纺织学报 ›› 2019, Vol. 40 ›› Issue (03): 102-108.doi: 10.13475/j.fzxb.20180300807

• 染整与化学品 • 上一篇    下一篇

丙烯酸酯-有机硅/有机颜料亚微胶囊在涂料印花中的应用

陈智杰1, 周鹏1, 杜春晓1, 金黔宏2, 戚栋明1, 向忠3()   

  1. 1.浙江理工大学 先进纺织材料与制备技术教育部重点实验室, 浙江 杭州 310018
    2.义乌市中力工贸有限公司,浙江 义乌 322007
    3.浙江省现代纺织装备技术重点实验室, 浙江 杭州 310018
  • 收稿日期:2018-03-01 修回日期:2018-12-04 出版日期:2019-03-15 发布日期:2019-03-15
  • 通讯作者: 向忠
  • 作者简介:陈智杰(1989—),男,博士。主要研究方向为颜料胶囊制备及成膜研究。
  • 基金资助:
    国家自然科学基金联合基金项目(U1609205);浙江省自然科学基金重点项目(LZ18E030002);浙江理工大学科研启动基金(18022114-Y);义乌市科技攻关项目(2017-z-03);浙江省新苗人才计划(2017R406048)

Application of acrylate-silicone/organic pigment submicron capsules in pigment printing

CHEN Zhijie1, ZHOU Peng1, DU Chunxiao1, JIN Qianhong2, QI Dongming1, XIANG Zhong3()   

  1. 1. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, China
    2. Yiwu Zhongli Industry and Trade Co., Ltd., Yiwu, Zhejiang 322007, China
    3. Key Laboratory of Modern Textile Equipment Technology in Zhejiang Province, Hangzhou, Zhejiang 310018, China
  • Received:2018-03-01 Revised:2018-12-04 Online:2019-03-15 Published:2019-03-15
  • Contact: XIANG Zhong

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摘要：

为进一步提高颜料亚微胶囊涂料印花织物的手感、透气性等服用性能,通过原位细乳液共聚合将端乙烯基聚二甲基硅氧烷(ViPDMS)引入聚丙烯酸酯(PAcr)胶囊壁材中,制得颜料亚微胶囊P(DMS-Acr)/PB;再将其用于织物涂料印花,并对印花织物的透气性、硬挺度、耐干湿摩擦牢度、K/S值等进行测试比较。结果表明:当ViPDMS质量分数为30%时,可制得平均粒径为318 nm、放置均匀稳定的深色胶乳;P(DMS-Acr)/PB印花织物的耐干湿摩擦牢度和K/S值与PAcr/PB印花织物相近,但透气性更好,手感更柔软;在亚微胶囊壁材中引入高柔顺性的有机硅组分,可增强焙烘过程中织物表面涂层的黏流分相能力。

关键词: 有机颜料, 胶囊, 端乙烯基聚二甲基硅氧烷, 涂料印花, 透气性

Abstract:

In order to further improve the handle feeling, permeability and other performance of the fabric printed by the organic pigment submicron capsules, vinyl-terminated polydimethylsiloxane (ViPDMS) was co-polymerized with acrylic monomer (Acr) by miniemulsion polymerization, and a series of P(DMS-Acr)/PB submicron capsules were prepared. Then the P(DMS-Acr)/PB submicron capsules with high viscous flowability were used for the pigment printing of polyester plain weave fabric, and the air permeability, stiffness, dry and wet rubbing fastness and K/S values of the printed fabric were tested and compared. The results show that when the mass fraction of ViPDMS is 30%, a uniform and stable dark latex with an average particle size of 318 nm can be obtained. The K/S values and the dry and wet rubbing fastness of the fabric printed by the P(DMS-Acr)/PB submicron capsules are similar with these of the PAcr/PB printed fabric, while the air permeability and the fabric stiffness are much better than the later. It is considered that the introduction of the silicone composition into the submicron capsule wall material can significantly enhance the viscous flowability and the phase separation capability of the coating on the fabric surface during the baking process.

Key words: organic pigment, capsule, vinyl-terminated polydimethylsiloxane, pigment printing, permeability

中图分类号: 

  • TQ32517

表1

细乳液聚合所制颜料亚微胶囊的配方和粒径大小及其分布"

样品组
编号		 各配方质量/g 平均粒径/
nm		 粒径分布
指数
MMA BA ViPDMS PB HD SDS KPS H2O
1 5.0 5.0 0 0.5 160 0.107
2 4.5 4.5 1 0.5 194 0.154
3 3.5 3.5 3 0.5 0.2 0.5 0.3 88.5 318 0.212
4 2.5 2.5 5 0.5 652 0.523
5 3.5 3.5 3 0 290 0.115

图1

PAcr/PB、P(DMS-Acr)和P(DMS-Acr)/PB胶膜的微观形貌"

图2

亚微胶囊ViPDMS质量分数对所印织物透气率的影响"

图3

不同ViPDMS质量分数亚微胶囊印制织物的SEM照片"

图4

亚微胶囊ViPDMS质量分数对印花织物硬挺度的影响"

图5

不同ViPDMS质量分数亚微胶囊涂料印花织物表面形貌SEM照片"

表2

不同ViPDMS质量分数亚微胶囊印花织物耐干湿摩擦牢度和耐皂洗牢度"

ViPDMS
质量分数/%		 耐皂洗
牢度/级		 耐摩擦牢度/级
干 湿
0 4~5 4~5 4
10 4~5 4 4
30 4~5 4 4
50 4~5 3~4 2~3

图6

不同ViPDMS质量分数的P(DMS-Acr)/PB印花织物的K/S值"

