Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (12): 98-103.doi: 10.13475/j.fzxb.20180505806

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation of modified aramid fiber and epoxy resin composites and stab resistance thereof

ZHUANG Qun1, ZHANG Fei1, DU Zhaofang1(), JIANG Hua2   

  1. 1. Textile Engineering and Academy of Art, Anhui Agricultural University, Hefei, Anhui 230036, China
    2. Suzhou Gao Jia Protection Technology Co., Ltd., Suzhou, Jiangsu 215000, China
  • Received:2018-05-24 Revised:2019-09-12 Online:2019-12-15 Published:2019-12-18
  • Contact: DU Zhaofang E-mail:dzf@ahau.edu.cn

Abstract:

In order to improve the stab resistance of aramid fabrics, oxygen plasma modified aramid 1414 fabrics were combined with epoxy resin to prepare epoxy aramid composites. The influence of plasma pretreatment on the functional modification of the fabric was investigated, and then stab resistance of the composites was further studied. The experiment results show that when the plasma treatment power is 600 W and the treatment time is 18 min, the fabric surface is etched obviously and the number of oxygen-containing groups increases, and the wettability is improved, but the fabric tensile strength decreases; when the epoxy resin is coated on the plasma-modified aramid fabric, the epoxy group in the resin is firmly bonded with the oxygen-containing active group in the aramid fiber and the bond strength of the complex is better. The tensile strength is increased by 7.89% and the tested composite stab resistance is significantly improved compared with the conventional aramid 1414 fabric, the multi-layered structure has more excellent stab resistance.

Key words: plasma treatment, modified aramid fiber, surface treatment, aramid epoxy composite, stab resistant material

CLC Number: 

  • TS156

Tab.1

Layers setting of composite materials"

试样编号 芳纶织物层数 复合材料层数
1# 1 0
2# 0 1
3# 1 1
4# 0 2
5# 1 2
6# 2 2

Fig.1

Infrared spectra of aramid fibers"

Fig.2

SEM images of aramid fiber(×5 000). (a)Untreated; (b)Treated with 9 min;(c)Treated with 18 min; (d)Treated with 36 min"

Tab.2

Test results of tensile strength"

处理时间/min 拉伸强度/GPa 强度下降百分率/%
0 3.22
9 3.03 5.90
18 2.98 7.45
36 2.43 24.53

Tab.3

Test results of air permeability"

试样名称 喷嘴号 透气率/(cm3·(cm2·s)-1)
未处理芳纶 00 0.68
600 W处理18 min芳纶 02 2.89
单层芳纶环氧复合材料 09 0.00

Tab.4

Test results of puncture-proof"

