纺织学报 ›› 2023, Vol. 44 ›› Issue (11): 120-131.doi: 10.13475/j.fzxb.20220907501

• 染整与化学品 • 上一篇    下一篇

天然染料质谱数据库的建立与应用

寿晨超1, 娜仁高娃2, 高素芸1, 刘剑1,3, 赵丰1,3()   

  1. 1.浙江理工大学 纺织科学与工程学院(国际丝绸学院), 浙江 杭州 310018
    2.巴音郭楞蒙古自治州博物馆,新疆 库尔勒市 841001
    3.中国丝绸博物馆 纺织品文物保护国家文物局重点科研基地, 浙江 杭州 310012
  • 收稿日期:2022-09-29 修回日期:2023-04-06 出版日期:2023-11-15 发布日期:2023-12-25
  • 通讯作者: 赵丰(1961—),男,研究员,博士。主要研究方向为纺织科技史与染织艺术史。E-mail: zhaofeng@dhu.edu.cn。
  • 作者简介:寿晨超(1998—),男,硕士。主要研究方向为天然染料质谱数据库。
  • 基金资助:
    国家重点研发计划项目(2019YFC1520302)

Establishment and application of mass spectral database for natural dyes

SHOU Chenchao1, NARENGGAOWA 2, GAO Suyun1, LIU Jian1,3, ZHAO Feng1,3()   

  1. 1. College of Textile Science and Engineering(International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Museum of Bayinguoleng Mongol Autonomous Prefecture, Korla, Xinjiang 841001, China
    3. Key Research Base for Textile Conservation, State Administration for Culture Heritage, China National Silk Museum, Hangzhou, Zhejiang 310012, China
  • Received:2022-09-29 Revised:2023-04-06 Published:2023-11-15 Online:2023-12-25

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摘要：

为提高纺织品文物中天然染料鉴定的准确性和便捷性,利用高效液相色谱-质谱联用(HPLC-MS)技术对68种天然染料化合物标准品进行分析,收集化合物分子质量、碎片离子及丰度、检测离子模式、保留时间等信息,建立了基于美国国家标准技术研究院质谱数据库的天然染料质谱数据库。通过设置合理的检索条件,确定质谱库检索最佳参数,对代表性蒽醌类(茜素)、黄酮类(槲皮素、木犀草素)、生物碱类(小檗碱)化合物进行了分子碎裂机制解析。应用自建的质谱数据库成功实现了2件古代纺织品文物中天然染料的快速鉴定,质谱数据库检索结果显示其含有茜素、茜紫素、木犀草素、小檗碱、巴马汀等染料化合物,且在文物样品的检索过程中,质谱数据库正向检索匹配度与反向检索匹配度均大于800,匹配率均在95%以上。利用质谱数据库检索技术鉴定天然染料具有可行性,为纺织品文物中天然染料的研究工作提供了新思路。

关键词: 质谱检索, 天然染料, 高效液相色谱-质谱联用技术, 美国国家标准技术研究院质谱数据库, 多级质谱

Abstract:

Objective There are different types of natural dyes, including indoles, anthraquinones, naphthoquinones, flavonoids, alkaloids, curcumins, and so on. Facing a large number of textile culture relics, it is impossible to identify quickly the dye compounds only by manual identification using spectral or chromatographic analysis techniques. This research aims to establish a mass spectral database of natural dyes. Using the retrieval technology of the mass spectrum database, the components of natural dyes in textile cultural relics would be identified quickly, bringing efficiency and convenience for the identification of natural dyes in the future.

Method In this study, standard natural dye compounds were analyzed by high performance liquid chromatography-mass spectrometry (HPLC-MS), and mass spectrum data were collected. The natural dye mass spectral database was established using National Institute of Standards and Technology (NIST) spectral database software. The search parameters of the software were optimized to achieve the best search results. By comparing the relative peak strength and mass of the unknown mass spectrum with the standard mass spectrum in the database, the similarity between them was identified, and the search result was finally determined.

