纺织学报 ›› 2005, Vol. 26 ›› Issue (1): 73-75.

• 生产技术 • 上一篇    下一篇

加成法合成氨基硅油

郑帼,刘燕军,葛启   

  1. 天津工业大学精细化工研究所 天津300160
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2005-02-15 发布日期:2005-02-15

Preparation of amino-silicone by hydrosilyation reaction

ZHENG Guo;LIU Yan-jun;GE Qi   

  1. Fine-Chemical Institute;Tianjin Polytechnic University;Tianjin 300 160;China
  • Received:1900-01-01 Revised:1900-01-01 Online:2005-02-15 Published:2005-02-15

摘要: 以H2 PtCl6 为催化剂 ,以丙烯胺与含氢硅油加成 ,合成了氨值在 0.8~1.5的侧基型氨基硅油 ,并且在硅油分子中引入了烷氧基。最佳的反应条件是以甲苯为溶剂 ,催化剂用量 0.2mmol g,回流条件下在 2h内滴加丙烯胺 ,继续保温 2~3h ,然后在 30min内加入正丙醇 ,继续反应 90min。

Abstract: The amino-silicone was prepared by hydrosilylation of hydrogen-silicone with a llyl amino.The amino-value of the amino-sili cone is 0.8~1.5, and then inserted the alkoxy group into the structure to imp rove the crosslink ability.The optimal reactive condition was the toluene as sol vent,H2PtCl6 catalyst content 0.2 mmol/g and added the allyl amino to hyd rogen-silicone dropwise within 2 hours under reflux.Kept the temperature to r ea ct 2~3 h,then added n-propanol containing KOH in 30 minutes and reacted 90 m inutes to gain amino-silicone containing alkoxy group.

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