纺织学报 ›› 2019, Vol. 40 ›› Issue (03): 175-182.doi: 10.13475/j.fzxb.20180402608

• 综合述评 • 上一篇    下一篇

彩色聚合物微球的制备及其在纺织品印染中应用的研究进展

王东伟1,2, 房宽峻1,3(), 刘秀明1, 张健飞1,4, 舒大武1, 张鑫卿5   

  1. 1.天津工业大学 纺织科学与工程学院, 天津 300387
    2.中原工学院 纺织学院, 河南 郑州 450007
    3.山东省生态纺织协同创新中心, 山东 青岛 266071
    4.天津工业大学 先进纺织复合材料教育部重点实验室, 天津 300387
    5.河南工程学院 材料与化学工程学院, 河南 郑州 450007
  • 收稿日期:2018-04-13 修回日期:2018-10-17 出版日期:2019-03-15 发布日期:2019-03-15
  • 通讯作者: 房宽峻
  • 作者简介:王东伟(1978—),女,博士生。主要研究方向为纺织品清洁染整技术。
  • 基金资助:
    国家重点研发计划资助项目(2017YFB0309800);国家重点研发计划资助项目(2016YFC0400503)

Preparation of colored polymer microspheres and research progress thereof in textile dyeing and printing

WANG Dongwei1,2, FANG Kuanjun1,3(), LIU Xiuming1, ZHANG Jianfei1,4, SHU Dawu1, ZHANG Xinqing5   

  1. 1. School of Textile Science and Technology, Tianjin Polytechnic University, Tianjin 300387, China
    2. School of Textiles, Zhongyuan University of Technology, Zhengzhou, Henan 450007, China
    3. Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao, Shandong 266071, China
    4. Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, China
    5. School of Materials and Chemical Engineering, Henan University of Engineering, Zhengzhou, Henan 450007, China
  • Received:2018-04-13 Revised:2018-10-17 Online:2019-03-15 Published:2019-03-15
  • Contact: FANG Kuanjun

RichHTML

7

PDF (PC)

145

摘要：

为弥补纺织品着色用染料和颜料存在的不足,开发彩色聚合物微球作为新型色素是有效途径之一。介绍了聚合物微球的制备方法,综述了近年来国内外制备彩色聚合物微球的3种方法:聚合包覆法、直接染色法和表面修饰法,从彩色聚合物微球的粒径尺寸及单/窄分散性、染料在聚合物微球表面的吸附量及吸附稳定性、纯度和功能性4个方面探讨了由不同方法所制得的彩色聚合物微球的特点。结果表明:将彩色聚合物微球用于织物的染色和印花,可获得较高的颜色深度和鲜艳度,主要色牢度指标均达到服用性能要求;彩色聚合物微球具有染料色彩鲜艳和有机颜料耐久性好等优点,在纺织品印染方面具有良好的应用前景。

关键词: 新型色素, 彩色聚合物微球, 纺织品, 染色, 印花

Abstract:

In order to make up the inadequacy of dye and pigment used in textile dyeing and printing, the preparation of the colored polymer microspheres may be one of the effective ways to solve the problem. The preparation methods of the polymer microspheres were introduced. The three methods recently developed in preparation of the colored polymer microspheres, including the entrapment method, the direct staining method and the surface modification method, as well as their research progress were reviewed. The characteristics of the colored polymer microspheres prepared by various methods were analyzed and compared from four aspects, which include the size and single/narrow dispersion, the adsorption capacity and stability of the dye on the surface of the polymer microspheres, purity and functionality. The results show that the application of colored polymer microspheres in dyeing and printing of textiles achieve higher color depth and brightness, and the main color fastness can satisfy the requirement of wearability. With the advantages of good chromatic properties of dyes and good durability of organic pigments, the colored polymer microspheres show a good prospect in textile dyeing and printing.

