纺织学报 ›› 2011, Vol. 32 ›› Issue (3): 25-29.

• 纤维材料 • 上一篇    下一篇

芳纶/醋酸纤维素纳米纤维的制备及表征

姚理荣1; 张伟2; 周琪3   

  1. 1. 南通大学纺织服装学院 2. 盐城工学院纺织服装学院 3. 杭州聚光科技有限公司
  • 收稿日期:2010-03-04 修回日期:2010-06-19 出版日期:2011-03-15 发布日期:2011-03-15
  • 通讯作者: 张伟

Preparation and characterization of meta-aramid/ cellulose acetate nanofibers

YAO Lirong1; ZHANH Wei2; ZHOU Qi3

  

  1. 1. School of Textile and Clothing, Nantong University 2. School of Textile and Clothing, Yancheng Institute of Technology 3. Hangzhou JuGuang Science and Technology company Ltd.
  • Received:2010-03-04 Revised:2010-06-19 Online:2011-03-15 Published:2011-03-15
  • Contact: ZHANG Wei

摘要:

醋酸纤维素在N,N-二甲基甲酰胺(DMAc)中难以进行静电纺丝,将其与芳纶溶液混合后成功制备了芳纶/醋酸纤维素纳米纤维。芳纶/醋酸纤维素混合溶液有利于静电纺丝,当芳纶/醋酸纤维质量比大于1:2后即可获得均匀的纳米纤维。随混合溶液中芳纶/醋酸纤维素的质量比和溶液质量分数的提高,纳米纤维中的珠状缺陷逐渐减少。芳纶/醋酸纤维素纳米纤维的热稳定性较纳米芳纶明显提高。纳米芳纶在150℃附近存在一个热失重过程,而芳纶/醋酸纤维素纳米纤维在这一阶段的热失重温度升至250℃左右。

Abstract:

The cellulose acetate/ DMAc solution is unable to be electrospun into ultra fine fiber. However, the cellulose acetate/meta-aramid solution with a mass ratio 1:2 can be successfully electrospun into uniform nanofibers. The beads on the nanofibers decreased gradually as the mass ratio of cellulose acetate/meta-aramid in the solution and the mass concentration of the solution increased. The thermal property of cellulose acetate/meta-aramid nanofibers improved significantly as compared with aramid nanofibers, and the thermal loss process of aramid nanofibers occurred at around 150℃, whereas it occurred at 250℃ for cellulose acetate/meta-aramid nanofibers.

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