纺织学报 ›› 2009, Vol. 30 ›› Issue (01): 91-96.

• 染整与化学品 • 上一篇    下一篇

热敏变色整理剂的研制

吴赞敏;吕小卓;冯文昭   

  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2009-01-15 发布日期:2009-01-15

Preparation of thermochromic finishing agent

WU Zanmin;LV Xiaozhuo; FENG Wenzhao   

  • Received:1900-01-01 Revised:1900-01-01 Online:2009-01-15 Published:2009-01-15

摘要: 为了提高热敏变色材料的稳定性和变色可逆性,以蜜胺树脂为壳材,结晶紫内酯–硬脂酸–十四醇有机复配物为芯材,加入乳化剂乳化,黄原胶水溶液为保护胶体,将热敏变色材料制备成微胶囊。制备工艺为:乳化剂质量分数为2%、超声波乳化时间为30min、芯壳质量比为2:1、搅拌转速为720r/min、反应温度为70℃。制备的微胶囊变色温度为46℃,变色时间25 s;复色温度为40℃,复色时间为49 s,可在紫色和浅黄色之间发生可逆变化。

Abstract: In order to enhance the stability and reversibility of thermochomic materials,using melamine resin as the wall materials, and the crystal violet lactone-stearic acid and tetradecanol as the core, and adding emulsifying agent and xanthan gum aqueous solution as the protective colloid, organic thermal materials are prepared and microencapsulted. Preparation technics:the mass of emulsifier is 2%, super ultrasonic emulsified time is 30min, the ratio of core and shell is 2:1, the rate of stirring is 720r/min and the temperature of reaction is 70℃. The temperature of color changing of the microcapsule is 46℃, while the time of color changing is 25s, and the temperature and the time of color fading are 40℃ and 49s, and its color change reversibly can be effected between purple and light yellow.

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