试样编号 穿刺宽度/cm 穿刺深度/mm
1# 1.83 37.3
2# 1.07 27.3
3# 0.93 24.3
4# 0.56 12.0
5# 0.23 7.6
6# 0.07 4.8
[1] 张晓会, 李艳艳, 李宏英, 等. 防刺阻燃芳纶迷彩面料的性能研究[J]. 针织工业, 2016(12):66-69.
ZHANG Xiaohui, LI Yanyan, LI Hongying, et al. Research on the performance of anti prickly and flame retardant aramid camouflage fabric[J]. Knitting Industries, 2016(12):66-69.
[2] 袁江亮. 高性能芳纶防护织物的研究与开发[D]. 上海:东华大学, 2010: 1-20.
YUAN Jiangliang. Research and development of high performance aramid protective fabric[D]. Shanghai: Donghua University, 2010: 1-20.
[3] 邢京京, 钱晓明, 雷中祥. 民用防刺服的结构优化设计[J]. 纺织科技进展, 2016(1):20-23.
XING Jingjing, QIAN Xiaoming, LEI Zhongxiang. Structural optimization design of civilian stab-proof clothing[J]. Progress in Textile Science & Technology, 2016 (1):20-23.
[4] 李丽娟, 蒋高明, 缪旭红. 柔性防刺材料的现状与发展[J]. 产业用纺织品, 2010(8):8-12.
LI Lijuan, JIANG Gaoming, MIAO Xuhong. Current situation and development of flexible anti pricking materials[J]. Technical Textiles, 2010 (8):8-12.
[5] 聂颖, 燕丰. 橡胶补强和骨架新材料-对位芳纶的开发及应用前景[C]// 中国橡胶工业协会橡胶工业骨架材料中外技术论坛暨2011年度骨架材料专业委员会会员大会论文集.青岛:中国橡胶工业协会, 2011: 242-250.
NIE Ying, YAN Feng. A new rubber reinforcement and framework material: development and application prospect of para-aramid[C]// China Rubber Industry Association Industrial Rubber Framework Material and Foreign Technology Forum and the 2011 Annual Conference Framework Materials Specialized Committee Members. Qingdao: Chinese Rubber Industry Association, 2011: 242-250.
[6] 刘强, 赵领航. 芳纶在产业用纺织品中的应用及展望[J]. 棉纺织技术, 2014(6):74-77.
LIU Qiang, ZHAO Linghang. Application and prospect of aramid in industrial textiles[J]. Cotton Textile Technology, 2014 (6):74-77.
[7] 孔海娟, 张蕊, 周建军, 等. 芳纶纤维的研究现状与进展[J]. 中国材料进展, 2013(11):676-684.
KONG Haijuan, ZHANG Rui, ZHOU Jianjun, et al. Research status and progress of aramid fiber[J]. China Material Progress, 2013(11):676-684.
[8] 侯晓鹏, 常金, 李烨, 等. 芳纶1414纤维含量对织物功能性影响[C]// 陕西省纺织工程学会2014年学术年会论文集.西安:陕西省纺织科学研究所, 2014: 1-5.
HOU Xiaopeng, CHANG Jin, LI Ye, et al. Aramid 1414 fiber content on the influence function of fabric[C]// Shaanxi Province Textile Engineering Society Symposium 2014 on Textile Science Research. Xi'an: Shaanxi Textile Science Institute, 2014: 1-5.
[9] 杨川. 芳纶纤维柔性复合材料制备及其防刺性能研究[D]. 哈尔滨:哈尔滨工业大学, 2010:1
YANG Chuan. Study on the preparation and anti stab resistance of flexible composites of aramid fiber[D]. Harbin: Harbin Institute of Technology, 2010:1
[10] 陈加敏, 孟家光, 薛涛, 等. 等离子体处理对芳纶针织物复合材料性能的影响[J]. 合成纤维, 2016(9):33-36,51.
CHEN Jiamin, MENG Jiaguang, XUE Tao, et al. Effects of plasma treatment on the properties of aramid knitted fabric composites[J]. Synthetic Fiber in China, 2016(9):33-36,51.
[11] 季家友. 芳纶Ⅲ表面改性及其与环氧复合体系的结构与性能研究[D]. 武汉:武汉理工大学, 2012: 7-15.
JI Jiayou. Study on the structure and properties of epoxy composites with aramid fiber surface modification[D]. Wuhan: Wuhan University of Technology, 2012: 7-15.
[12] 季家友, 苏奇, 陈卓. 芳纶Ⅲ的氧气等离子的表面改性[J]. 武汉工程大学学报, 2012,34(6):62-64, 78.
JI Jiayou, SU Qi, CHEN Zhuo. The surface modification of oxygen plasma of aramid III[J]. Journal of Wuhan Institute of Technology, 2012,34(6):62-64, 78.
[13] JIA Caixia, CHEN Ping, LIU Wei, et al. Surface treatment of aramid fiber by air dielectric barrier discharge plasma at atmospheric pressure[J]. Applied Surface Science, 2011,257(9):4165-4170.
[14] 杨婉秋, 刘晓艳, 于伟东. 多层防刺材料中间隔织物的缓冲作用[J]. 纺织学报, 2019,40(4):51-54.
YANG Wanqiu, LIU Xiaoyan, YU Weidong. Buffering effect of interlayer fabric with multi-layer stab-proof material[J]. Journal of Textile Research, 2019,40(4):51-54.
[15] 李扬, 滕飞, 周鑫, 等. 国内外防刺服关键技术指标探析[J]. 警察技术, 2015(5):75-77.
LI Yang, TENG Fei, ZHOU Xin, et al. Analysis of key technical indexes of the domestic and foreign anti stab clothing[J]. Police Technology, 2015 (5):75-77.
[1] LIU Jinxu, LIU Pengqing. Advances in flame-retardant surface treatments for textiles [J]. Journal of Textile Research, 2020, 41(10): 178-187.
[2] CHEN Qian, LIAO Zhen, XU Ming, ZHU Yawei. Effect of plasma treatment on adhesion performance of polytetrafluoroethylene film [J]. Journal of Textile Research, 2020, 41(08): 15-21.
[3] ZHU Jinming, QIAN Jianhua, SUN Liying, LI Zhengping, PENG Huimin. Properties of functionalized composite polyester fabric prepared from silver nanowires of high aspect ratio [J]. Journal of Textile Research, 2019, 40(11): 113-118.
[4] . Cold plasma treatment and aging properties of aramid fiber [J]. Journal of Textile Research, 2018, 39(11): 73-78.
[5] . Mechanical and thermal properties of phase change microcapsules with carbon nanotubes [J]. JOURNAL OF TEXTILE RESEARCH, 2018, 39(02): 119-125.
[6] . Preparation and properties of polylactic acid coated phase change material composite fabric [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(01): 67-72.
[7] . Effect of fabric surface treatment on ink jet printing with reactive dyes [J]. Journal of Textile Research, 2015, 36(02): 128-132.
[8] ZHU Xuzhao;IONG Jie;XU Shuyan;SONG Yeping;HUO Pengfei. Influences of treatment conditions on properties of UHMWPE fibers [J]. JOURNAL OF TEXTILE RESEARCH, 2009, 30(06): 10-14.
[9]
. Effect of aminating treatment on surface performance of CF and its composites [J]. JOURNAL OF TEXTILE RESEARCH, 2009, 30(02): 18-23.
HU Peixian;WEN Yufang;YANG Yonggang;LU Lang
[10] WANG Xiaochun;ZHAO Guoliang;HE Hao;ZHANG Cuiling. Blood compatibility of polyester textile modified by surface grafting [J]. JOURNAL OF TEXTILE RESEARCH, 2008, 29(11): 84-87.
[11] JIANG Sheng. Properties of plasma treated UHMWPE/LDPE composites [J]. JOURNAL OF TEXTILE RESEARCH, 2007, 28(9): 57-60.
[12] YANG Yan-gong;JIA Zhao. Elementary experiment of grafting soybean protein onto the surface of PAN fiber [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(6): 62-63.
[13] YANG Jun-ling. Application of nano-TiO_2 on textile finishing [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(1): 99-102.
[14] YANG Yan-gong;WANG Hou-de;JIA Zhao. Influence of surface treatment of PAN on its thermal and pre-oxidation properties [J]. JOURNAL OF TEXTILE RESEARCH, 2006, 27(1): 65-67.
[15] XIE Hong-de;WANG Hong-wei;LI Ning;ZHANG Wei-dong. Studies on change of properties of tussah fabric after graft modification by plasma treatment [J]. JOURNAL OF TEXTILE RESEARCH, 2005, 26(5): 28-30.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!