纺织学报 ›› 2020, Vol. 41 ›› Issue (07): 47-52.doi: 10.13475/j.fzxb.20191005706

• 纺织工程 • 上一篇    下一篇

丝织品的热老化及其寿命预测

郭郎1,2, 王丽琴1,2(), 赵星1,2   

  1. 1.西北大学 文化遗产学院, 陕西 西安 710069
    2.西北大学 文化遗产研究与保护技术教育部重点实验室, 陕西 西安 710069
  • 收稿日期:2019-10-28 修回日期:2020-04-13 出版日期:2020-07-15 发布日期:2020-07-23
  • 通讯作者: 王丽琴
  • 作者简介:郭郎(1997—),男,硕士。主要研究方向为古代纺织品文物保护、文物保护材料研发。
  • 基金资助:
    国家自然科学基金项目(21175104);陕西省重点研发计划资助项目(2019ZDLSF07-05)

Thermal aging and life prediction of silk fabrics

GUO Lang1,2, WANG Liqin1,2(), ZHAO Xing1,2   

  1. 1. School of Cultural Heritage, Northwest University, Xi'an, Shaanxi 710069, China
    2. Key Laboratory of Cultural Heritage Research and Protection Technology, Ministry of Education, Northwest University, Xi'an, Shaanxi 710069, China
  • Received:2019-10-28 Revised:2020-04-13 Online:2020-07-15 Published:2020-07-23
  • Contact: WANG Liqin

摘要:

为探究湿、热环境对丝织品文物保存状况的影响,在110、130 ℃条件下分别对桑蚕丝试样进行干热老化和湿热老化模拟实验。借助万能材料试验机、色度计、扫描电子显微镜和傅里叶红外光谱仪对老化前后试样的抗拉强度、颜色、微观形貌和结构进行了分析。同时,提出了丝织品的寿命预测方程。结果表明:试样强度随老化时间呈线性下降,颜色变黄;干热老化和湿热老化后,纤维表面出现不同程度的破坏,且湿热老化后,纤维束交织形成的孔洞周围较其他部位溶蚀显著;纤维二级结构中β-折叠构象含量显著降低,与强度变化趋势一致;低温、干燥条件适于丝织品文物的保存。

关键词: 丝织品, 干热老化, 湿热老化, 寿命预测, 文物保存

Abstract:

In order to investigate the influence of wet and thermal environments on the preservation of silk cultural relics, silk (Bombyx mori) samples were aged by dry heat and damp heat at 110 ℃ and 130 ℃, respectively. Material testing machine, colorimeter, scanning electron microscope and Fourier transform infrared spectrometer were used to measure and analyze the tensile strength, color, micro-morphology and structure of simulated silk samples before and after aging. The life prediction equation of silk fabrics was proposed. The results show that the tensile strength of the samples decrease linearly with the aging time, while the color turned yellow. After dry heat and damp heat aging, the fiber surfaces show different degrees of damage, and in the latter condition pores formed by fiber bundle interlacing are more significantly corroded than other parts. The content of β-sheet in the secondary structure is significantly reduced, consistent with the trend of strength change. The work reveals that the low temperature and dry condition are suitable for the preservation of silk cultural relics.

Key words: silk fabric, dry heat aging, damp heat aging, life prediction, preservation of cultural relics

中图分类号: 

  • TS146

图1

蚕丝试样在不同老化时间的抗拉强度保留率"

图2

110 ℃干热老化条件蚕丝试样的色度变化值"

图3

蚕丝试样老化前后的SEM照片"

图4

原始试样酰胺Ⅲ带1 350~1 205 cm-1区域Gaussian拟合结果"

表1

4个子峰与二级结构的对应关系"

子峰 波数范围/cm-1 二级结构
a 1 350~1 327 α-螺旋
b 1 327~1 282 α-螺旋
c 1 282~1 245 无规卷曲
d 1 245~1 205 β-折叠

图5

不同老化条件试样二级结构相对含量的变化"

表2

不同老化条件下丝织品的寿命"

实验组 老化条件 寿命/d
1 110 ℃干热老化 58.61
2 110 ℃湿热老化 27.86
3 130 ℃干热老化 7.61
4 130 ℃湿热老化 5.56

图6

丝织品的寿命随温度的变化曲线"

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