热分析仪研究了微胶囊的形貌结构及热稳定性。结果表明:Alg/Chi/HA多糖微胶囊具有很好的中空结构及较强的稳定性;考察了多糖微胶囊吸附释放行为及其随pH值的变化规律,发现Alg/Chi/HA多糖微胶囊具有良好的pH值响应性;进一步将Alg/Chi/HA多糖微胶囊整理至棉纤维上,以制备缓释型功能纺织材料,为功能纺织品开发提供有益的实践经验与技术储备。

关键词: 层层自组装, 多糖微胶囊, 响应性, 缓释, 织物整理

Abstract:

The oppositely charged sodium alginate (Alg), chitosan (Chi), hyaluronic acid (HA) were coated onto the CaCO3 template via layer-by-layer (LBL) self-assembled technique. The template was removed by using ethylenediaminetetraacetic acid (EDTA) to obtain hollow Alg/Chi/HA microcapsules. The purpose is to prepare biosafety functional fabrics.The morphology and thermal stability of microcapsules were studied by optical microscope with a large-depth-of-field, scanning electron microscope, infrared spectroscopy and comprehensive thermal analyzer. The results show that Alg/Chi/HA microcapsules have good hollow structure and strong stability. The pH-stimuli release behavior of microcapsules were investigated. These Alg/Chi/HA microcapsules were finished in the cotton fiber to manufacture the sustained releasing textile. This work is beneficial for the development of functional fabrics.

Key words: layer-by-layer self-assembly, polysaccharide microcapsule, stimuli-responsive, controlled release, fabric modification

中图分类号: 

  • TS195.5

图1

Alg, Chi, HA, Alg/Chi/HA微胶囊的红外光谱"

图2

Alg/Chi/HA微胶囊的热分析曲线"

图3

Alg/Chi/HA微胶囊的SEM和超景深显微照片"

图4

Alg/Chi/HA微胶囊在pH值为5.8和pH值为7.4时对RhB的释放曲线"

图5

Alg/Chi/HA/Chi整理前后棉纤维的SEM照片"

表1

微胶囊整理织物的透湿量测试"

