纺织学报 ›› 2007, Vol. 28 ›› Issue (11): 13-16.

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戊二醛交联胶原蛋白/PVA 复合纤维的结构与性能

王雪娟;唐屹;吴炜誉;徐建军;叶光斗   

  1. 四川大学高分子材料工程国家重点实验室
  • 收稿日期:2007-01-24 修回日期:2007-04-18 出版日期:2007-11-15 发布日期:2007-11-15

Research on collagenPPVA composite f ibers with glutaraldehyde as cross2linker

WANG Xuejuan;TANG Yi;WU Weiyu;XU Jianjun;YE Guangdou   

  • Received:2007-01-24 Revised:2007-04-18 Online:2007-11-15 Published:2007-11-15

摘要: 在胶原蛋白与PVA 复合后的溶液中加入戊二醛交联剂,得到稳定的复合纺丝原液,再用湿法纺丝得到初生纤维,经热拉伸和热定型、缩醛化处理得到胶原蛋白PPVA 复合纤维。复合纤维的强度、模量、伸长率分别达到3. 74 cNPdtex、44. 60 cNPdtex、31. 30 %;结晶度为60. 79 %;水中软化点和回潮率分别为105 ℃和8. 9 %。通过扫描电镜观察发现:复合纤维内部有少许孔洞、裂纹,且随纺丝原液中固含量的增加而减少。

Abstract: Spinning solution was prepared with collagen and PVA blending by addition of glutaraldehyde as
cross2linker. CollagenPPVA composite as2formed fiber could be produced via wet spinning. After heat drawing ,
heat setting , and acetalization , the collagenPPVA composite fiber was obtained. The composite fiber had
strength 3. 74 cNPdtex , modulus 44. 60 cNPdtex , elongation 31. 30 % and crystallinity 60. 79 %. The value of
stick point in water was 105 ℃, and the moisture regain was 8. 9 %. According to SEM photographs , cross2
section of the composite fiber had a few of holes and cracks , these defects diminished with increasing the sold
content of the spinning solution.

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