Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (01): 9-13.doi: 10.13475/j.fzxb.20180203905

• Fiber Materials • Previous Articles     Next Articles

Influence of organic onium salt doping on spectrum blue-shift of rare earth aluminate strontium luminesent fiber

LI Jing1(), ZHU Ya’nan2, YU Yuan2, GE Mingqiao2   

  1. 1. Union College, Ningbo University, Ningbo, Zhejiang 315211, China
    2. Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China
  • Received:2018-02-22 Revised:2018-10-14 Online:2019-01-15 Published:2019-01-18

Abstract:

In order to solve single-light color for the rare-earth strontium aluminate luminescent fiber, the blue-light luminesent fiber doped with organic onium salt was prepared by combining photo-initiating material triaryl sulfonium hexafluoroantimonate (THFS) and rare earth-activated alkaline earth strontium aluminate luminescent materials by microwave calcination, and melt blend spinning using PP as matrix. Moreover, the influence of the ratio of the raw materials, melting temperature, excitation conditions and other factors on the spectral performance of the fiber was investigated. The results show that when the content of THFS reaches 0.5%, the emission spectrum moves toward the shortwave and the spectrum shifts blue. The change of the luminescent material has no effect on the emission peak of the luminescent fiber, and the effect of light blue shift is not obvious. As the excitation wavelength is weakened, the emission wavelength of the luminescent fiber moves toward the short wavelength, and its emission peak produces blue shift.

Key words: luminescent fiber, triarylsulfonium bexafluoroantimonate, rare-earth strontium aluminate luminescent material, emission spectrum, blue shift

CLC Number: 

  • TS151

Fig.1

XRD spectra of samples"

Fig.2

Emission spectra of PP luminscent fiber with different contents of SrAl2O4:Eu2+,Dy3+"

Fig.3

Emission spectra of luminscent fiber with different contents of THFS"

Fig.4

Emission spectra of luminous fiber at different excitation wavelengthes"

[1] 张变香, 郭一力, 杨丽花, 等. 一种新型芳基硫鎓盐光引发剂的合成及应用[J]. 影像科学与光化学, 2015(2):177-182.
ZHANG Bianxiang, GUO Yili, YANG Lihua, et al. Synjournal and application of a new aryl sulfonium salt photoinitiator[J]. Imaging Science and Photochemistry, 2015(2):177-182.
[2] 徐燃霞, 葛明桥, 李永贵. 蓄能型夜光纤维染色性能的探讨[J]. 印染, 2005 (18):9-11.
XU Ranxia, GE Mingqiao, LI Yonggui. Dyeing properties of luminous fiber with energy storage type[J]. China Dyeing & Finishing, 2005 (18):9-11.
[3] WEI X, FAN J, ZHOU X, et al. Study on Sr2MgSi2O7:Eu2+,Dy3+ long-afterglow luminescent materials via sol-hydrothermal synjournal[J]. Transactions of the Indian Ceramic Society, 2017,76(1):50-55.
doi: 10.1080/0371750X.2016.1241162
[4] 李婧, 朱亚楠, 葛明桥, 等. 绣花商标用夜光纤维的光效对比分析[J]. 纺织学报, 2015,36(1):77-80.
LI Jing, ZHU Ya'nan, GE Mingqiao, et al. Comparative analysis on lighting for embroidery efficiency of luminous fibers trademark[J]. Journals of Textile Resedrch, 2015,36(1):77-80.
[5] 李婧, 葛明桥. 蓄能型夜光机绣织物的余辉亮度研究[J]. 化工新型材料, 2015,43(9):150-152.
LI Jing, GE Mingqiao. Study on afterglow brightness of accumulating luminous computer-embroidery fabric[J]. New Chemical Materials, 2015,43(9):150-152.
[6] LI J, CHEN Z, GE M. Computer-aided design of luminous fiber embroidered fabric and characterization of afterglow performance[J]. Textile Research Journal, 2016,86(11):1162-1170.
doi: 10.1177/0040517515599747
[7] 陈云, 邵亚, 范丽娟. 共轭高分子材料荧光颜色的调节机理及方法[J]. 化学进展, 2014,26(11):1801-1810.
CHEN Yun, SHAO Ya, FAN Lijuan. Regulating mechanism and methods of conjugated polymer fluorescent color[J]. Progress in Chemical, 2014,26(11):1801-1810.
[8] FAN G, XIAO G, ZHANG Z, et al. Modification of optical properties of SrAl2O4: Eu2+,Dy3+ phosphor by terbium doping[J]. Journal of the Chinese Ceramic Society, 2012,40(1):85-89.
[9] HUANG S, TENG F, XU Z. Electrooptical properties of nanoscale and bulk SrAl2O4: Eu,Dy[J]. Spectroscopy and Spectral Analysis, 2009,29(12):3220-3222.
pmid: 20210136
[10] LALEVEE J, BLANCHARD N, TEHFE M A, et al. Efficient dual radical/cationic photoinitiator under visible light: a new concept[J]. Polymer Chemistry, 2011,2(9):1986-1991.
doi: 10.1039/c1py00140j
[11] CRIVEllO J V. The discovery and development of onium salt cationic photoinitiators[J]. Journal of Polymer Science Part A Polymer Chemistry, 1999,37(23):4241-4254.
doi: 10.1002/(ISSN)1099-0518
[12] LI J, CHEN Z, GE M Q. Researches on preparation and luminescent properties of chromatic rare-earth fiber based on SrAl2O4:Eu2+,Dy3+[J]. Journal of Optoelectronics and Advanced Materials, 2016,18(3/4):288-293.
[1] . Conformation and afterglow properties of rare earth magnesium strontium silicate polypropylene luminescent fiber [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(4): 22-26.
[2] GE Mingqiao;ZHAO Jumei;GUO Xuefeng. Photochromic properties of rare-earth strontium aluminate luminescent fiber [J]. JOURNAL OF TEXTILE RESEARCH, 2009, 30(05): 1-5.
[3] ZHAO Jumei;GUO Xuefeng;XU Yanna;GE Mingqiao. Luminescence properties of rare-earth strontium aluminate luminescent fiber [J]. JOURNAL OF TEXTILE RESEARCH, 2008, 29(11): 1-5.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!