纺织学报 ›› 2008, Vol. 29 ›› Issue (7): 6-8.

• 纤维材料 • 上一篇    下一篇

硼酸改性丝胶聚乙烯醇膜的性能

王群;齐鲁   

  1. 天津工业大学生物与纺织材料研究所 天津300160
  • 收稿日期:2007-07-18 修回日期:2008-01-31 出版日期:2008-07-15 发布日期:2008-07-15

Properties of sericin /PVA membrane modified by boric acid

WANG Qun;QI Lu

  

  1. Institute of Biologic and Spinning Materials;Tianjin Polytechnic University;Tianjin 300160;China
  • Received:2007-07-18 Revised:2008-01-31 Online:2008-07-15 Published:2008-07-15

摘要: 将硼酸加入丝胶/聚乙烯醇的共混水溶液中,通过平板膜法制备薄膜材料。研究硼酸对丝胶/聚乙烯醇膜材料的力学性能和耐溶失性能的影响,利用红外光谱分析和差示扫描量热分析研究硼酸对材料的改性机制和热稳定性。结果发现:硼酸的加入提高了材料的抗张强度和耐溶失性,硼酸对丝胶蛋白在膜材料中有明显的固定作用,明显改善了材料的热稳定性;当丝胶与聚乙烯醇物质的量比为3∶7,硼酸用量为丝胶与聚乙烯醇总质量的0.4%时,所制备膜的综合性能相对较好。

Abstract: Add aqueous boric acid to the aqueous blended solution of sericin and PVA,and sericin /PVA membrane was prepared by level glass plate process.The effect of boric acid on the mechanical property and insolubility property of the sericin / PVA membrane was researched.Preliminary study of the modification mechanism thermal stability of the membrane was performed by using fourier transform infrared spectrophotometry-attenuated total reflectance(FTIR-ATR) and differential scanning calorimetry(DSC).The results indicated that boric acid improves the tensile strength and insolubility property of the membrane,has positive effect on the fixing sericin protein to the membrane,and enhances its thermal stability remarkably.When the mass ratio of sericin and PVA is 3∶7 and the amount of boric acid is 0.4% of the total mass of sericin and PVA,the prepared sericin /PVA membrane has better properties.

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