纺织学报 ›› 2012, Vol. 33 ›› Issue (8): 71-75.

• 染整与化学品 • 上一篇    下一篇

氧漂活化剂的制备及应用

董玲   

  1. 南通大学染整技术研究所
  • 收稿日期:2011-08-29 修回日期:2012-05-07 出版日期:2012-08-15 发布日期:2012-08-08
  • 通讯作者: 董玲 E-mail:dong.l@ntu.edu.cn
  • 基金资助:

    南通大学2009年度校级产学研课题

Preparation and application of peroxide bleaching activator

 DONG  Ling   

  1. Institute of Dyeing and Finishing Technology, Nantong University
  • Received:2011-08-29 Revised:2012-05-07 Online:2012-08-15 Published:2012-08-08
  • Contact: Ling DONG E-mail:dong.l@ntu.edu.cn

摘要: 针对传统棉织物漂白工艺温度高和强力损失大等问题,制备了氧漂活化剂,其主要有效成分为壬酰氧基苯磺酸钠(NOBS),得出了较佳的制备工艺:将对羟基苯磺酸钠溶解于等摩尔物质的量的氢氧化钠溶液,加入5%四丁基溴化铵,壬酰氯与对羟基苯磺酸钠物质的量比1.3︰1,30 ℃下反应80 min,所得产品不经分离可作为活化剂直接应用于纯棉针织物的练漂加工中。该氧漂活化剂的应用可将练漂温度降至80 ℃,并能保证练漂效果,且强力损失降低,能耗减少。

关键词: 低温 , 漂白 , 活化剂 , 制备 ,  , 应用

Abstract: Aiming at the problems existing in traditional cotton fabric bleaching such as high temperature and strength loss, a peroxide bleaching activator was prepared, and the main effective component was nonanoyloxybenzenesulfonate sodium(NOBS). The optimal synthetic conditions were as follows: 4-phenolsulfonate sodium was dissolved in sodium hydroxide solution, the mol ratio of sodium hydroxide to 4-phenolsulfonate sodium was 1:1. The mol ratio of nonanoyl chloride to 4-phenolsulfonate sodium was 1.3:1. Then nonanoyl chloride was added dropwise, followed by stirring at 30 ℃ for 80 min with 5% phase transfer catalyst tetrabutylammonium bromide and the peroxide bleaching activator was obtained. The results showed that addition of the activator to the scouring and bleaching process can lower the temperature of bleaching to 80 ℃ and similar effects were obtained. Compared to the traditional bleaching, the strength loss and the energy consumption was lower.

Key words: low temperature , bleaching , activator , preparation , application

中图分类号: 

  • TS192.2
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