Results Samples of the natural dyes were analyzed by HPLC-MS to obtain their total ion chromatogram data (Tab. 1). The appropriate chromatographic peak was selected using Thermo Xcalibur Qual Browser software (Fig. 1), the MS/MS spectra of natural dye compounds were exported to NIST MS Search 2.3 software before entering the information of the compounds such as name, formula, molecular weight, synonyms, detection ion mode, retention time, and chemical structure into the self-built mass spectral database. The above operations were repeated until the mass spectral database was established. In order to identify the molecular structure of dye compounds, it is necessary to analyze the mechanism of MS/MS fragmentation. Fragmentation pathways of alizarin, quercetin and luteolin were analyzed, and the derivation of ion information of dye molecular fragments and molecular fragmentation pathway in secondary mass spectral provided an important reference for the identification of natural dye compounds. Using the self-built mass spectrum database, some natural dyes from two textile cultural relics were quickly and accurately identified and the plant origins of the dyes were inferred. In the dye identification of the tricolor sachet, the search result of the mass spectral database showed that the red silk thread contained alizarin and purpurin (Fig. 10), which could be inferred as madder dyeing. The yellow silk thread contained jatrorrhizine and berberine (Fig. 11), and it was inferred as barberry dyeing. In the dye identification of the silk with striped and floral design, the search results of the mass spectral database showed that the yellow silk thread contained luteolin and apigenin (Fig. 12), which was identified as weld dyeing. In addition, in the retrieval process of cultural relics, the match and reverse match scores were both greater than 800, and the matching probability was more than 95%, which was a high score and could substantially confirm the existence of substances.

Conclusion The establishment of natural dye mass spectral database can not only shorten the time of dye molecular structure analysis, facilitate fast and accurate identification of dyes in textile cultural relics, but can also reduce the dependence on standard products in dye analysis and reduce the operating cost of the laboratory. This study proved the feasibility and potential of the application of the mass spectral database retrieval technology to the identification of natural dyes and provided a new idea for the follow-up research of natural dyes.

Key words: mass spectrometry search, natural dye, high performance liquid chromatography-mass spectrometry, National Institute of Standards and Technology mass spectrometry database, multi-stage mass spectrometry

中图分类号: 

  • TS193.1

表1

主要天然染料化合物标准品列表"

类别 代表成分(规格)
蒽醌类 大黄素(≥98%),茜素(≥95%),茜紫素(≥95%),胭脂红酸(≥90%),虫胶酸(≥90%)
生物碱类 盐酸巴马汀(≥98%),盐酸药根碱(≥98%),盐酸小檗碱(≥98%)
黄酮类 芦丁(≥98%),槲皮素(≥98%),山奈酚(≥98%),漆黄素(≥98%),芹菜素(≥98%),杨梅素(≥98%),木犀草素(≥98%),香叶木素(≥90%),金圣草素(≥90%),桑色素(≥90%),鼠李素(≥90%),荭草素(≥97%),牡荆黄素(≥90%)
吲哚类 靛玉红(≥95%),靛蓝(>95%),靛红(≥90%)
酚类 苏木精(≥90%),儿茶素(≥98%),没食子酸(≥98%),原儿茶酸(≥99%),姜黄素(≥90%)
查尔酮类 紫铆因(≥90%),硫黄菊素(≥90%),红花黄色素(≥90%)

表2

天然染料质谱数据库的相关数据"

