纺织学报 ›› 2021, Vol. 42 ›› Issue (01): 84-89.doi: 10.13475/j.fzxb.20200403306

• 染整与化学品 • 上一篇    下一篇

生物基锦纶56用抗静电纺丝油剂的复配及其对短纤维可纺性的影响

王迎1, 王怡婷1, 吴佳庆1, 郭亚飞2, 郝新敏2()   

  1. 1.大连工业大学 纺织与材料工程学院, 辽宁 大连 116034
    2.军事科学院系统工程研究院 军需工程技术研究所, 北京 100082
  • 收稿日期:2020-04-14 修回日期:2020-09-27 出版日期:2021-01-15 发布日期:2021-01-21
  • 通讯作者: 郝新敏
  • 作者简介:王迎(1976—),女,教授,博士。主要研究方向为纺纱技术。
  • 基金资助:
    国家自然科学基金项目(U1808211);辽宁省重大科技专项资助项目(2019JH1/10100010)

Preparation of compound antistatic spinning oil for bio-based polyamide 56 and its effect on staple fiber spinnability

WANG Ying1, WANG Yiting1, WU Jiaqing1, GUO Yafei2, HAO Xinmin2()   

  1. 1. School of Textile and Material Engineering, Dalian Polytechnic University, Dalian, Liaoning 116034, China
    2. Institute of Quartermaster Engineering & Technology, Institute of System Engineering, Academy of Military Sciences, Beijing 100082, China
  • Received:2020-04-14 Revised:2020-09-27 Online:2021-01-15 Published:2021-01-21
  • Contact: HAO Xinmin

RichHTML

5

PDF (PC)

125

摘要：

针对生物基锦纶56(PA56)短纤维质量比电阻大,静电严重,可纺性差的问题,采用市售油剂和抗静电剂复配技术开发了抗静电性、集束性、可纺性较好的生物基PA56纺丝油剂。研究了抗静电剂质量浓度对复配油剂电导率、pH值的影响,考察了经复配油剂处理后PA56纤维的表面形貌、摩擦因数、质量比电阻及梳理机成网加工性能。结果表明:复配油剂在纤维表面形成一层光滑、均匀的油膜;复配纺丝油剂中抗静电剂质量浓度在2 g/L、市售油剂质量浓度在12 g/L为宜,经处理的PA56纤维在相对湿度为35%,室温下可顺利梳理成网,且纤维网均匀、无破洞、云斑;该油剂复配方案提升了锦纶的集束性、抗静电性、可纺性,节能环保,对纺纱车间温湿度要求低。

关键词: 生物基锦纶, 抗静电性, 纺丝油剂, 复配油剂, 可纺性

Abstract:

Aiming at the problems of high mass specific resistance, serious static electricity and poor spinnability of bio-based polyamide 56 (PA56) staple fibers, a spinning oil was developed using the compound technology of commercial oil and antistatic agent. The influence of antistatic agent concentration on the conductivity and pH value of the compound oil was studied. The surface morphology, friction coefficient, mass specific resistance and carding performance of the bio-based PA56 staple fibers were investigated. The results showed that a smooth and uniform oil film was formed on the fiber surface after the compound oil treatment. The optimum concentration of antistatic agent and spinning oil were 2 g/L and 12 g/L respectively. Under this condition, a fiber-web from the PA56 staples was formed at the relative humidity of 35% and room temperature, which was uniform without holes and cloud spots. This compound spinning oil improves the bunching, antistatic and spinnability of PA56 staple fibers. It is a green and energy-saving method, requiring only for ambient temperature and humidity of spinning workshop.

