纺织学报 ›› 2010, Vol. 31 ›› Issue (4): 1-6.

• 纤维材料 •    下一篇

碳纤维负载TiO2光催化薄膜的制备及其性能

朱曜峰;丁艳杰;傅雅琴   

  1. 浙江理工大学先进纺织材料与制备技术教育部重点实验室
  • 收稿日期:2009-04-13 修回日期:2009-06-07 出版日期:2010-04-15 发布日期:2010-04-15
  • 通讯作者: 傅雅琴

Preparation and performances of photocatalysed titanium dioxide thin film deposited on polyacrylonitile based carbon fiber

Yaofeng Zhu;Yanjie Ding;FU Ya-Qin   

  1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University
  • Received:2009-04-13 Revised:2009-06-07 Online:2010-04-15 Published:2010-04-15
  • Contact: FU Ya-Qin

摘要:

以PAN基碳纤维(CF)为基体,钛酸丁酯为前驱体,通过溶胶-凝胶浸渍涂覆法将TiO2负载于经过表面修饰的CF上,制备CF负载的TiO2光催化薄膜。采用扫描电子显微镜(SEM)和X射线衍射仪(XRD)表征了制备材料的形态结构,通过超声震荡清洗测试了CF对TiO2的负载牢度,以质量浓度为80 mg/L的酸性橙Ⅱ溶液为目标降解物,测试了材料在紫外线光照下的催化性能。结果表明:溶胶浓度影响制备材料的形态结构、CF对TiO2的负载率及负载牢度;溶胶浓度和退火温度对制备材料的催化活性有明显的影响。Ti浓度为0.5 mol/L的溶胶制备的TiO2/CF负载牢度好,负载率高,催化活性好。

Abstract:

Photocatalysed titanium dioxide (TiO2) thin film was prepared and deposited on polyacrylonitile based carbon fiber (PAN-CF) substrates with tetrabutyl titanate as precursor through a facile sol-gel dip coating technique. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were utilized to investigate the morphologies and structures of the photocatalysed TiO2/CF film. The load fastness of TiO2 on CF was evaluated by ultrasonic vibration method and the photocatalytic properties of TiO2/CF film were investigated by degrading acid orange Ⅱ (80mg/L) under UV irradiation. The results suggest that the concentration of the sol have significant effects on the morphologies and structures of TiO2/CF film, the load rate of TiO2 and load fastness. It is also shown that the catalytic activity of TiO2/CF film was remarkably influenced by concentrations of the sol and annealing temperature. As the results indicated, the TiO2/CF prepared from the Ti sol with concentration of 0.5 mol/L displayed better load fastness, higher load rate and excellent catalytic performance.

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