剪切增稠液/纤维复合材料防弹性能的研究进展

doi:10.13475/j.fzxb.20200603809

Abstract

Abstract:

In order to promote the research and applications of intelligent impact protection materials, this paper reviewed the progress in shear thickening fluid (STF) impregnated high-performance fibers, summarizing their effective mechanical response and energy absorption mechanism upon high velocity impact. The research progress of STF rheological properties, mechanical properties of STF/fiber composites and their anti-ballistic impact mechanisms were reviewed. The selection of STF raw material, the construction principle of composite material system and the preparation method were analyzed. According to the characteristics of ballistic impact process and the reaction mechanisms of STF/fiber composites under high velocity impact, the factors affecting ballistic impact performance were discussed and perspective solutions proposed. The research direction of flexible and intelligent STF/fiber bullet proof composites with high responsiveness is forecasted, and it was made clear that the characterization and evaluation methods of flexible and intelligent STF/fiber bulletproof composites still need improving. The composites based on the three-dimensional self-reinforcing structures, the interfacial bonding between fiber material and STF, the rheological slip and friction characteristics are the key research points in the future.

Key words: shear thickening, bulletproof mechanism, fiber reinforced composite, rheological property, bulletproof property

CLC Number:

TB332

ZHANG Qianyu, QIN Zhigang, YAN Ruosi, JIA Lixia. Research progress on bulletproof properties of shear thickening fluid/high performance fiber composites[J].Journal of Textile Research, 2021, 42(06): 180-188.

Figures/Tables 6

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Fig.3

Tab.1

Tab.2

Tab.3

References 65

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分散相(质量分数)	分散介质	单相/多相	制备方法	参考文献
气相SiO₂(10%~40%)	聚乙二醇(PEG)	单相	高速分散器	[17]
SiO₂颗粒(60%、65%)	PEG	单相	机械+超声波搅拌	[18-19]
亚微米SiO₂(65%)	PEG	单相	匀浆器+超声波搅拌	[19]
改性SiO₂(50%)	PEG	单相	超声波搅拌	[20]
CaCO₃(10%~40%)	PEG	单相	高速剪切机+超声波搅拌	[21]
玉米淀粉(43%、55%)	水	单相	超声波搅拌	[7]
SiO₂(50%~64%)	离子液体	单相	超声波搅拌	[11]
聚氯乙烯(47%~57%)	邻苯二甲酸二辛酯	单相	机械搅拌	[22]
聚甲基丙烯酸甲酯(51%)	PEG	单相	机械搅拌	[23]
SiO₂(20%)/SiC(45%)	PEG	多相	高速分散器	[24]
SiO₂(44%)/CNT(0.8%)	PEG	多相	高速剪切机	[25-26]
Si(20%)/SiC(5%、25%、45%)	PEG	多相	高速分散器	[27]
SiO₂(10%、17.5%、25%)/ 硅烷偶联剂(18%、28%、38%)	PEG	多相	超声波搅拌	[28-29]
Si(25%、50%、75%)/CaCO₃(75%、50%、25%)	PEG	多相	高速剪切机+超声波搅拌	[21]
聚苯乙烯丙烯酸酯(53.5%)/CNT(1%、1.5%)	PEG	多相	超声波搅拌	[30]

纤维名称	纤维名称	织物结构	增强体类型	与STF复合方法	参考文献
芳纶	Kevlar??	平纹斜纹非织造布	叠层叠层叠层	浸渍浸渍浸渍	[19] [32] [11]
		非织造布	叠层	涂层	[21]
	Kevlar??/铝板	层合板结构	多元复合结构	浸渍	[33]
	Kevlar??/玻璃纤维	经编间隔织物	三维结构	填充	[34]
	HT-840(Heracron??)	平纹	叠层	浸渍	[35]
		平纹	叠层	涂层	[36]
	Twaron??	平纹	叠层	浸渍	[16]
	芳纶/碳纤维	三明治蜂窝芯结构	多元复合结构	填充	[37]
	芳纶	三维正交	三维结构	浸渍	[38]
超高分子量聚乙烯 (UHMWPE)	UHMWPE	平纹	叠层	浸渍	[39-40]
	UHMWPE	单向织物	叠层	浸渍	[41]
	UHMWPE/发泡材料	层合板结构	多元复合结构	浸渍	[42]
其他	高模聚丙烯	平纹	叠层	浸渍	[25]
其他	涤纶	经编间隔织物	三维结构	填充	[43-44]

影响类型	影响因素	影响方式	参考文献
纤维	种类	断裂强度	[49?-51]
纤维	线密度	颗粒附着量	[35]
织物	密度	纱线间摩擦力	[35]
织物	组织结构	应力传递	[45-46]
结构	叠层结构(层数/顺序/角度/叠层方式)	强度/材料延伸率/应力传递/整体性	[52,19,16,21]
	三明治结构	粒子团聚	[43]
	多元复合结构	应力/应变	[48]
	三维结构	整体性	[38]
纳米填料	种类	黏度	[19,53]
	粒径	临界剪切速率	[54]
	含量	粒子团聚数量	[19,53,55]
	是否改性	粒子团聚速度	[56]
	多类	摩擦力/强度	[40,57-58]
复合方式	浸渍	渗透进内部	[18]
	喷涂	附着于表面	[21]
	填充	膨胀程度	[37]
环境	温湿度	断裂强力/布朗运动	[59]
环境	PH值	布朗运动	[59]
子弹	大小	冲击区域	[2]
	形状	冲击区域	[48]
	速度	剪切速率	[15,60]

Research progress on bulletproof properties of shear thickening fluid/high performance fiber composites

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