PET基底上碳氟膜纳米结构及均匀性研究

纺织学报 ›› 2007, Vol. 28 ›› Issue (12): 48-50.

PET基底上碳氟膜纳米结构及均匀性研究

王东¹;矫丽珍¹;昃向君¹;路建军²;齐宏进³

1.山东检验检疫技术中心山东青岛266000;2.航空特种材料及工艺技术研究所北京100010;3.五邑大学广东江门529020

收稿日期:2006-12-05 修回日期:2007-05-31 出版日期:2007-12-15 发布日期:2007-12-15

Study of nanostructure and uniformity of fluorocarbon films prepared on PET substrates

WANG Dong;JIAO Lizhen;ZE Xiangjun;LU Jianjun;QI Hongjin

1.Shandong Inspection & Quarantine Technology Centre;Qingdao;Shandong 266000;China;2.Research Institute of Aerospace Special Material & Technology;Beijing 100010;China;3.Wuyi University;Jiangmen;Guangdong 529020;China

Received:2006-12-05 Revised:2007-05-31 Online:2007-12-15 Published:2007-12-15

摘要/Abstract

摘要： 研究开发防水透湿聚酯(PET)织物,利用磁控溅射法在PET薄膜及织物上制备碳氟高分子膜,利用扫描电子显微镜(SEM)、X射线衍射(XRD)、光电子能谱(XPS)对PET基底上碳氟膜的纳米结构及均匀性进行研究。SEM研究表明,一定条件下制备的碳氟膜表现出一定的有序性,呈现一定的微观结构均匀性,具有网络和棒状纳米自组装的特征;在一定条件下得到了开发防水透湿织物所需的微观网络结构。XRD研究表明碳氟膜是部分结晶的。XPS研究表明碳氟膜的氟碳面积比随着压力的增加而增加。

Abstract: In order to research and develop waterproof & moisture permeable PET fabric,fluorocarbon film was prepared on PET film and fabric by magnetron sputtering.Nanostructure and homogeneity of fluorocarbon film were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS).SEM shows that fluorocarbon film is in good orientation under certain conditions and has a character of network and rod-shaped nano self-assembly.Network structure of film was obtained for development of waterproof & moisture permeable fabrics.It is indicated by XRD that fluorocarbon film is partly crystallized.XPS shows that the ratio of F/C increases with the pressure increase

王东;矫丽珍;昃向君;路建军;齐宏进. PET基底上碳氟膜纳米结构及均匀性研究[J]. 纺织学报, 2007, 28(12): 48-50.

WANG Dong;JIAO Lizhen;ZE Xiangjun;LU Jianjun;QI Hongjin. Study of nanostructure and uniformity of fluorocarbon films prepared on PET substrates[J]. JOURNAL OF TEXTILE RESEARCH, 2007, 28(12): 48-50.

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