Key words: bio-based polyamide fiber, antistatic performance, spinning oil, compound oil, spinnability

中图分类号: 

  • TS154

表1

抗静电剂与油剂的复配方案"

试样编号 抗静电剂质量浓度/
(g·L-1)		 市售油剂质量浓度/
(g·L-1)
N0 0.00 0
Y0 0.00 12
E1 0.05 12
E2 0.10 12
E3 0.20 12
E4 0.60 12
E5 1.00 12
E6 2.00 12
E7 4.00 12
E8 6.00 12
E9 8.00 12
E10 10.00 12

图1

复配纺丝油剂的电导率"

图2

复配纺丝油剂的pH值"

表2

油剂特性、纤维摩擦因数与可纺性的关系"

类别 效果 油剂特性 摩擦因数要求
成网性 均匀 平滑性、抱合性 μs大,μd小
棉条蓬松 小 抱合性、抗静电性 μs大
堵喇叭口 不堵 平滑性、抗静电性 μs大,μd小
牵伸斑 少 平滑性 μs大,μd小
棉条断落 少 抱合性、平滑性 μs大,μd小
成纱强力 高 抱合性 μs大

表3

PA56短纤维的静摩擦因数"

试样编号 静摩擦因数 试样编号 静摩擦因数
Y0 0.432 0 E6 0.466 9
E1 0.433 4 E7 0.491 9
E2 0.426 9 E8 0.558 0
E3 0.445 7 E9 0.564 2
E4 0.439 3 E10 0.504 6
E5 0.437 2

图3

PA56短纤维的质量比电阻"

图4

PA56短纤维SEM照片(×2 000)"

图5

PA56短纤维的EDS图谱"

图6

PA56短纤维梳理效果"