样品
编号		 初始质量
W0/g		 0.5 h后质量
W1/g		 1 h后质量
W2/g		 透湿量/
(g·m-2·d-1)
1 251.80 252.39 253.61 7 612
2 251.56 252.11 253.27 7 237
[1] DECHER G. Fuzzy nanoassemblies: toward layered polymeric multicomposites[J]. Science, 1997,277(5330):1232-1237.
[2] 张维, 李秋瑾, 张健飞. 层层组装微胶囊的制备及其缓释性能[J]. 纺织学报, 2015,36(3):58-62.
ZHANG Wei, LI Qiujin, ZHANG Jianfei. Preparation and controlled release of microcapsules via layer-by-layer assembly[J]. Journal of Textile Research, 2015,36(3):58-62.
[3] 冯建国, 杨关天, 袁小勇, 等. 高效氯氰菊酯微胶囊的制备、表征及释放性能[J]. 高等学校化学学报, 2017,38(11):1974-1981.
FENG Jianguo, YANG Guantian, YUAN Xiaoyong, et al. Preparation, characterization and release properties of β-cypermethrin microcapsules[J]. Chemical Journal of Chinese Universties, 2017,38(11):1974-1981.
[4] 杨辉, 李通, 仝维鋆, 等. 基于碳酸钙模板的特殊形状层层组装微胶囊的制备[J]. 高等学校化学学报, 2018,39(1):172-177.
YANG Hui, LI Tong, TONG Weijun, et al. Fabrication of microcapsules with special shapes by layer-by-layer assembly on CaCO3 microparticles[J]. Chemical Journal of Chinese Universities, 2018,39(1):172-177.
[5] COOK M T, TZORTZIS G, CHARALAMPOPOULOS D, et al. Production and evaluation of dry alginate-chitosan microcapsules as an enteric delivery vehicle for probiotic bacteria[J]. Biomacromolecules, 2011,12(7):2834-2840.
pmid: 21574635
[6] DENG L, LI Q, AL-REHILI S A, et al. Hybrid iron oxide-graphene oxide-polysaccharides microcapsule: a micro-matryoshka for on-demand drug release and antitumor therapy in vivo[J]. ACS Applied Materials & Interfaces, 2016,8(11):6859-6868.
doi: 10.1021/acsami.6b00322 pmid: 26915062
[7] TAHTAT D, MAHLOUS M, BENAMER S, et al. Oral delivery of insulin from alginate/chitosan crosslinked by glutaraldehyde[J]. International Journal of Biological Macromolecules, 2013,58:160-168.
doi: 10.1016/j.ijbiomac.2013.03.064 pmid: 23567292
[8] 王亚, 黄菁菁, 张如全. 艾蒿油-壳聚糖抗菌微胶囊的制备及其应用[J]. 纺织学报, 2018,39(10):99-103.
WANG Ya, HUANG Jingjing, ZHANG Ruquan. Preparation and application of antimicrobial mug wort oil-chitosan microcapsules[J]. Journal of Textile Research, 2018,39(10):99-103.
[9] CAÑIBANO-HERNÁNDEZ A, SAENZ DEL BURGO L, ESPONA-NOGUERA A, et al. Alginate microcapsules incorporating hyaluronic acid recreate closerin vivo environment for mesenchymal stem cells[J]. Molecular Pharmaceutics, 2017,14(7):2390-2399.
doi: 10.1021/acs.molpharmaceut.7b00295 pmid: 28558467
[10] 杨晨辰. 基于透明质酸的刺激响应纳米凝胶的构建及其靶向药物传输治疗方面的应用研究[D]. 南京: 南京大学, 2016: 17-20.
YANG Chenchen. Study on the preparation of stimuli-responsive nanogels based on hyaluronic acid and its application in targeting drug delivery[D]. Nanjing: Nanjing University, 2016: 17-20.
[11] DETEMMERMAN M, DEMEESTER J, DEVOS F, et al. Encapsulation performance of layer-by-layer microcapsules for proteins[J]. Biomacromolecules, 2011,12(4):1283-1289.
doi: 10.1021/bm101559w pmid: 21375235
[1] 隋智慧, 伞景龙, 王旭, 常江, 吴学栋, 祖彬. 纳米ZnO / 有机氟硅改性聚丙烯酸酯乳液的合成及应用[J]. 纺织学报, 2020, 41(04): 84-90.
[2] 李思捷, 张彩丹. 聚天冬氨酸基纤维水凝胶的制备及其释药性能[J]. 纺织学报, 2020, 41(02): 20-25.
[3] 王访鹤, 王锐, 魏丽菲, 王照颖, 张安莹, 王德义. 层层自组装阻燃改性聚酯织物的制备及其性能[J]. 纺织学报, 2019, 40(11): 106-112.
[4] 范静静, 王鸿博, 傅佳佳, 王文聪. 层层自组装的碳纳米管复合导电棉织物制备[J]. 纺织学报, 2019, 40(04): 90-95.
[5] 付译鋆 安琪 张伟 张瑜 柯惠珍. 壳聚糖基纳米纤维载药体系及其缓释行为[J]. 纺织学报, 2018, 39(12): 7-12.
[6] 李孟轩 王瑞 刘星 杨华 丁艳然. 老颧草微胶囊复合织物的制备及其药物释放机制[J]. 纺织学报, 2018, 39(02): 138-143.
[7] 陈威 关晋平 陈国强 匡小慧. 静电层层自组装法整理多巴胺改性涤/棉混纺织物的阻燃性能[J]. 纺织学报, 2017, 38(09): 94-100.
[8] 任元林 张悦 曾倩 谷叶童. 织物阻燃涂层新工艺的研究进展[J]. 纺织学报, 2017, 38(09): 168-173.
[9] 李兰倩 卢明 刘一萍 谭炼 赵振云 刘祖兰 . 聚苯胺/蚕丝复合织物的制备及其pH值响应性[J]. 纺织学报, 2016, 37(4): 91-95.
[10] 隋智慧 杨康乐 陈杰 赵欣. 含氟聚丙烯酸酯乳液整理剂的性能及其应用[J]. 纺织学报, 2016, 37(09): 100-105.
[11] 张维 李秋瑾 张健飞. 层层组装微胶囊的制备及其缓释性能[J]. 纺织学报, 2015, 36(03): 58-62.
[12] 蔡京昊 王鸿博 万玉芹 傅佳佳 强静. 夹心式单宁/醋酸复合纳米材料的制备及缓释性能评价[J]. 纺织学报, 2014, 35(4): 16-0.
[13] 刘苏 夏风林 张琦 蒋高明. 经编电子送经的模糊PID控制设计[J]. 纺织学报, 2013, 34(8): 127-0.
[14] 许云辉 王晓明 张晓丽. 大豆蛋白/复合羧酸改性棉织物的制备及其缓释效果[J]. 纺织学报, 2013, 34(6): 73-78.
[15] 蒋岩岩 秦静雯 钱伟伟 傅佳佳 王鸿博. 载药聚乳酸/丝素纳米纤维的制备及缓释性能[J]. 纺织学报, 2012, 33(11): 15-19.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发