纺织学报

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蒸镀超疏水涤纶织物的制备及其疏水性能

  

  • 出版日期:2017-04-15 发布日期:2017-04-15

Preparation and properties of super-hydrophobic polyester fabric by vacuum evaporation

  • Online:2017-04-15 Published:2017-04-15

摘要:

为实现耐久超疏水涤纶织物的简易制备,采用物理气相沉积技术在碱减量预处理的涤纶表面蒸镀低表面能的聚四氟乙烯。采用扫描电子显微镜、接触角测试仪、耐磨试验仪和热分析仪分别对镀膜织物的微观形貌、浸润性、耐久性和膜材的热稳定性进行表征。设计单因素与正交的组合试验方案,对各因素与疏水性能之间的关系进行分析。结果表明:影响镀膜织物疏水性能的主次因素依次为NaOH 质量浓度、蒸镀速率和蒸镀厚度;当NaOH 质量浓度为15g/L,蒸镀速率为0.3nm/s,蒸镀厚度为1.5 μm 时,可制得超疏水涤纶镀膜织物,其接触角和滚动角分别为151°和8.1°;经过7 000次的摩擦试验后,镀膜织物仍拥有124°的接触角和58.6°的滚动角,表现出良好的使用耐久性。

关键词: 涤纶织物, 真空蒸镀, 碱减量, 聚四氟乙烯, 超疏水

Abstract:

In order to achieve the simple priparation durable and super-hydrophobic polyester fabrics, polytetrafluoroethylene with low surface energy were evaporation-coated on polyester fabrics subjected to alkali pretreatment by physical vapor deposition. Scanning electron microscope, contact angle test, friction test and thermal analyzer were used to characterize microstructure, wettability, durability of coated fabrics and thermal stability of films. By designing single factor test and orthogonal test, the relationship between factors and hydrophobic properties was analyzed. The results showed that the order of factors with effects on hydrophobicity of the fabrics as follows: NaOH concentration, deposition speed and deposition thickness. The optimum processing parameters are NaOH concentration of 15 g/L, deposition speed of 0.3 nm/s and deposition thickness of 1.5μm, and under the conditions, super-hydrophobic fabric can be prepared. The contact angle and rolling angle of the coated fabric were 151° and 8.1°, respectively. After 7,000 times mechanical friction test, the coated fabrics still have good durability, and the contact angle and rolling angle of the coated fabric were 124° and 58.6°, respectively.

Key words: polyester fabric, vacuum evaporation, aldali deweighting, polytetrafluoroethylenes, super-hydrophobic

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