Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (8): 14-19.doi: 10.13475/j.fzxb.20180804406

• Fiber Materials •     Next Articles

Preparation and optimization of carboxyl viscose fiber grafted with silkworm chrysalis peptide

YIN Sili1, YANG Yang1, JIANG Wen1, SHI Yexin1, ZHOU Xiaohua1(), HUANG Jinhong2   

  1. 1. School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China
    2. Huimei Tread Industry Co., Ltd., Yibin, Sichuan 644000, China
  • Received:2018-08-15 Revised:2019-04-29 Online:2019-08-15 Published:2019-08-16
  • Contact: ZHOU Xiaohua E-mail:zhou65306590@cqu.edu.cn

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Abstract:

In order to improve the skin affinity and dyeing property of viscose fibers, carboxyl viscose fiber was prepared by oxidation of glucose oxidase(GOD). Silkworm peptide was grafted to the viscose fiber using N,N-dicyclohexylcarbodiimide(DCC) as crosslinking agent, and the main physicochemical and dyeing properties were characterized. The results show that the grafted silkworm peptide carboxyl viscose fiber is composed of 15 kinds of amino acids. The silkworm peptide is located on the surface of carboxyl viscose fiber. The reactions of the fiber with water-soluble aniline blue, basic fuchsin and biuret all show specific dyeing. The grafted silkworm peptide carboxyl viscose fiber is successfully prepared. The optimum process for the preparation of carboxyl viscose fiber by GOD is: pH value of 5.5, the temperature of 35 ℃, the percentage of glucose oxidase in fiber mass of 6%. The optimum process of grafting the carboxyl viscose fiber with silkworm peptide is pH value of 4.0 and the temperature of 60 ℃, the dosage of DCC of 40% of fiber mass.

Key words: carboxyl viscose fiber, N, N-dicyclohexylcarbodiimide, glucose oxidase, silkworm peptide, dyeing property

CLC Number: 

  • TS193.1

Fig.1

Infrared spectra of viscose and carboxyl viscose fiber"

Fig.2

Mass spectrometry of carboxyl viscose fiber"

Fig.3

Effect of basic fuchsin dyeing on viscose (a) and carboxylated viscose(b) fiber"

Fig.4

Infrared spectra of graft carboxyl viscose fiber before and after grafting silkworm chrysalis peptide"

Tab.1

Types and proportions of amino acids"

氨基酸
名称		 蚕蛹肽
中含量/%		 产物中
含量/%		 氨基酸
名称		 蚕蛹肽中
含量/%		 产物中
含量/%
天冬氨酸 4.21 8.63 酪氨酸 2.42 3.38
谷氨酸 1.88 5.52 胱氨酸 44.95 27.70
丝氨酸 3.59 2.35 甲硫氨酸 0.73 2.16
组氨酸 0.44 2.75 色氨酸 1.91 1.56
甘氨酸 13.96 17.27 异亮氨酸 2.24
精氨酸 3.07 2.96 苯丙氨酸 6.69 7.85
苏氨酸 2.37 3.61 亮氨酸 0.82 0.54
丙氨酸 6.68 11.49 赖氨酸 6.28

Fig.5

Effect of biuret reagent dyeing on viscose fiber.(a) Carboxyl viscose fiber;(b) Grafted silkworm chrysalis peptide carboxylic viscose fiber"

Fig.6

Effects of water soluble aniline blue and basic fuchsin dyeing on viscose fiber. (a) Aniline blue dyeing on carboxyl viscose fiber; (b) Aniline blue dyeing on grafted silkworm chrysalis peptide carboxylic viscose fiber; (c) Basic fuchsin dyeing on carboxyl viscose fiber; (d) Basic fuchsin dyeing on grafted silkworm chrysalis peptide carboxylic viscose fiber"

Fig.7

SEM images of viscose (a) and grafted silkworm chrysalis peptide carboxylic viscose(b) fiber (×8 000)"

Fig.8

Effect of pH value(a), temperature(b) and glucose oxidase mass ratio (c) on oxidation ratio of viscose fiber"

Fig.9

Effect of DCC amount(a), temperature(b) and time(c) on graft ratio of viscose fiber"

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