Key words: novel colorant, colored polymer microsphere, textile, dyeing, printing

中图分类号: 

  • TS194.9

表1

聚合物微球制备方法的比较"

制备方法 微球尺寸/μm 分散度 表面活性剂 引发剂 反应介质 主要特点
乳液聚合 <1 较宽 乳化剂 水溶性 水相 粒径较小
悬浮聚合 20~1 000 较宽 悬浮剂 油溶性 水相 粒径较大
分散聚合 0.1~10 较窄 稳定剂 水溶性或油溶性 水相或超临界CO2或有机溶剂 单或窄分散性好
沉淀聚合 0.1~100 较窄 无 水溶性或油溶性 水相或超临界CO2或有机溶剂 产物纯净
[1] 宋心远, 涂料应用及节能减排:一[J]. 印染, 2013(12):44-47.
SONG Xinyuan. Pigment dyeing and energy-saving and emission reduction:Ⅰ[J]. China Dyeing & Finishing, 2013(12):44-47.
[2] 舒大武, 房宽峻, 刘秀明, 等. 活性染料无盐连续轧-蒸与冷轧堆染色效果的比较[J]. 纺织学报, 2018,39(4):77-81.
SHU Dawu, FANG Kuanjun, LIU Xiuming, et al. Comparision on dyeing effect of reactive dyes by salt-free continous pad-steam dyeing and cold pad-batch dyeing[J]. Journal of Textile Research, 2018,39(4):77-81.
[3] 贾艳萍, 姜成, 郭泽辉, 等. 印染废水深度处理及回用研究进展[J]. 纺织学报, 2017,38(8):172-180.
JIA Yanping, JIANG Cheng, GUO Zehui, et al. Research progress on deep treatment and recycling of dye wastewater[J]. Journal of Textile Research, 2017,38(8):172-180.
[4] KHATRI A, PEERZADA M H, MOHSIN M. A review on developments in dyeing cotton fabrics with reactive dyes for reducing effluent pollution[J]. Journal of Cleaner Production, 2015,87:50-57.
[5] 陈智杰, 吴明华, 史鹤鹤, 等. 涂料印染用自黏性有机颜料亚微胶囊的细乳液法制备[J]. 纺织学报, 2017,38(3):91-98.
CHEN Zhijie, WU Minghua, SHI Hehe, et al. Preparation of self-adhesive submicron organic pigment-containing capsules by miniemulsion polymerization for paint coloring[J]. Journal of Textile Research, 2017,38(3):91-98.
[6] WILSON J H, BRADBURY R, ANNABLE T, et al. Inkjet printable aqueous composite dye-polymer nanoparticles[J]. Dyes and Pigments, 2012,95(2):201-205.
[7] FU S H, ZHANG G F, DU C S, et al. Preparation of encapsulated disperse dye dispersion for polyester inkjet printing ink[J]. Journal of Applied Polymer Science, 2011,121(3):1616-1621.
[8] LI D, LE Y, HOU X Y, et al. Colored nanoparticles dispersions as electronic inks for electrophoretic display[J]. Synthetic Metals, 2011,161(5):1270-1275.
doi: 10.1016/j.synthmet.2011.04.022
[9] IBRAHIM E H, DENIZLI A, BEKTAS S, et al. Cadmium removal from human plasma by cibacron blue F3GA and thionein incorporated into polymeric microspheres[J]. Journal of Chromatography B, 1998,720(9):217-224.
[10] GOKAY O, KARAKOC V, ANDAC M, et al. Dye-attached magnetic poly(hydroxyethyl methacrylate) nanospheres for albumin depletion from human plasma[J]. Artificial Cells Nanomedicine and Biotechnology, 2015,43(1):1-9.
doi: 10.3109/21691401.2014.964554
[11] 任斌. 彩色聚合物微球的制备及其性能研究[D]. 青岛: 青岛大学, 2012: 1-6.
REN Bin. Preparation and properties of color polymer microspheres[D]. Qingdao: Qingdao University, 2012: 1-6.
[12] 张晗, 杨新林. 多层聚合物微球及其功能性空心聚合物微球的研究进展[J]. 高分子通报, 2010(7):9-23.