[1] 邓洁, 高震, 高华, 等. 生物酶法合成1,5戊二胺的研究进展[J]. 广西科学, 2017,24(1):40-47.
DENG Jie, GAO Zhen, GAO Hua, et al. Research progress of the bio-synjournal of l,5 diamin-opentane[J]. Guangxi Sciences, 2017,24(1):40-47.
[2] 马雪松, 徐晓晨, 陈英. 生物基化学纤维PA56的性能与应用[J]. 纺织导报, 2019 (8):43-46.
MA Xuesong, XU Xiaochen, CHEN Ying. Performance and application of bio-based PA56 Fiber[J]. China Textile Leader, 2019 (8):43-46.
[3] 董奎勇, 杨婷婷, 王学利, 等. 生物基聚酯与聚酰胺纤维的研发进展[J]. 纺织学报, 2020,41(1):174-182.
DONG Kuiyong, YANG Tingting, WANG Xueli, et al. Research and development progress of bio-based polyester and polyamide fibers[J]. Journal of Textile Research, 2020,41(1):174-182.
[4] LAURA Morales Gámez, DAVID Soto, LOURDES Franco, et al. Brill transition and melt crystallization of nylon 56: an odd-even polyamide with two hydrogen-bonding directions[J]. Polymer, 2010(51):5788-5798.
[5] 郝新敏, 李岳玲, 王建明, 等. 锦纶纤维酸性染料染色动力学对比研究[J]. 纺织学报, 2015,36(2):77-80.
HAO Xinmin, LI Yueling, WANG Jianming, et al. Study on acid dyestuff dyeing kinetics of polyamide 56 fiber compared with polyamide 6 and 66[J]. Journal of Textile Research, 2015,36(2):77-80.
[6] WANG Yu, KANG Hongliang, WANG Rui, et al. Crystallization of polyamide 56/polyamide 66 blends: non-isothermal crystallization kinetics[J]. Journal of Applied Polymer Science, 2018,46409:1-13.
[7] GUO Yafei, HAO Xinmin, LI Yueling, et al. Evaluate on the alkaline resistance properties of bio-based nylon 56 fiber compared with the normal nylon fibers[J]. Advanced Materials Research, 2014,1048:31-35.
[8] WANG Yu, KANG Hongliang, GUO Yafei, et al. The structures and properties of bio-based polyamide 56 fibers prepared by high-speed spinning[J]. Journal of Applied Polymer Science, 2020,49344:1-13.
[9] 孙禹, 戴桦根. 浅谈锦纶FDY油剂[J]. 化纤与纺织技术, 2009(1):42-45.
SUN Yu, DAI Huagen. Nylon FDY oil[J]. Chemical Fiber & Textile Technology, 2009(1):42-45.
[10] 郑帼, 刘燕军, 徐进云, 等. 涤纶短纤油剂及其摩擦性能[J]. 纺织学报, 2005,26(3):85-88.
ZHENG Guo, LIU Yanjun, XU Jinyun, et al. Polyester staple finishes and its fractional property[J]. Journal of Textile Research, 2005,26(3):85-88.
[1] 李亮, 刘静芳, 胡泽栋, 耿长军, 刘让同. 涤纶织物的氧化石墨烯负载及其抗静电性能[J]. 纺织学报, 2020, 41(09): 102-107.
[2] 苗苗, 王晓旭, 王迎, 吕丽华, 魏春艳. 氧化石墨烯接枝聚丙烯非织造布的制备及其抗静电性[J]. 纺织学报, 2019, 40(11): 125-130.
[3] 凡力华, 宋伟华, 王潮霞. 紫外光还原氧化石墨烯腈纶织物抗静电性能[J]. 纺织学报, 2019, 40(05): 97-101.
[4] 张安莹, 王照颖, 王锐, 董振峰, 魏丽菲, 王德义. 阻燃聚左旋乳酸及其纤维的制备与结构性能[J]. 纺织学报, 2019, 40(04): 7-14.
[5] 黄廷健 牟浩 阳知乾 任红檠 徐建军 刘鹏清. 高强高模聚甲醛纤维的制备及其性能[J]. 纺织学报, 2018, 39(10): 1-6.
[6] 刘婷 张安莹 王锐 董振峰 朱志国 王照颖. 季戊四醇磷酸酯/二乙基次磷酸锌协同阻燃聚酰胺6的制备及其性能 [J]. 纺织学报, 2018, 39(09): 8-14.
[7] 马娟 金剑 金欣 肖长发. 亲水抗静电共混聚酯母粒的制备及其性能[J]. 纺织学报, 2017, 38(07): 6-10.
[8] 刘鹏雷 姜鹏飞 刘燕军 郑帼. 纺丝油剂中脂肪酸酯类平滑剂的抗氧化及热稳定性[J]. 纺织学报, 2017, 38(04): 68-72.
[9] 朱斐超 韩建 于斌 余洁 欧璐. 熔喷非织造用聚(3-羟基丁酸-co-3-羟基戊酸共聚酯)/聚乳酸双组分生物降解材料的可纺性能[J]. 纺织学报, 2016, 37(2): 21-26.
[10] 刘婵 谢春萍 刘新金 曲华洋 徐伯俊. 黑牦牛绒氧化脱色工艺优化及其可纺性[J]. 纺织学报, 2016, 37(07): 49-54.
[11] 苟捷 刘建立 高卫东. 应用主成分分析的原棉可纺性指数构建[J]. 纺织学报, 2015, 36(08): 16-21.
[12] 郝新敏 郭亚飞. 生物基锦纶环保加工技术及其应用[J]. 纺织学报, 2015, 36(04): 160-164.
[13] 郝新敏 李岳玲 王建明 郭亚飞 杨元. 锦纶纤维酸性染料染色动力学对比研究[J]. 纺织学报, 2015, 36(02): 77-80.
[14] 朱斐超 于斌 韩建 丁新波. 纺粘非织造用聚乳酸/聚（3-羟基丁酸-co-3-羟基戊酸共聚酯）的可纺性[J]. 纺织学报, 2014, 35(9): 19-0.
[15] 徐红 曹吉强 叶伟 谢占林. 锯齿式皮棉清理对机采棉性能的影响[J]. 纺织学报, 2014, 35(1): 35-0.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发