纺织学报 ›› 2021, Vol. 42 ›› Issue (10): 41-46.doi: 10.13475/j.fzxb.20201207506

• 纤维材料 • 上一篇    下一篇

4种家蚕茧壳的结构与性能

薛如晶1, 莫晓璇1, 刘福娟1,2,3()   

  1. 1.苏州大学 纺织与服装工程学院, 江苏 苏州 215021
    2.苏州大学 现代丝绸国家工程实验室,江苏 苏州 215123
    3.南通纺织丝绸产业技术研究院, 江苏 南通 226300
  • 收稿日期:2020-12-28 修回日期:2021-06-17 出版日期:2021-10-15 发布日期:2021-10-29
  • 通讯作者: 刘福娟
  • 作者简介:薛如晶(1997—),女,硕士生。主要研究方向为功能性纺织品。
  • 基金资助:
    中国纺织工业联合会科技指导性项目(2019010);南通市科技项目(JC2019009)

Structure and properties of four different kinds of domestic cocoon varieties

XUE Rujing1, MO Xiaoxuan1, LIU Fujuan1,2,3()   

  1. 1. College of Textile and Clothing Engineering, Soochow University, Suzhou, Jiangsu 215021, China
    2. National Engineering Laboratory of Modern Silk, Soochow University, Suzhou, Jiangsu 215123, China
    3. Nantong Textile & Silk Industrial Technology Research Institute, Nantong, Jiangsu 226300, China
  • Received:2020-12-28 Revised:2021-06-17 Published:2021-10-15 Online:2021-10-29
  • Contact: LIU Fujuan

摘要:

为开发设计新型功能纺织品,借助扫描电子显微镜、傅里叶红外光谱仪、X射线衍射仪、万能材料试验机和温湿度试验仪等研究了4种不同的家蚕茧壳的多层形貌、化学结构、结晶结构、力学性能和热传导性能,并对蚕茧壳的多层结构进行理论分析。结果表明:4种家蚕茧壳都具有独一无二的多层多孔结构,从外层到内层,纤维的直径先增大后减小;蚕茧壳厚度和尺寸不同,但都具有良好的热缓冲能力,相对而言,虎头蚕茧壳的耐热性最好,而斑马蚕茧壳(绿色)的热传导性最好。

关键词: 蚕茧壳, 热传导性能, 多层结构, 多孔介质

Abstract:

In order to develop and design new functional textiles, multilayer morphology, chemical structure, crystalline structure, mechanical properties and thermal conductivity of four varieties of different silkworm cocoons walls were characterized by scanning electron microscope, Fourier transform infrared spectroscopy, X-ray diffractometer, universal material testing machine and temperature and humidity tester, respectively. Theoretical analysis on the multilayer structure was conducted and the design principle of thermal protection products was studied and established. Research results show that all the four varieties of cocoon walls have unique multilayer porous structure, and the diameter of the fibers first increase and then decrease from the outer layer to the inner layer. Although the thickness and size are different, the four varieties of silkworm cocoon walls have good thermal buffering properties. In general, the tiger head cocoon wall has the best heat resistance, and the zebra cocoon wall (green) has the best thermal conductivity. When designing the multilayer structure of thermal protection products, the thermal insulation effect will be greatly improved by appropriately increasing the number of layers of thermal protection products under cost permission.

Key words: cocoon wall, thermal conductivity, multilayer structure, porous media

中图分类号: 

  • TS141

图1

蚕茧取样示意图"

图2

4种蚕茧壳的外观和内层扫描电镜照片(×150)"

图3

4种蚕茧壳从外层到内层纤维的平均直径"

图4

4种蚕茧壳最外层和最内层的红外光谱"

图5

4种蚕茧壳最外层与最内层的衍射光谱"

图6

4种蚕茧壳在径向和轴向上的应力-应变曲线"

表1

4种蚕茧在径向和轴向上的断裂应力和应变"