ZHANG Han, YANG Xinlin. Progress of monodisperse multi-layer polymer microspheres and the corresponding hollow functional polymer microspheres[J]. Chinese Polymer Bulletin, 2010(7):9-23.
[13] 任斌, 房宽峻, 蔡玉青. 超声悬浮共聚法制备聚合物微球及其形态[J]. 功能高分子学报, 2011,24(3):292-296.
REN Bin, FANG Kuanjun, CAI Yuqing. Preparation and morphology of polymer microspheres by ultrasonic suspension copolymerization method[J]. Journal of Functional Polymers, 2011,24(3):292-296.
[14] 张海超. 聚合物微球的表面改性及阴离子染料染色[D]. 青岛: 青岛大学, 2012: 1-4.
ZHANG Haichao. Surface modification of polymer microspheres and anionic dye staining[D]. Qingdao: Qingdao University, 2012: 1-4.
[15] 张洪涛, 黄锦霞. 乳液聚合新技术及应用[M]. 北京: 化学工业出版社, 2006: 74-99.
ZHANG Hongtao, HUANG Jinxia. New Technology and Application of Emulsion Polymerization[M]. Beijing: Chemical Industry Press, 2006: 74-99.
[16] 潘祖仁, 翁志学, 黄志明. 悬浮聚合[M]. 北京: 化学工业出版社, 1996: 49-192.
PAN Zuren, WENG Zhixue, HUANG Zhiming. Suspension Polymerization[M]. Beijing: Chemical Industry Press, 1996: 49-192.
[17] REN B, FANG K J, CAI Y Q. Preparation and morphology of polymer microspheres by ultrasonic suspension copolymerization method[J]. Journal of Functional Polymers, 2011,24(3):292-296.
[18] 张凯, 雷毅, 王宇光, 等. 单分散聚苯乙烯微球的制备及影响因素研究[J]. 功能高分子学报, 2002,15(2):189-193.
ZHANG Kai, LEI Yi, WANG Yuguang, et al. Studies of the preparation of monodisperse polystyrene microspheres and its influence factors[J]. Journal of Functional Polymers, 2002,15(2):189-193.
[19] 党高飞, 付志峰. 分散聚合技术及其研究进展[J]. 高分子通报, 2008,4(10):41-46.
DANG Gaofei, FU Zhifeng. Progress on research and technology of dispersion polymerization[J]. Polymer Bulletin, 2008,4(10):41-46.
[20] ROMACK T J, MAURY E E, DESIMONE M. Precipitation polymerization of acrylic acid in supercritical carbon dioxide[J]. Macromolecules, 1996,28:912-915.
[21] 潘祖仁. 高分子化学[M]. 北京: 化学工业出版社, 1997: 18-120.
PAN Zuren. Polymer Chemistry[M]. Beijing: Chemical Industry Press, 1997: 18-120.
[22] 张海超, 房宽峻, 蔡玉青. 阳离子表面活性剂与聚合物乳液相互作用[J]. 印染助剂, 2012,29(5):10-13.
ZHANG Haichao, FANG Kuanjun, CAI Yuqing. The interaction of cationic surfactants and polymer emul-sion[J]. Textile Auxiliaries, 2012,29(5):10-13.
[23] 张彩云, 房宽峻, 蔡玉青. 阳离子红X-GRL与聚合物乳液的相互作用[J]. 纺织学报, 2012,33(10):62-65.
ZHANG Caiyun, FANG Kuanjun, CAI Yuqing. Interaction of cationic red X-GRL with polymer emul-sion[J]. Journal of Textile Research, 2012,33(10):62-65.
doi: 10.1177/004051756303300108
[24] 王飞, 房宽峻. 乳化剂对阳离子乳液聚合及乳胶粒性能的影响[J]. 功能高分子学报, 2012,25(4):404-409, 438.
WANG Fei, FANG Kuanjun. Influence of emulsifiers on cationic emulsion polymerization and colloidal feature[J]. Journal of Functional Polymers, 2012,25(4):404-409, 438.
[25] 赵会霞, 房宽峻. 水溶性偶氮引发剂对阳离子乳液聚合的影响[J]. 功能高分子学报, 2013,26(4):417-422.
ZHAO Huixia, FANG Kuanjun. Influence of water-soluble azo initiators on cationic emulsion polymeriz-ation[J]. Journal of Functional Polymers, 2013,26(4):417-422.
