纺织学报 ›› 2021, Vol. 42 ›› Issue (03): 175-180.doi: 10.13475/j.fzxb.20200203806

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聚合物基石墨烯复合纤维及其纺织品研究进展

姜兆辉1,2, 李永贵2(), 杨自涛3, 郭增革1, 张战旗4, 齐元章4, 金剑5   

  1. 1.山东理工大学 鲁泰纺织服装学院, 山东 淄博 255000
    2.闽江学院 福建省新型功能性纺织纤维及材料重点实验室, 福建 福州 350108
    3.武夷学院 福建省生态产业绿色技术重点实验室, 福建 武夷山 354300
    4.鲁丰织染有限公司, 山东 淄博 255100
    5.中国纺织科学研究院有限公司, 北京 100025
  • 收稿日期:2020-02-19 修回日期:2020-08-17 出版日期:2021-03-15 发布日期:2021-03-17
  • 通讯作者: 李永贵
  • 作者简介:姜兆辉(1982—),男,副教授,博士。主要研究方向为功能纤维材料。
  • 基金资助:
    山东省重点研发计划项目(2019RKB01208);淄博市校城融合发展计划项目(2018ZBXC474);福建省生态产业绿色技术重点实验室开放基金资助项目(WYKF2019-5);福建省新型功能性纺织纤维及材料重点实验室开放基金项目(FKLTFM1820)

Research progress in graphene/polymer composite fibers and textiles

JIANG Zhaohui1,2, LI Yonggui2(), YANG Zitao3, GUO Zengge1, ZHANG Zhanqi4, QI Yuanzhang4, JIN Jian5   

  1. 1. Lutai School of Textile and Apparel, Shandong University of Technology, Zibo, Shandong 255000, China
    2. Fujian Key Laboratory of Novel Functional Textile Fibers and Materials, Minjiang University, Fuzhou, Fujian 350108, China
    3. Provincial Key Laboratory of Eco-Industrial Green Technology, Wuyi University, Wuyishan, Fujian 354300, China
    4. Lufeng Company Limited, Zibo, Shandong 255100, China
    5. China Textile Academy, Beijing 100025,China
  • Received:2020-02-19 Revised:2020-08-17 Online:2021-03-15 Published:2021-03-17
  • Contact: LI Yonggui

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摘要：

针对高纯石墨烯纤维可纺性差、成本高及分散难等问题,归纳了石墨烯的功能化改性方法,并对聚合物基石墨烯及其纺织品的研究进展进行综述。通过石墨烯与聚合物基体相的相互作用分析,深入探讨石墨烯对聚合物基石墨烯纤维微结构的影响机制,提出聚合物基石墨烯纺织品开发面临的技术挑战和理论难题。研究表明,石墨烯的高导电性和聚合物基体的柔性赋予聚合物基石墨烯纤维良好的可编织性,可确保其在拉伸、扭转、冲击等条件下具有良好的电导率稳定性,有望加快柔性可穿戴纺织品的开发进程。最后指出,利用可控和可预测的加工技术,在解决石墨烯高效分散的基础上可解决石墨烯高成本的问题,是聚合物基石墨烯纺织品的重要研究方向。

关键词: 石墨烯复合纤维, 智能纺织品, 石墨烯改性, 超分子结构, 柔性可穿戴纺织品

Abstract:

In view of the poor spinnability, high cost and difficult dispersion of high-purity graphene fibers, functional modification methods of graphene are summarized, and the research progress in polymer-based graphene fibers and fabrics is reviewed. Based on the analysis of the interaction between graphene and polymer matrix, the mechanism of graphene effect on the microstructure of polymer-based graphene fibers is also discussed, and the technical challenges and theoretical problems in the development of polymer-based graphene textiles are put forward. This review indicates that due to the high conductivity of graphene and flexibility of polymer matrix, the polymer-based graphene fibers have good flexibility and weavability, ensuring their good conductivity under the conditions of tension, torsion, impact, and so on. This is expected to accelerate the development process of flexible, wearable and smart textiles. It is pointed out that in face of the high cost of graphene, using controllable and predictable processing technology to solve the high dispersion of graphene, to achieve the high-efficiency under the low addition of graphene and to reduce the high cost, is an important research direction of polymer-based graphene textiles.

Key words: graphene composite fiber, intelligent textiles, graphene modification, supramolecular structure, flexible wearable textiles

中图分类号: 

  • TQ317.2

图1

聚合物基石墨烯纤维制备方法"

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