蚕茧种类 径向 轴向
断裂应力/MPa 断裂应变/% 断裂应力/MPa 断裂应变/%
虎头蚕茧壳 15.71 ± 6.29 12.45 ± 2.16 5.02 ± 1.18 14.04 ± 1.85
白色茧壳 23.90 ± 4.64 12.03 ± 1.02 8.18 ± 2.81 9.15 ± 1.23
斑马蚕茧壳(绿色) 22.27 ± 1.77 12.60 ± 0.71 1.81 ± 0.81 8.28 ± 7.12
斑马蚕茧壳(黄色) 32.45 ± 5.19 16.18 ± 1.52 10.56 ± 2.35 14.85 ± 2.10

图7

环境温度升高和降低时4种蚕茧壳的内部温度变化"

[1] 张阳阳, 李菁, 赵丰, 等. 家蚕、蓖麻蚕和天蚕的茧丝结构比较[J]. 蚕业科学, 2015, 41(3):491-497.
ZHANG Yangyang, LI Jing, ZHAO Feng, et al. A comparison on structure of cocoon filaments from mulberry silkworm, eri-silkworm and giant silkworm[J]. Science of Sericulture, 2015, 41(3):491-497.
[2] 谢启凡, 胡彬慧, 杨明英, 等. 家蚕茧及其茧丝和生丝的机械性能概述[J]. 蚕业科学, 2015, 41(6):1120-1126.
XIE Qifan, HU Binhui, YANG Mingying, et al. A review on mechanical properties of silkworm cocoon, cocoon filament and raw silk[J]. Science of Sericulture, 2015, 41(6):1120-1126.
[3] 肖信香, 余博文, 朱文清, 等. 天然柞蚕茧基本性能研究[J]. 武汉纺织大学学报, 2015, 28(3):5-9.
XIAO Xinxiang, YU Bowen, ZHU Wenqing, et al. Study on basic properties of natural tussah cocoon[J]. Journal of Wuhan Textile University, 2015, 28(3):5-9.
[4] DANKS H V. The roles of insect cocoons in cold conditions[J]. European Journal of Entomology, 2004, 101(3):433-437.
doi: 10.14411/eje.2004.062
[5] 岳冬梅 . 王林美, 李树英. 几种野蚕丝形态结构的比较分析[C]// 中国蚕学会. 中国蚕学会第八届青年学术研讨会论文集. 昆明: 中国蚕学会, 2014: 241-245.
YUE Dongmei, WANG Linmei, LI Shuying. The comparative analysis on the morphological structure of wild silk[C]// Chinese Silkworm Society. Proceedings of the 8th Youth Academic Symposium of Chinese Silkworm Society. Kunming: Chinese Silkworm Society, 2014: 241-245.
[6] CHEN F J, PORTER D, VOLLRATH F. Structure and physical properties of silkworm cocoons[J]. Journal of the Royal Society Interface, 2012, 7(74):2299-2308.
[7] GUAN J, ZHU W S, LIU B H, et al. Comparing the microstructure and mechanical properties of bombyx mori and antheraea pernyi cocoon composites[J]. Acta Biomaterialia, 2017, 47:60-70.
doi: 10.1016/j.actbio.2016.09.042
[8] ZHANG J, KAUR J, RAJKHOWA R, et al. Mechanical properties and structure of silkworm cocoons: a comparative study of bombyx mori, antheraea assamensis, antheraea pernyi and antheraea mylitta silkworm cocoons[J]. Materials Science & Engineeering C: Materials for Biological Applications, 2013, 33(6):3206-3213.
[9] LIU F J, WANG P, ZHANG Y, et al. A fractional model for insulation clothings eith cocoon-like porous structure[J]. Thermal Science, 2016, 20(3):779-784.
doi: 10.2298/TSCI1603779L
[10] CHUNG D E, KIM H H, KIM M K, et al. Effects of different bombyx mori silkworm varieties on the structural characteristics and properties of silk[J]. International Journal of Biological Macromolecules, 2015, 79:943-951.
doi: 10.1016/j.ijbiomac.2015.06.012
[11] LIU F J, ZHANG X J, LI X. Silkworm (bombyx mori) cocoon vs wild cocoon multi-layer structure and performance characterization[J]. Thermal Science, 2019, 23(4):2135-2142.
doi: 10.2298/TSCI1904135L
[12] HIEBER C S. The insulation layer in the cocoons of argiopeaurantia (araneae, araneidae)[J]. Journal of Thermal Biology, 1985, 10(3):171-175.
doi: 10.1016/0306-4565(85)90023-3
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