纺织学报 ›› 2017, Vol. 38 ›› Issue (10): 81-87.doi: 10.13475/j.fzxb.20161103607

• 染整与化学品 • 上一篇    下一篇

应用电子束辐照技术的棉织物抗菌整理工艺优化

  

  • 收稿日期:2016-11-15 修回日期:2017-05-27 出版日期:2017-10-15 发布日期:2017-10-16

Optimization on antibacterial finishing process of cotton fabric based on electron beam irradiation

  • Received:2016-11-15 Revised:2017-05-27 Online:2017-10-15 Published:2017-10-16

摘要:

为实现棉织物的高效抗菌,以氯苯咪唑为抗菌剂对棉织物进行抗菌整理,比较了轧烘焙、电子束辐照及等离子体预处理等方式对棉织物抗菌性能的影响。将整理剂浓度、浸泡时间以及辐照剂量作为影响因素进行正交试验,得到电子束辐照工艺的优化工艺条件为:整理剂浓度15%、浸泡时间60 min、辐照剂量65 kGy。对经轧烘焙工艺(PDC工艺)、电子束辐照工艺(EB工艺)、基于等离子体预处理的电子束辐照工艺(P-EB工艺)整理的棉织物进行表面形貌观察、红外光谱表征、抗菌性能及其耐洗牢度测试、断裂强力及白度测试。结果表明,三种工艺整理的棉织物均有效接枝氯苯咪唑,经P-EB整理的棉织物抗菌性能最优,并具有优异的耐洗牢度,且织物强力及白度均满足服用要求。

关键词: 棉织物, 抗菌整理, 轧烘焙, 电子束辐照, 等离子体预处理

Abstract:

In order to realize efficient antibacterial performance of cotton fabrics, clotrimazole, used as antibacterial agent was grafted onto cotton fibers by antibacterial finishing, and the effect of pad-dry-cure, electron beam irradiation, together with plasma pretreatment on antibacterial properties of cotton fabrics was demonstrated. The optimum condition of electron-beam irradiation was investigated by orthogonal experiments, which included such factors as the concentration of finishing agent, soaking time and irradiation dose. The electron-beam irradiation processing could be optimized under the condition of concentration of finishing agent of 15%, soaking time of 60 min and irradiation dose of 65 kGy. In addition, a series of standard tests were carried out on cotton fabrics finished by pad-dry-cure (PDC) processing, electron beam irradiation (EB) processing and electron beam irradiation processing based on plasma pretreatment (P-EB), including observation of surface morphology, Infrared spectra characterization, antibacterial performance as well as fastness to washing, breaking strength and whiteness. The results show that clotrimazole is successfully grafted onto cotton fabrics finished by all three finishing processes mentioned above. Peculiarly, the antibacterial activity of cotton fabrics finished by P-EB is the most optimized, on account of the finished cotton fabrics’ perfect fastness to washing and its breaking strength and whiteness conforming to apparel fabric standards.

Key words: cotton fabric, antibacterial finishing, pad-dry-cure, electron-beam irradiation, plasma pretreatment

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