纺织学报 ›› 2015, Vol. 36 ›› Issue (08): 74-77.

• 染整与化学品 • 上一篇    下一篇

环保型含氟多功能整理剂的合成及其应用

  

  • 收稿日期:2014-08-08 修回日期:2015-04-13 出版日期:2015-08-15 发布日期:2015-08-07
  • 基金资助:

    江苏省大学生创新项目

Synthesis and application of an environmentally friendly multi-finishing agent

  • Received:2014-08-08 Revised:2015-04-13 Online:2015-08-15 Published:2015-08-07

摘要:

以三聚氯化磷腈、四氟丙醇及金属钠为原料,以四氢呋喃为溶剂,合成出一种无PFOS的含氟整理剂,并研究了其在棉织物上的整理效果。通过红外图谱分析,合成产物符合设计要求;研究了整理剂用量、催化剂用量及焙烘温度对整理后织物的阻燃性能和拒水性能,得到了优化工艺:二浸二轧,整理剂用量100 g/L,催化剂用量2.5g/L, 预烘温度80℃,焙烘温度150℃。整理后织物的Tg和DTg分析显示,经整理棉织物的热稳定性得到提高,残渣量增加,LOI值测试显示,整理后织物具有良好的阻燃性能;接触角测试显示,整理后织物具有良好的拒水性能。

Abstract:

In this paper, an environmentally friendly multi-finishing agent without PFOS was synthesized by phosphonitrilic chloride trimer,,tetrafluoropropyl alcohol and sodium metal in tetrahydrofuran, it’s application on cotton was researched. The structure of this finishing agent was characterized by IR. The effect of dosage of finishing agent, catalytic agent and the temperature of curing was also researched, and the optimum process was observed: immerse twice padding two times at room temperature, the dosage of finishing agent was100 g/L,the dosage of catalytic agent was2.5g/L, and the curing temperature was 150℃.The thermal stability of treated cotton was observed by Tg and DTg. The results show that after treated by the multi-finishing agent, the cotton was endowed nice flame retardance and water repellence.

中图分类号: 

  • TS193.5
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