Journal of Textile Research ›› 2018, Vol. 39 ›› Issue (10): 81-85.doi: 10.13475/j.fzxb.20171008806

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Dyeing properties of difluorenylidene quinoidal thiophene dye on cotton fabric

  

  • Received:2017-10-25 Revised:2018-03-27 Online:2018-10-15 Published:2018-10-17

Abstract:

In order to develop environmentally friendly direct dyes for cotton fabrics, a self-made difluorenylidene quinoidal thiophene dye SR was applied to dye cotton fabric. The effects of dyeing temperature, time, dye dosage and mass concentration of sodium sulfate on dyeing performance were investigated and dyeing condition was optimized. Dyeing dynamics were studied by using pseudo second-order kinetic model. Besides, relevant experimental data were analyzed by using Freundlich adsorption isotherm model. The results showed that proper dyeing condition at 1% (o.w.f.) of dye concentration are 55 oC of temperature, 60 min of contact time, 10 g/L of mass concentration of sodium sulfate and 1:50 of liquor ratio. Under the conditions, 70.7% of equilibrium dye-uptake and 18.76 of color depth are achieved. The dyeing dynamics can be described with pseudo second-order kinetic model. As the dyeing temperature increase, dyeing rate constant as well as diffusion coefficient increase, accompanied with the decrease of half-dyeing time. The Freundlich type thermodynamic adsorption model fits well to describe the adsorption behavior of dye SR on cotton fabric.

Key words: difluorenylidene quinoidal thiophene dye, cotton fabric, dyeing, dyeing dynamics

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