纺织学报 ›› 2009, Vol. 30 ›› Issue (06): 80-85.

• 染整与化学品 • 上一篇    下一篇

紫外线吸收剂对涤纶的上染及其紫外吸收性能

陈维国;戴瑾瑾;汪智勇;孟照成;崔志华   

  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2009-06-15 发布日期:2009-06-15

Investigation on uptake of UV-absorber onto polyester fabric and its UV absorption properties

CHEN Weiguo; DAI Jinjin; WANG Zhiyong; MENG Zhaocheng; CUI Zhihua   

  • Received:1900-01-01 Revised:1900-01-01 Online:2009-06-15 Published:2009-06-15

摘要: 为研究紫外线吸收剂对改善涤纶织物吸收紫外线性能的影响,将5只苯并三唑类紫外线吸收剂经分散后用高温高压浸染法使其上染到涤纶织物上,以残液法测试紫外线吸收剂对涤纶的上染率,用紫外线透过率表征织物的紫外线吸收性能。结果表明:选用的紫外线吸收剂可以在130℃下保温40~60min上染涤纶织物,紫外线吸收剂结构、分子质量、上染温度和用量都会影响其对涤纶的上染率,分子质量适中、芳环较多、疏水性基团比例较高的紫外线吸收剂对涤纶的上染率较高;上染率较高的紫外线吸收剂能更明显地改善涤纶织物的紫外线吸收性能,上染率不够高但分子中含有2个分子内氢键螯合环的紫外线吸收剂也能明显提高涤纶织物的紫外吸收能力。

Abstract: In order to investigate the improvement of the UV absorption properties of polyester fabrics with UV-absorbers, 5 UV absorbers with the structure of benzotriazole were dispersed and then applied onto polyester fabrics in high pressure dyeing method. The uptake of the UV-absorbers on polyester fabric and the transmittance of UV radiation through fabrics were measured. The results showed the UV absorbers selected could be taken up onto polyester fabrics by exhaustion dyeing at 130℃ for 40—60min. The uptakes of UV absorbers onto polyester fabrics were influenced by the structure, molecular weight of the UV absorbers, dyeing temperature and amount of UV absorbers applied as well. The UV absorbers with suitable molecular weight more aromatic groups and greater ratio of hydrophobic group in molecule could have greater uptakes. The UV absorbers with greater uptakes could improve the UV absorption properties more significantly. The UV absorber which had lower uptake but with double chelation ring of hydrogen bond within the molecule could also improve the UV absorption ability obviously.

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