纺织学报 ›› 2022, Vol. 43 ›› Issue (12): 42-47.doi: 10.13475/j.fzxb.20210906506

• 纤维材料 • 上一篇    下一篇

废弃玉米秸秆的结构特征及其吸声性能

吕丽华(), 李臻   

  1. 大连工业大学 纺织与材料工程学院, 辽宁 大连 116034
  • 收稿日期:2021-09-01 修回日期:2022-05-13 出版日期:2022-12-15 发布日期:2023-01-06
  • 作者简介:吕丽华(1978—),女,教授,博士。主要研究方向为纤维材料再生资源利用技术。E-mail lvlh@dlpu.edu.cn
  • 基金资助:
    大连市科技创新基金项目(2019J12SN71)

Structural characteristics and sound absorption performance of waste corn straw

LÜ Lihua(), LI Zhen   

  1. School of Textile and Material Engineering, Dalian Polytechnic University, Dalian, Liaoning 116034, China
  • Received:2021-09-01 Revised:2022-05-13 Published:2022-12-15 Online:2023-01-06

摘要:

为增加废弃玉米秸秆的回收利用率,分别以长度为1.5、6和10 mm的废弃秸秆颗粒、棉纤维和大麻纤维为增强材料,聚己内酯为基体材料,通过热压成型工艺制备厚度为1.5 cm的吸声复合材料。采用声阻抗传递函数法对复合材料的吸声性能进行测试与对比,并分析其吸声机制。结果表明:1.5 mm长的废弃秸秆所制备复合材料的吸声性能最好,最大吸声系数达到0.71,平均吸声系数为0.50,降噪系数达到了0.51;废弃秸秆纤维素大分子主链上的氧六环结构为声波反复反射、折射提供了基础,较高的线性使得氢键等单键能够自由旋转,增加了声波能量的消耗,且废弃玉米秸秆的结晶度低使得声能易于沿着分子链传播,从而将声能转化为分子链段振动耗散。

关键词: 废弃玉米秸秆, 吸声材料, 结构特征, 吸声性能, 吸声机制, 聚己内酯

Abstract:

In order to recycle effectively the waste corn straw, sound-absorbing composites with a thickness of 1.5 cm were prepared by hot pressing the waste straw pellets with length of 1.5 mm, 6 mm, and 10 mm, cotton fiber and hemp fiber as reinforcement materials, and polycaprolactone as the matrix material. The sound absorption capabilities of the composites were evaluated and compared using the acoustic impedance transfer function approach. The results demonstrate that the 1.5 mm length of waste corn straw is suitable for the creation of sound-absorbing composites because it has the best sound absorption performance, with a maximum absorption coefficient of 0.71, an average absorption coefficient of 0.50, and a noise reduction coefficient of 0.51. The oxyhexacyclic structure on the main chain in corn straw cellulose macromolecule provides the basis for repeated reflection and refraction of sound waves. The high linearity enables the hydrogen bonds and other single bonds to rotate freely, which increases the consumption of sound energy. Moreover, the low crystallinity of waste corn straw makes the sound energy easy to propagate along the molecular chain, thus converting the sound energy into the vibration dissipation of the molecular chain.

Key words: waste corn straw, sound absorption material, structural characteristic, sound absorption performance, sound absorption mechanism, polycaprolactone

中图分类号: 

  • TS102.9

图1

不同增强体制备的复合材料的实物图"

图2

不同增强体制备复合材料的吸声系数曲线"

表1

复合材料的平均吸声系数和降噪系数"

样品名称 平均吸声系数 降噪系数
1.5 mm 废弃秸秆复合材料 0.50 0.51
6 mm 废弃秸秆复合材料 0.37 0.36
10 mm 废弃秸秆复合材料 0.36 0.28
棉纤维复合材料 0.20 0.16
大麻纤维复合材料 0.26 0.24

图3

纤维素Ⅰ结构式"

图4

β-D-葡萄糖椅式氧六环结构"

图5

吡喃木糖结构"

图6

废弃玉米秸秆的XRD图谱"

图7

废弃玉米秸秆形态结构的SEM照片"

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