[1] 付少海, 王大同, 杜长森, 等. 提高喷墨印花颜料墨水印花牢度的方法[J]. 纺织学报, 2015,36(2):141-147.
FU Shaohai, WANG Datong, DU Changsen, et al. Improve color fastness of inkjet printing textiles using pigment ink[J]. Journal of Textile Research, 2015,36(2):141-147.
[2] LEE S J, DONG N, HEO M, et al. Most simple preparation of an inkjet printing of silver nanoparticles on fibrous membrane for water purification: technological and commercial application[J]. Journal of Industrial and Engineering Chemistry, 2017,46(2):273-278.
[3] FU S H, DU C S, ZHANG M J, et al. Preparation and properties of polymer-encapsulated phthalocyanine blue pigment via emulsion polymerization[J]. Progress in Organic Coatings, 2012,73(2):149-154.
[4] LI M, ZHANG L P, PENG H Y, et al. Preparation of fluorescent pigment latex and its application on binder-free printing of cotton fabrics[J]. Journal of Applied Polymer Science, 2018,135(6), 45826-45834.
[5] LI M, ZHANG L P, WANG D, et al. Influence of nano-coated pigment ink formulation on ink-jet printability and printing accuracy[J]. Coloration Technology, 2017,133(6):476-484.
[6] 陈智杰, 吴明华, 史鹤鹤, 等. 涂料印染用自黏性有机颜料亚微胶囊的细乳液法制备[J]. 纺织学报, 2017,38(3):91-98.
CHEN Zhijie, WU Minghua, SHI Hehe, et al. Preparation of self-adhesive submicron organic pigment-containing capsules via miniemulsion polymerization for paint coloring[J]. Journal of Textile Research, 2017,38(3):91-98.
[7] 陈智杰, 吴明华, 史鹤鹤, 等. 壳聚糖大分子链的形态调控及其在微悬浮聚合中的分散稳定作用[J]. 高分子学报, 2017,5(5):802-810.
CHEN Zhijie, WU Minghua, SHI Hehe, et al. Conformation regulation of chitosan macromolecular chain and its dispersing and stabilizing effects in micro-suspension polymerization[J]. Acta Polymerica Sinica, 2017,5(5):802-810.
[8] 陈智杰, 申兴丛, 徐杰, 等. 有机颜料微胶囊形态对棉织物涂料印花效果的影响[J]. 纺织学报, 2011,32(8):81-86.
CHEN Zhijie, SHEN Xingcong, XU Jie, et al. Effect of morphology of microcapsulated natural pigmenton printing result of cotton fabrics[J]. Journal of Textile Research, 2011,32(8):81-86.
[9] 孙段冰, 吴明华, 陈权胜, 等. 有机硅交联剂对聚丙烯酸酯性能的影响[J]. 纺织学报, 2014,35(11):95-101.
SUN Duanbing, WU Minghua, CHEN Quansheng, et al. Influence of silicone crosslinking agent on properties of polyacrylate[J]. Journal of Textile Research, 2014,35(11):95-101.
[10] 李强, 吴明华, 孙晓芳, 等. 双端丙烯酰氧基聚醚硅油的制备及其改性聚丙烯酸酯性能[J]. 纺织学报, 2012,33(10):72-78.
LI Qiang, WU Minghua, SUN Xiaofang, et al. Synjournal of double terminated acryloyloxy-polyether silicone oil and peoperty of its modified polyacrylate latex[J]. Journal of Textile Research, 2012,33(10):72-78.
[11] ZHANG Q Y, GALVAN M, MING W H, et al. Synjournal and surface properties of PDMS-containing latexes by emulsion polymerization using AIBN as the initiator[J]. European Polymer Journal, 2013,49(8):2327-2333.
[12] HAO G F, ZHU L Q, YANG W, et al. Investigation on the film surface and bulk properties of fluorine and silicon contained polyacrylate[J]. Progress in Organic Coatings, 2015,85:8-14.
[13] UMAPORN P, YURI R, KATHARINA L, et al. Hoffmann L, et al. Soft core-hard shell silicone hybrid nanoparticles synthesized by miniemulsion polymerization: effect of silicone content and crosslinking on latex film properties[J]. Australian Journal of Chemistry, 2011,64(8):1054-1064.
[14] LIN M T, CHU F X, GUYOT A, et al. Silicone-polyacrylate composite latex particles: particles formation and film properties[J]. Polymer, 2005,46(4):1331-1337.
[15] SHEN J, SUN J W, HU Y, et al. Polysiloxane/polyacrylate composite latexes with balanced mechanical property and breathability: effect of core/shell mass ratio[J]. Journal of Applied Polymer Science, 2017,134(35):958-964.
[16] 樊武厚, 黄玉华, 韩丽娟, 等. 端羟乙基硅油的合成及其在硅丙乳液制备中应用[J]. 纺织学报, 2016,37(2):112-120.
FAN Wuhou, HUANG Yuhua, HAN Lijuan, et al. Synjournal of dihydroxyethyl-terminated polysiloxane and its application in preparation of silicone-acrylate emulsions[J]. Journal of Textile Research, 2016,37(2):112-120.
[17] KHANJANI J, PAZOKIFARD S, ZOHURIAAN M. Improving dirt pickup resistance in waterborne coatings using latex blends of acrylic/PDMS polymers[J]. Progress in Organic Coatings, 2017,102:151-166.
[18] SHINODA H, MATYJASZEWSKI K, OKRASA L, et al. Structural control of poly(methyl methacrylate)-g-poly(dimethylsiloxane) copolymersusing controlled radical polymerization: effect of the molecular structureon morphology and mechanical properties[J]. Macromolecules, 2003,36(13):4772-4778.
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