纺织学报 ›› 2022, Vol. 43 ›› Issue (01): 89-95.doi: 10.13475/j.fzxb.20210909107

• 纺织工程 • 上一篇    下一篇

全棉水刺非织造布的低碳节能冷堆处理工艺

孙婷1, 张如全1,2(), 唐子杰1, 涂虎1,2, 胡敏1,2   

  1. 1.武汉纺织大学 纺织科学与工程学院, 湖北 武汉 430200
    2.武汉纺织大学 省部共建纺织新材料与先进加工技术国家重点实验室, 湖北 武汉 430200
  • 收稿日期:2021-09-26 修回日期:2021-11-02 出版日期:2022-01-15 发布日期:2022-01-28
  • 通讯作者: 张如全
  • 作者简介:孙婷(1996—),女,硕士生。主要研究方向为功能性非织造材料。
  • 基金资助:
    国家自然科学基金项目(52103125);湖北省重点研发计划项目(2020BAB076)

Study on low-carbon and energy-saving cold pad-batch bleaching treatment of cotton spunlaced nonwoven

SUN Ting1, ZHANG Ruquan1,2(), TANG Zijie1, TU Hu1,2, HU Min1,2   

  1. 1. College of Textile Science and Engineering, Wuhan Textile University, Wuhan, Hubei 430200, China
    2. Key Laboratory Base of New Textile Materials and Advanced Processing Technology,Wuhan Textile University, Wuhan, Hubei 430200, China
  • Received:2021-09-26 Revised:2021-11-02 Published:2022-01-15 Online:2022-01-28
  • Contact: ZHANG Ruquan

摘要:

为推动纺织行业实现碳中和、碳达峰目标,在满足绿色低碳、节能减排的前提下,以碱氧浓度、冷堆时间、双氧水活化剂浓度及不同处理方法为主要分析点,对全棉水刺非织造布采用冷堆脱漂工艺处理,分析其对质量损失率、吸水量、白度及残余液pH值、化学需氧量(COD)等的影响,并从微观结构上对形貌变化进行分析。结果表明:双氧水活性室温冷堆比碱氧冷堆时间可缩短4 h,温度比高温碱氧降低60 ℃,且白度比高温碱氧仅减少0.41%,残余液pH值与泡沫高度满足要求,COD值比高温碱氧处理仅高出104 mg/L;在一定程度上冷堆脱漂工艺可代替高温碱氧处理工艺,具有低碳节能的优点。

关键词: 棉水刺非织造布, 脱漂, 冷堆, 绿色低碳, 双氧水活化剂

Abstract:

As a bid to achieve the carbon neutrality and carbon emission peak in the textile industry, the influence of weight loss, water absorption, whiteness, residual pH value and COD value ws investigated by analysing alkali oxygen concentration, cold pad-batch time, hydrogen peroxide activator concentration, different treatment methods, as well as the microstructure of cotton spunlaced nonwoven fabrics. The results showed that the production cycle of hydrogen peroxide activator cold pad-batch was 4 h shorter than that of alkali oxygen cold pad-batch, and in addition the temperature was 60 ℃ lower than high temperature alkali oxygen process and whiteness was only decreased by 0.41%. The COD value increased by only 104 mg/L, with both the residual pH value and foam height meeting the requirements. Cold pad-batch bleaching technique with the advantages of low carbon and energy saving demonstrated great potential for replacing the high-temperature alkaline oxygen treatment process.

Key words: cotton spunlaced nonwoven, degreasing and bleaching, cold pad-batch, green and low-carbon, hydrogen peroxide activator

中图分类号: 

  • TS174.8

表1

各类别样品工艺参数"

样品编号 处理方式 质量浓度配比 处理条件
A1 未脱漂
A2 高温碱氧 4:6:2:0:0 90 ℃,1 h
A3 碱氧冷堆 4:6:2:0:0 30 ℃,12 h
A4 复合酶冷堆 0:0:2:0:5 30 ℃,8 h
A5 双氧水活性冷堆 4:6:2:2:0 30 ℃,8 h

图1

全棉水刺非织造布的电镜照片"

图2

全棉水刺非织造布的红外光谱"

图3

各因素对质量变化率与吸水量影响"

图4

各因素对白度影响"

表2

各类别节能减排效果及样品性能对比表"

样品
编号
COD值/
(mg·L-1)
残余液
pH值
泡沫高
度/mm
残余双氧
水含量/
(mg·L-1)
透气率/
(mm·s-1)
强力/
N
断裂伸
长率/%
A1 2 517 27.5 49.9
A2 2 540 9.11 6 2.04 2 869 21.1 59.1
A3 2 235 7.54 0.8 1.36 2 778 22.9 57.7
A4 853 7.3 1 0 2 808 18.2 68.1
A5 2 644 7.32 1.6 3.4 2 726 19.7 64.9

表3

各工艺参数下节能减排效果表"

质量浓度/(g·L-1) 处理时
间/h
残余液
pH值
泡沫高
度/mm
残余双氧水质量
浓度/(mg·L-1)
NaOH H2O2
4 6 8 7.32 2.0 2.04
6 6 8 8.23 0.8 2.38
4 6 12 7.31 1.6 1.70
6 6 12 8.04 0.5 1.70
4 8 8 7.15 0.4 1.02
4 8 12 7 2.0 1.36

图5

各因素对残余液pH值与双氧水含量影响"

图6

各类别雷达图"

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