纺织学报 ›› 2013, Vol. 34 ›› Issue (9): 21-0.

• 纤维材料 • 上一篇    下一篇

采用生物酶法去除山羊绒肤皮屑

陈晓盟1,王树根1,薛晨2,   

    1. 生态纺织教育部重点实验室(江南大学)
    2. 新疆天山毛纺股份有限公司
  • 收稿日期:2012-09-13 修回日期:2013-03-25 出版日期:2013-09-15 发布日期:2013-09-12
  • 通讯作者: 王树根 E-mail:wangshugen@163.com

Enzymatic removal of skin crumbs from cashmere

  • Received:2012-09-13 Revised:2013-03-25 Online:2013-09-15 Published:2013-09-12

摘要: 尝试采用生物酶法去除山羊绒染色中多年未根本解决的羊绒肤皮点问题。分别选用角质酶、胃蛋白酶和蛋白酶三种生物酶处理了山羊绒肤皮屑,考核去屑效果,研究各生物酶处理的工艺条件,同时考察了处理前后山羊绒损伤情况.结果表明,T.fusca角质酶去除山羊绒肤皮屑工艺条件为:角质酶用量8mL/g,pH=8.0,60℃,5h,浴比1:50,肤皮屑去除率29%.胃蛋白酶去除山羊绒肤皮屑工艺条件为:胃蛋白酶用量6%(o.w.f),pH=2.2,4℃,6h,浴比1:50,肤皮屑去除率17%.蛋白酶Savinase 16L去除山羊绒肤皮屑工艺条件为:蛋白酶用量1mL/g,pH=8.5,45℃,4h,浴比1:50,肤皮屑去除率46%.在上述工艺条件下,角质酶和胃蛋白酶处理对羊绒有轻微的损伤,可以作为一种新的去除羊绒肤皮点的方法,蛋白酶对羊绒的损伤较严重,不能采用.生物酶法能部分去除山羊绒肤皮屑,有必要进行进一步的研究。

关键词: 山羊绒, 肤皮屑, 角质酶, 胃蛋白酶, 蛋白酶

Abstract: This paper attempts to adopt enzymatic approach to remove the skin crumbs from cashmere, since the skin crumb is a long-standing problem not fundamentally solvedover the years in cashmere dyeing. Three biological enzymes-cutinase, pepsin and protease were sdlected and applied to the treatment of skin crumbs searately.The effect of skin crumbs removal was investigated and the individual process conditions were examined. The fiber damages of the cashmere before and after treatment were compared. The results showed that the skin crumbs removal rate reached 29% when T. fuscacutinase was used in the treatment of skin crumbs under the conditions: amount of T. fuscacutinase 8 mL/g, pH=8.0 , temperature 60°C , time 5 h ,and liquor ratio 1:50 .The removal rate was 17% in the case of pepsin under the conditions: pH=2.2, temperature 4 °C ,amount of pepsin 6% (o.w.f), time 6 h, and liquou ratio 1:50. And the removal rate was up to 46% in the case of protease Savinase 16 L under the conditions: amount of Savinase 16 L, 1 mL/g, pH=8.5, temperature 45°C, time 4 h, and liquor ratio 1:50. The experimental results revealed that cutinase and pepsin caused only slight damage to the treated fiber whereas protease led to serious fiber damage. Therefore, the former two kinds of enzymes may be used in the treatment of cashmere for removing skin crumbs. The enzymatic method can partially remove the cashmere skin crumbs, so it is necessary to make further study.

Key words: cashmere, skin crumbs, cutinase, pepsin, protease

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