纺织学报 ›› 2010, Vol. 31 ›› Issue (6): 76-80.

• 染整与化学品 • 上一篇    下一篇

氨基硅与羧基硅超分子膜形貌及其应用性能

王科峰; 安秋凤; 黄良仙; 王前进   

  1. 教育部轻化工助剂化学与技术重点实验室 陕西科技大学
  • 收稿日期:2009-07-15 修回日期:2009-09-28 出版日期:2010-06-15 发布日期:2010-06-15
  • 通讯作者: 安秋凤

Morphology of supramolecular film of amino polysiloxane and carboxyl polysiloxane and its application properties

WANG Kefeng; AN Qiufeng; HUANG Liang-xian; WANG Qianjin   

  1. Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology
  • Received:2009-07-15 Revised:2009-09-28 Online:2010-06-15 Published:2010-06-15
  • Contact: AN Qiufeng

摘要:

以N-β-氨乙基-γ-氨丙基聚二甲基硅氧烷(ASO-1)和羧烃基聚硅氧烷(CAS-2)作为构筑基元,获得了单晶硅表面的ASO-1/CAS-2超分子膜,用原子力显微镜(AFM)等仪器研究了超分子膜形貌及应用性能。结果表明, 氨基硅和羧基硅超分子膜(ASO-1/CAS-2)明显呈规则有序的窗棂状形貌。应用性能测试结果表明,随着ASO-1比例的增加,织物的柔软性不断提高,但是织物的白度和吸湿性却降低。当ASO-1与CAS-2质量比为1∶1时,所得的织物的柔软性最好且具有独特的油润手感。基于不同黏度ASO-1所构筑的超分子ASO-1/CAS-2整理织物其白度及吸湿性差别不大,但柔软性却随ASO-1黏度的增大而提高。

Abstract:

Using N-β-aminoethyl-γ-aminopropyl polysiloxane (ASO-1) and carboxyl groups containing polysiloxane (CAS-2) as architecture units, a self-assembled supramolecular film of ASO-1/CAS-2 on the monocrystalline silicon was prepared. Its morphology and the application properties were investigated by atomic force microscope (AFM) and other instruments. Experimental results showed that the supramolecular film (ASO-1/CAS-2) showed a highly ordered, window grating-like structure. The application test indicated that when the proportion of ASO-1 increased, the softeness of the treated fabric was improved, while the whiteness and the water absorption decreased. When the ratio of ASO-1 to CAS-2 was 1∶1, the treated fabric exhibited the best softness and unique silky hand. In addition, the fabrics treated by the supramolecular ASO-1/CAS-2 based on various viscosity of ASO-1 showed almost the same whiteness and water absorption. However, the softenss was improved as the viscosity of ASO-1 increased.

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