序号 化合物名称 保留
时间/min		 分子式 准分子离子
m/z及检测模式		 二级碎片
离子m/z		 三级碎片
离子m/z
1 胭脂红酸(Carmine) 6.78 C22H20O13 491([M-H]-) 447,357,448
2 大黄素(Emodin) 15.66 C15H10O5 269([M-H]-) 225,241,269
3 茜素(Alizarin) 13.30 C14H8O4 239([M-H]-) 211,239,167
4 茜紫素(Purpurin) 14.64 C14H8O5 254([M-H]-) 227,228,183
5 虫胶红酸A(Laccaic acid A) 9.09 C26H19NO12 536([M-H]-) 492 448,430,474
6 虫胶红酸B(Laccaic acid B) 9.09 C24H16O12 495([M-H]-) 451 407,389,433
7 虫胶红酸C(Laccaic acid C) 9.09 C25H17NO13 538([M-H]-) 494 450,449,448
8 虫胶红酸D(Laccaic acid D) 11.02 C16H10O7 313([M-H]-) 269 225,241,201
9 虫胶红酸E(Laccaic acid E) 9.09 C24H17NO11 494([M-H]-) 450 406,405,389
10 对羟基苯甲酸 (4-Hydroxybenzoic acid) 4.69 C7H6O3 137([M-H]-) 93,109
11 苏木精(Hematoxylin) 7.08 C16H14O6 303([M-H]-) 259,229,257
12 儿茶素(Catechin) 4.39 C15H14O6 289([M-H]-) 245,205,179
13 鞣花酸(Ellagic acid) 7.76 C14H6O8 301([M-H]-) 257,229,185
14 2,4-二羟基苯甲酸(2,4-Dihydroxybenzoic acid) 3.19 C7H6O4 153([M-H]-) 109
15 原儿茶酸(Protocatechuic acid) 6.09 C7H6O4 153([M-H]-) 109 65,67
16 儿茶酚(Catechol ) 5.20 C6H6O2 109([M-H]-) 63,99
17 没食子酸(Gallic acid) 8.01 C7H6O5 169([M-H]-) 81,97,69
18 芦丁(Rutin) 8.24 C27H30O16 609([M-H]-) 301,300,343
19 莰菲醇-3-O-芸香糖苷(Kaempferol-3-O-rutinoside) 7.95 C27H30O15 593([M-H]-) 285 257,267,229
20 莰菲醇-7-O-葡萄糖苷(Kaempferol 7-O-glucopyranoside) 9.11 C21H20O11 447([M-H]-) 285 257,267,229
21 牡荆素鼠李糖苷(Vitexin-2-O-rhamnoside) 7.86 C27H30O14 577([M-H]-) 413,293,457
22 异鼠李素-3-O-葡萄糖苷(Isorhamnetin 3-O-glucoside) 8.89 C22H22O12 477([M-H]-) 314,315,357
23 杨梅酮 4'-甲醚-3-O-鼠李糖苷(Mearnsitrin) 8.31 C22H22O12 477([M-H]-) 331,315,330
24 槲皮素3-O-葡萄糖酸苷(Quercetin 3-O-glucuronide) 7.70 C21H18O12 477([M-H]-) 301 179,151,273
25 异懈皮苷(Isoquercetin) 7.92 C21H20O12 463([M-H]-) 301,300,343 179,151,273
26 槲皮素-7-O-葡萄糖苷(Quercimeritrin) 7.67 C21H20O12 463([M-H]-) 301 151,179,255
27 木犀草素-3-O-葡萄糖醛酸苷(Luteolin-3-O-glucuronide) 9.03 C21H18O12 461([M-H]-) 285 241,175,199
28 木犀草素-7-O-葡萄糖醛酸苷(Luteolin 7-O-glucosiduronic acid) 7.89 C21H18O12 461([M-H]-) 285 241,175,199
29 木犀草苷(Cynaroside) 7.74 C21H20O11 447([M-H]-) 285 241,175,199
30 木犀草素-5-O-葡萄糖苷(Luteollin 5-O-glucoside) 7.35 C21H20O11 447([M-H]-) 285,327 241,175,199
31 槲皮素-7-O-鼠李糖苷(Vincetoxicoside B) 9.36 C21H20O11 447([M-H]-) 301 179,151,273
32 荭草素(Orientin) 7.16 C21H20O11 447([M-H]-) 327,357,369
33 槲皮苷(Quercitrin) 8.52 C21H20O11 447([M-H]-) 301 179,151,273
34 芹菜素-7-O-葡萄糖醛酸苷(Apigenin 7-O-glucuronide) 8.58 C21H18O11 445([M-H]-) 269,175 225,149,201
