纺织学报 ›› 2014, Vol. 35 ›› Issue (1): 82-0.

• 染整与化学品 • 上一篇    下一篇

蚕丝和棉及锦纶织物对儿茶素的选择性吸附和媒染效应

钱红飞1,2,钱军2,3,施舒雯1,2   

    1. 绍兴文理学院纺织服装学院
    2. 浙江省清洁染整技术研究重点实验室
    3. 浙江富利达丝绸印染有限公司
  • 收稿日期:2013-02-01 修回日期:2013-07-20 出版日期:2014-01-15 发布日期:2014-01-15
  • 通讯作者: 钱红飞 E-mail:qhf@usx.edu.cn
  • 基金资助:

    浙江省自然科学基金项目

Selective adsorption of catechins on silk, cotton and polyamide fabric and their mordanting effect

  • Received:2013-02-01 Revised:2013-07-20 Online:2014-01-15 Published:2014-01-15

摘要: 为了深入了解各类织物对茶多酚中各儿茶素的吸附情况,比较其媒染效应,采用高效液相色谱仪,在两个不同茶多酚起始浓度下,分别测定了蚕丝、棉和尼龙织物对茶多酚中六种不同儿茶素的吸附率,并用硫酸亚铁、硫酸铜和明矾三种媒染剂进行媒染。结果表明,蚕丝、棉、尼龙三种不同织物对茶多酚的吸附能力有较大差异,尼龙的吸附能力最强,其次是蚕丝,而棉织物为最小。尼龙与蚕丝对酯类儿茶素显示较高的吸附率,而棉织物对非酯类儿茶素显示较高的吸附率。各类织物对EGCG的吸附量最大。三种不同媒染剂的媒染效果有较大不同,在相同的工艺条件下,亚铁盐获得较深的颜色,而铜盐得色较浅,明矾最浅。蚕丝与棉拥有相近的色相,尼龙色相存在较大的差异。相比较而言,尼龙得色较蚕丝、棉织物浅。

关键词: 儿茶素, 蚕丝, 棉, 锦纶, 吸附, 媒染

Abstract: In order to understand deeply the adsorption of chtechins on various kinds of fabric and compare their mordanting effects, the adsorption percentage of six types of catechins on silk, cotton and nylon fabric were measured respectively by using the high-performance liquid chromatography under two different initial concentration of tea polyphenol, and the mordanting was carried on with ferrous sulfate, copper sulfate and potassium aluminum sulfate as mordants. The results indicated that there was a greater difference in adsorption capacity of tea polyphenols onto Silk,cotton,nylon fabric. Nylon has the maximum adsorption capacity,followed by silk and cotton fabrics for the minimum. The ester catechins showed higher adsorption on nylon and silk,while the cotton fabric adsorb preferentially non-ester catechins. For each of the three fibers, the adsorption capacity of EGCG was the maximum among the six types of catechins. The effect of three mordants was quite different with each other. Under the same processing conditions, the ferrous salt showed a dark color, copper salt gave a light color,and alum was the most pale. Silk had a similar hue with cotton for every mordant,but difference with nylon. In comparison, the color of nylon was lighter than ether that of silk or cotton fabric.

Key words: catechins, silk, cotton, polyamide, adsorption, mordanting

中图分类号: 

  • TS 193. 6
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