[26] 刘燕, 房宽峻, 王玉平. 季铵盐阳离子单体对三元无皂乳液共聚物纳米球的影响[J]. 功能高分子学报, 2014,27(1):75-82.
LIU Yan, FANG Kuanjun, WANG Yuping. Effect of cationic comonomers on the emulsifier-free emulsion ternary copolymer nanospheres[J]. Journal of Functional Polymers, 2014,27(1):75-82.
[27] 石进荣. 活性黑5染料/聚合物微球的制备与染色应用[D]. 天津: 天津工业大学, 2018: 1-3.
SHI Jinrong. Preparation of reactive black 5 dye/ polymer microspheres and its application in dyeing[D]. Tianjin: Tianjin Polytechnic University, 2018: 1-3.
[28] LEE J H, GOMEZ I J, SITTER V B. Dye-labeled polystyrene latex microspheres prepared via a combined swelling-diffusion technique[J]. Journal of Colloid and Interface Science, 2011,363:137-144.
doi: 10.1016/j.jcis.2011.07.047 pmid: 21839463
[29] 刘宏波, 汪长春. 不同尺寸单分散PMMA/GMA/DVB聚合物荧光微球的制备[J]. 化学学报, 2008,66(10):1269-1273.
LIU Hongbo, WANG Changchun. Preparation of mono-dispersed fluorescent PMMA/GMA/DVB polymer microspheres with different sizes[J]. Acta Chimica Sinica, 2008,66(10):1269-1273.
[30] CANNIZZO C, AMIGONI-GERBIER S, FRIGOLI M, et al. A versatile preparation of azobenzene-dye functionalized colored polymer nanoparticles by surface modification[J]. Journal of Polymer Science: Part A: Polymer Chemistry, 2008,46:3375-3386.
[31] GAO H Y, KIM S, AN J H. Preparation of sub-micron colored particles by controlled emulsion polymeri-zation[J]. Journal of Industrial and Engineering Chemistry, 2013,19:1184-1190.
[32] LIU T, LI Z H, WU Q F, et al. Synjournal of nanocolorants with crosslinked shell by miniemulsion polymerization stabilized by waterborne poly-urethane[J]. Polymer, 2001,64:511-521.
[33] HU Z K, XUE M Z, ZHANG Q, et al. Nanocolorants: a novel class of colorants, the preparation and performance characterization[J]. Dyes and Pigments, 2008,76:173-178.
[34] POLPANICH D, ASAWAPIROM U, THIRAMANAS R, et al. Self-colored nanoparticles containing naphthalene-bisimide derivatives: synjournal and protein adsorption study[J]. Materials Chemistry and Physics, 2011,129:495-500.
[35] LI B T, SHEN J, JIANG Y M, et al. Preparation and properties of covalently colored polymer latex based on a new anthraquinone monomer[J]. Applied Polymer, 2013,129:1484-1490.
[36] HU Y, SHEN B Y, LI B T, et al. Preparation and properties of a novel polymerizable amphiphilic anthraquinone derivative and its cationic colored copolymer latexes[J]. RSC Advances, 2016,6:37765-37772.
[37] SONG J S, TRONC F, WINNIK M A. Monodisperse, controlled micron-size dye-labeled polystyrene particles by two-stage dispersion polymerization[J]. Polymer, 2006,47:817-825.
[38] WU W B, WANG M L, SUN Y M, et al. Dual-color polystyrene microspheres by two-stage dispersion copolymerization[J]. Materials Letters, 2008,62:2603-2606.
