Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (10): 101-106.doi: 10.13475/j.fzxb.20191102506

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and electric storage performance of stretchable polypyrrole/cotton knitted fabric

WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia()   

  1. College of Textile Science and Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
  • Received:2019-11-08 Revised:2020-06-30 Online:2020-10-15 Published:2020-10-27
  • Contact: WANG Chaoxia E-mail:wchaoxia@sohu.com

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Abstract:

To endow knitted cotton fabrics with new function such as conductance and electricity storage for wearable devices, pyrrole monomers were in-situ polymerized on a knitted cotton fabric to fabricate the polypyrrole/cotton knitted fabric. Scanning electron microscope and Fourier transform infrared spectra were used to detect the morphologies and chemical structures of the polypyrrole/cotton knitted fabric. The surface resistances and the electrochemical performances of polypyrrole/cotton knitted fabric at different tensile strain were also measured. The results show that sufficient polypyrrole is coated on knitted cotton fibers, and the surface resistances decreases from 429.2 Ω to 231.4 Ω when the strain is changed from 0% to 40%. The areal capacitance of the polypyrrole/cotton knitted fabric is 680.6 mF/cm 2 at the scan rate of 5 mV/s, and is 1 014.2 mF/cm2 at the current density of 2 mA/cm2. The symmetric supercapacitor device prepared from the polypyrrole/cotton knitted fabric shows an areal capacitance of 229.8 mF/cm2 at 1 mA/cm2 and 161.5 mF/cm2 at 5 mA/cm2, and this device exhibits a capacitance retention of 76.3% after 10 000 galvanostatic charging/discharging cycles.

Key words: conductive fabric, strain sensor, polypyrrole, cotton fabric, electrode, supercapacitor

CLC Number: 

  • TS106

Fig.1

Morphologies of cotton knitted fabric and PPy/cotton knitted fabric. (a) Cotton knitted fabric (×100); (b) Cotton knitted fabric (×3 000); (c) PPy/knitted cotton fabric (×100); (d) PPy/cotton knitted fabric (×5 000)"

Fig.2

FT-IR spectra of cotton knitted fabric and PPy/cotton knitted fabric"

Fig.3

Surface resistances of PPy/cotton knitted fabric at different strains(a) and its monitoring function for finger bending(b)"

Fig.4

Electrochemical performances of PPy/knitted cotton fabric tested in three-electrode system. (a) Cyclic voltammetry curves; (b) Areal capacitances and scan rates curve; (c) Voltage-time curves; (d) Areal capacitances and current densities curve"

Fig.5

Electrochemical performances of symmetric device based on PPy/cotton knitted fabric tested in two-electrode system. (a) Cyclic voltammetry curves; (b) Areal capacitances and scan rates curve; (c) Voltage and time curves; (d) Areal capacitances current densities curve"

Fig.6

Energy density and power density curve(a), capacitance retention and coulombic efficiency(b) of symmetric device based on PPy/cotton knitted fabric"

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