纺织学报 ›› 2019, Vol. 40 ›› Issue (07): 108-112.doi: 10.13475/j.fzxb.20180700905

• 染整与化学品 • 上一篇    下一篇

涤纶基材表面银/铜薄膜制备及其性能

孟灵灵1, 魏取福2, 黄新民1, 纪丹丹1   

  1. 1. 盐城工学院 纺织服装学院, 江苏 盐城 224051
    2. 生态纺织教育部重点实验室(江南大学), 江苏 无锡 214122;
  • 收稿日期:2018-07-02 修回日期:2019-03-31 出版日期:2019-07-15 发布日期:2019-07-25
  • 作者简介:孟灵灵 (1980-),女,副教授,博士。主要研究方向为功能纳米纺织材料。E-mail: mllwx1022@163.com
  • 基金资助:
    江苏省产学研前瞻性项目(BY2016065-51);江苏省产学研前瞻性项目(BY2016065-28);江苏省生态环保重点实验室开放课题(JH201832);盐城市科技局项目(YKN2015011);中国纺织工业联合会项目(2014052);中国纺织工业联合会项目(2016044)

Preparation and properties of Ag/Cu film deposited on surface of polyester substrates

MENG Lingling1, WEI Qufu2, HUANG Xinmin1, JI Dandan1   

  1. 1. College of Textile & Clothing, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China;
    2. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China;
  • Received:2018-07-02 Revised:2019-03-31 Online:2019-07-15 Published:2019-07-25

摘要:

为探索涤纶基Ag/Cu薄膜结构及性能,采用直流和射频共溅法,以不同组织结构纯涤纶织物为基材,金属银和铜为靶材,制备纳米薄膜。借助场发射扫描电子显微镜、X射线衍射仪、光电子能谱仪、织物感应式静电仪、纺织品防紫外线性能测试仪和电磁防辐射性能测试仪对试样表面薄膜形貌及结构、抗静电、防紫外线、电磁屏蔽性能进行表征。结果表明:非织造布表面薄膜均匀连续,机织布表面纳米颗粒直径较小,针织布表面颗粒分布较为连续,但仍然存在部分岛状颗粒;试样表面Cu(111)、Cu(200)、Ag(111)和Ag(200)衍射峰均不明显,结晶度低;纳米薄膜没有被氧化,以单质形式存在;以非织造布为基材的试样其抗静电、抗紫外线、电磁屏蔽性能最优,针织布最差。

关键词: 涤纶基材, Ag/Cu薄膜, 纳米薄膜, 结构, 性能

Abstract:

In order to explore the structure and properties of polyester-based Ag/Cu films, nanoscale films were prepared by direct current and radio frequency co-sputtering using pure polyester fabrics of different structures as the substrate and metallic silver and copper as targets. Field emission scanning electron microscopy, X-ray diffractometry, photoelectron spectroscopy, fabric inductive electrostatic analysis, fabric UV protection and electromagnetic radiation test were utilized to characterize the surface morphology and structure and antistatic, anti-UV and anti-electromagnetic shielding performance of the samples. The experimental results show that the film on the surface of the nonwoven fabric is uniform and continuous, the diameter of the nano-particles on the surface of the woven fabric is small, and the surface distribution of the knitted fabric is continuous, but some island-like particles still exist. Cu(111), Cu(200), Ag(111) and Ag(200) diffraction peaks of Cu/Ag film on the surface of the sample are not obvious, and the crystallinity is low. XPS image shows that the nano-film is not oxidized, and exists in elemental form. The nonwoven fabric is used as the substrate, the antistatic, anti-UV, anti-electromagnetic shielding performance of the sample is the best, and the knitted fabric is the worst.

Key words: polyester substrate, Ag/Cu film, nano film, structure, performance

中图分类号: 

  • TS174

图1

不同基材表面沉积Ag/Cu膜SEM照片(×50 000)"

图2

不同基材表面沉积Ag/Cu膜XRD图"

图3

沉积Ag/Cu膜XPS图"

表1

试样抗静电性能"

试样名称 静电电压/V 静电半衰期/s
非织造布基Ag/Cu膜
机织布基Ag/Cu 膜
针织布基Ag/Cu 膜
616
647
790
0.67
6.69
15.81

图4

不同基材表面沉积Ag/Cu膜透射率变化曲线"

图5

不同基材表面沉积Ag/Cu膜屏蔽效能值"

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