35 异牡荆黄素(Isovitexin) 7.47 C21H20O10 431([M-H]-) 311,341,413
36 牡荆素(Vitexin) 7.43 C21H20O10 431([M-H]-) 311,341 283
37 3-甲基鼠李素(Rhamnazin) 14.41 C17H14O7 329([M-H]-) 316,299,317
38 杨梅黄酮(Myricetin) 9.01 C15H10O8 478([M-H]-) 179,151,192
39 鼠李素(Rhamnetin) 12.89 C16H12O7 315([M-H]-) 165,193,300
40 异鼠李素(Isorhamnetin) 11.76 C16H12O7 315([M-H]-) 300,301
41 槲皮素(Quercetin) 10.81 C15H10O7 301([M-H]-) 179,151,273
42 桑色素(Morin) 10.07 C15H10O7 301([M-H]-) 151,229,125
43 香叶木素(Diosmetin) 11.62 C16H12O6 299([M-H]-) 284,285 256,284
44 金圣草(黄)素(Chrysoeriol) 11.77 C16H12O6 299([M-H]-) 284 256,284
45 木犀草素(Luteolin) 10.46 C15H10O6 285([M-H]-) 241,175,199
46 漆黄素(Fisetin) 9.58 C15H10O6 285([M-H]-) 163,135,257
47 莰菲醇(Kaempferol) 11.94 C15H10O6 285([M-H]-) 285,229,151
48 芹菜素(Apigenin) 11.33 C15H10O5 269([M-H]-) 225,201,181
49 金雀异黄酮(Genistein) 11.61 C15H10O5 269([M-H]-) 225,269,201
50 槲皮素(二水)(Quercetin dihydrate) 10.90 C15H14O9 337([M-H]-) 179,151,273
51 异荭草素(Isoorientin) 6.65 C21H20O11 447([M-H]-) 327,357,429
52 巴马汀(Palmatine) 8.77 C21H22NO4 353([M+H]+) 327,336,308
53 药根碱(Jatrorrhizine) 8.36 C20H20NO4 339([M+H]+) 323,322,294
54 小檗碱 (Berberine) 8.81 C20H18NO4 337([M+H]+) 321,320,308
55 靛玉红(Indirubin) 12.97 C16H10N2O2 263([M+H]+) 219,235,263
56 靛蓝(Indigo) 12.33 C16H10N2O2 263([M+H]+) 219,235,263
57 靛红(Isatin) 7.15 C8H5NO2 148([M+H]+) 130,120,92
58 紫草素 (Shikonin) 15.80 C16H16O5 287([M-H]-) 218,267,190
59 2-羟基-1,4-二萘醌(Lawsone) 9.80 C10H6O3 173([M-H]-) 145,155,173
60 红花红色素(Carthamin) 12.66 C43H42O22 909([M-H]-) 501,287,407
61 紫铆因(Butein) 8.91 C15H12O5 271([M-H]-) 135,253,153
62 硫黄菊素(Sulfuretin) 10.06 C15H10O5 269([M-H]-) 225,227,133
63 胭脂酮酸(Kermesic acid) 11.21 C16H10O8 329([M-H]-) 285 257,241,213
64 二脱甲氧基姜黄素
(Bisdemethoxycurcumin)		 14.23 C19H16O4 309([M+H]+) 225,147,189
65 去甲氧基姜黄素
(Demethoxycurcumin)		 14.49 C20H18O5 339([M+H]+) 255,245,175
66 胡桃醌(Juglone) 10.83 C10H6O3 173([M-H]-) 144,163,119
67 姜黄素(Curcumin) 14.64 C21H20O6 369([M+H]+) 217,173,347
68 氧化巴西红木素(Brazilein) 7.95 C16H12O5 283([M-H]-) 265,240,173

图1

标准品的质谱数据采集过程"

图2

质谱数据库存储结构"

图3

茜素裂解规律"

图4

茜素的二级质谱图"

图5

槲皮素裂解规律"

图6

槲皮素的二级质谱图"

图7

木犀草素裂解规律"

图8

木犀草素的二级质谱图"

图9

小檗碱裂解规律及二级质谱图"

图10

巴州红黄蓝三色香囊中红色丝线文物样品鉴定结果 注:图(c)、(d)中横坐标为质荷比,纵坐标为相对丰度。"

图11

巴州红黄蓝三色香囊中黄色丝线文物样品鉴定结果 注:图(c)、(d)中横坐标为质荷比,纵坐标为相对丰度。"

图12

彩条花卉纹提花缎中黄色丝线文物样品鉴定结果 注:图(c)、(d)中横坐标为质荷比,纵坐标为相对丰度。"

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