纺织学报 ›› 2007, Vol. 28 ›› Issue (11): 5-8.

• 目次 • 上一篇    下一篇

三聚氰胺甲醛纤维纺丝原液的稳定性

杨智渊;猛进;奎林;光斗;李守群;徐建军
  

  1. 四川大学高分子科学与工程学院
  • 收稿日期:2007-01-19 修回日期:2007-04-12 出版日期:2007-11-15 发布日期:2007-11-15
  • 通讯作者: 杨智渊

Stability of spinning solution of melamine formaldehyde f iber

YANG Zhiyuan; IANGMengjin;U Kuilin;E Guangdou;I Shouqun;XU jianjun   

  • Received:2007-01-19 Revised:2007-04-12 Online:2007-11-15 Published:2007-11-15
  • Contact: YANG Zhiyuan

摘要: 采用湿法纺丝制备三聚氰胺甲醛纤维的关键在于获得稳定的纺丝原液。先合成低黏度水溶性的三聚氰胺甲醛预聚体(MF) ,再与聚乙烯醇(PVA) 溶液混合,制得纺丝原液。研究了预聚体溶液及三聚氰胺(M) 甲醛(F)PPVA 复合纺丝溶液的稳定性,探讨了纺丝原液的黏度稳定性与预聚体结构之间的关系。结果表明:水溶性MF 树脂合成的2 个阶段中,树脂的结构对原液稳定性有影响;同时,原液的混合状态和结构、混合温度、混合比例等对原液
稳定性也有较大影响。

Abstract:

 The key factor of preparing melamine formaldehyde fiber is obtaining stable spinning solution. A
two step procedure was used to prepare the spinning solution. The first step was to synthesize the lower
viscosity and water2soluble melamine formaldehyde (MF) resins and the second one was to mix the resins with
PVA solution. The viscosity′s stability of MF′s solution and the spinning solution of MFPPVA was investigated.
Results show that resin′s structure at different polymerization phase has an effect on the stability of the spinning
solution. At the meantime , the mixture status , mixing temperature , ratio of MF to PVA , and storage time ,
also had an influence on the stability of spinning solution

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