[39] 张连兵, 房宽峻, 张霞. 聚合物包覆偶氮结构有机颜料的制备[J]. 印染助剂, 2011,28(2):25-28.
ZHANG Lianbing, FANG Kuanjun, ZHANG Xia, et al. Preparation of polymer-encapsulated organic pigment with azo structure[J]. Textile Auxiliaries, 2011,28(2):25-28.
[40] 孟庆豪, 房宽峻, 付少海. 苯乙烯共聚物包覆颜料及其超细化[J]. 染料与染色, 2007,44(3):1-3, 7.
MENG Qinghao, FANG Kuanjun, FU Shaohai. Properties of nanoscale pigment surface-modified by polystyrene-butyl acrylate-acrylic acid[J]. Dyestuffs and Coloration, 2007,44(3):1-3, 7.
[41] BRAGA M, LEITE C A P, GALEMBECK F. Hydrophobic polymer modification with ionic reagents: polystyrene staining with water-soluble dyes[J]. Langmuir, 2003,19:7580-7586.
[42] BOSMA G, PATHMAMANOHARAN C, HOOG E H A D, et al. Preparation of monodisperse, fluorescent PMMA-latex colloids by dispersion polymerization[J]. Journal of Colloid and Interface Science, 2002,245:292-300.
doi: 10.1006/jcis.2001.7986 pmid: 16290362
[43] JERCA V V, NICOLESCU F A, TRUSCA R. Oxazoline-functional polymer particles graft with azo-dye[J]. Reactive and Functional Polymers, 2011,71(4):373-379.
[44] FANG K J, REN B. A facile method for preparing colored nanospheres of poly(styrene-co-acrylic acid)[J]. Dyes and Pigments, 2014,100(1):50-56.
[45] 夏效杰, 房宽峻, 任斌, 等. 分散染料染色法制备的彩色聚(苯乙烯-丙烯酸)纳米球[J]. 应用化学, 2015,32(1):64-70.
XIA Xiaojie, FANG Kuanjun, REN Bin, et al. Colored poly(styrene-co-acrylic acid)nanospheres prepared by dyeing with disperse dyes[J]. Chinese Journal of Applied Chemistry, 2015,32(1):64-70.
[46] 韩冬梅, 房宽峻, 蔡玉青, 等. 反应性P(St-BA-VBT)/染料复合纳米球的制备[J]. 功能高分子学报, 2015,28(2):220-224.
HAN Dongmei, FANG Kuanjun, CAI Yuqing, et al. Preparation of reactive P(St-BA-VBT)/dye composite nanospheres[J]. Journal of Functional Polymers, 2015,28(2):220-224.
[47] 郭子婧, 刘秀明, 房宽峻. 染料/聚合物复合共聚物微球的制备[J]. 纺织学报, 2017,38(7):80-84.
GUO Zijing, LIU Xiuming, FANG Kuanjun. Preparation of reactive dye/polymer composite copolymer microspheres[J]. Journal of Textile Research, 2017,38(7):80-84.
[48] CANNIZZO C, AMIGONI-GERBIER S, LARPENT C. Boronic acid-functionalized nanoparticles: synjournal by microemulsion polymerization and application as a reusable optical nanosensor for carbohydrates[J]. Polymer, 2005,46:1269-1276.
[49] DONG X Q, ZHENG Y H, HUANG Y B, et al. Synjournal and characterization of multifunctional poly(glycidyl methacrylate) microspheres and their use in cell separation[J]. Analytical Biochemistry, 2010,405:207-212.
doi: 10.1016/j.ab.2010.06.022 pmid: 20599531
[50] LIU D M, HAO L Y, FANG K J. Adsorption of cationic copolymer nanospheres onto cotton fibers investigated by a facile nephelometry[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014,425:82-88.
[51] 贺东琴, 房宽峻. 电导滴定法研究阳离子乳胶粒的导电性能及其在棉织物上的吸附[J]. 应用化学, 2014,31(5):581-588.
HE Dongqin, FANG Kuanjun. Studies on the conductivity of cationic latexes and its adsorption on cotton fabrics by conductometric titration[J]. Chinese Journal of Applied Chemistry, 2014,31(5):581-588.
[52] FANG K J, LIU Y, HAO L Y. Cationic styrene-butyl acrylate-quaternary ammonium copolymer nanospheres for surface modification of cotton fibers[J]. Fibers and Polymers, 2015,16(5):982-990.
[53] FANG K J, ZHAO H X, LI J Z, et al. Salt-free dyeing of cotton fabrics modified with cationic copolymer nanospheres using an acid dye[J]. Fibers and Polymers, 2017,18(2):400-406.
[54] FANG K J, SHU D W, LIU X M, et al. Reactive pad-steam dyeing of cotton fabric modified with cationic P(St-BA-VBT) nanospheres[J]. Polymers, 2018,564(10):1-11.
[55] 宋亚伟. 分散染料/P(St-BA-MAA)聚合物微球的制备及喷墨性能研究[D]. 青岛: 青岛大学, 2016: 1-6, 43.
SONG Yawei. Preparation and inkjet performance research of disperse dye/P(St-BA-MAA) polymer microspheres[J]. Qingdao: Qingdao University, 2016: 1-6, 43.
[56] FANG K J, ZHANG L, CAI Y Q. Hollow disperse dyes/copolymer composite nanospheres[J]. Dyes and Pigments, 2017,136:191-196.
[57] LEE J Y, TSAI M C, CHEN P C, et al. Thickness effects on light absorption and scattering for nanoparticles in the shape of hollow spheres[J]. The Journal of Physical Chemistry C, 2015,119:25754-25760.
[1] 段方燕, 王闻宇, 金欣, 牛家嵘, 林童, 朱正涛. 淀粉纤维的成形及其载药控释研究进展[J]. 纺织学报, 2020, 41(10): 170-177.
[2] 沈瑞超, 郗欣甫, 孙以泽. 三维增材鞋面印花机对位平台的冗余驱动控制策略[J]. 纺织学报, 2020, 41(10): 164-169.
[3] 乔燕莎, 王茜, 李彦, 桑佳雯, 王璐. 聚多巴胺涂层聚丙烯疝气补片的制备及其体外炎性反应[J]. 纺织学报, 2020, 41(09): 162-166.
[4] 严佳, 李刚. 医用纺织品的研究进展[J]. 纺织学报, 2020, 41(09): 191-200.
[5] 裘柯槟, 陈维国, 周华, 应双双. 成像技术在纺织品颜色测量中的应用进展[J]. 纺织学报, 2020, 41(09): 155-161.
[6] 庞雅莉, 孟佳意, 李昕, 张群, 陈彦锟. 石墨烯纤维的湿法纺丝制备及其性能[J]. 纺织学报, 2020, 41(09): 1-7.
[7] 应双双, 裘柯槟, 郭宇飞, 周赳, 周华. 纺织品色彩管理色表测量数据的误差优化[J]. 纺织学报, 2020, 41(08): 74-80.
[8] 李瑞卿, 王伟, 魏炳举, 周长文, 张淑桃. 应用环保型还原剂的硫化黑染色工艺[J]. 纺织学报, 2020, 41(08): 50-54.
[9] 盛明非, 张丽平, 付少海. 基于染料掺杂型液晶微胶囊的电刺激响应智能纺织品的制备及其性能[J]. 纺织学报, 2020, 41(08): 63-68.
[10] 郑畑子, 王建萍. 服装印花图案设计的感性研究[J]. 纺织学报, 2020, 41(08): 101-107.
[11] 占镠祥, 李婉, 王高军, 赵先丽, 王妮, 李毓陵. 微波处理在蛋白质纤维加工中的应用研究进展[J]. 纺织学报, 2020, 41(08): 128-134.
[12] 陈文豆, 张辉, 陈天宇, 武海良. 二氧化钛水热改性涤/ 棉混纺织物的自清洁性能[J]. 纺织学报, 2020, 41(07): 122-128.
[13] 丁永生, 代亚敏, 钟毅, 徐红, 毛志平, 张琳萍, 陈支泽. 棉纱线在活性染料皮克林乳液体系中的染色动力学[J]. 纺织学报, 2020, 41(07): 101-108.
[14] 刘国金, 石峰, 陈新祥, 张国庆, 周岚. 聚氨酯/ 相变蜡蓄热调温功能整理剂的制备及其在棉织物上的应用[J]. 纺织学报, 2020, 41(07): 129-134.
[15] 王亚停, 赵家琪, 王碧佳, 冯雪凌, 钱国春, 隋晓锋. 超细纤维合成革的染色与功能整理研究进展[J]. 纺织学报, 2020, 41(07): 188-196.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号　 京公网安备11010502044800号
版权所有 © 2021 《纺织学报》编辑部
地址： 北京市朝阳区延静里中街3号主楼6层《纺织学报》杂志社　邮政编码：100025　
电话：010-65017711,65917740　传真：010-65016539　Email:fangzhixuebao@vip.126.com
本系统由北京玛格泰克科技发展有限公司设计开发