Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (12): 93-97.doi: 10.13475/j.fzxb.20180900406

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and properties of polypyrrole composite fabric by soft template process

CHEN Ying(), ZHOU Shuang, WEI Tianjing, FANG Haoxia, LI Yufei   

  1. School of Materials Design & Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China
  • Received:2018-09-03 Revised:2019-08-16 Online:2019-12-15 Published:2019-12-18

RichHTML

2

PDF (PC)

61

Abstract:

In order to improve conductivity and hydrophobicity of polypyrrole composite fibers, polypyrrole composite cotton and polyester(PET) fabrics were prepared by different soft templates. The micro-morphology of the composite material were characterized by scanning electron microscopy, and the surface resistance, electrical conductivity, contact angle, K/S value, dry friction and breaking strength of the polypyrrole/cotton and polypyrrole/polyester fabrics were tested. The results show that the best soft template for polypyrrole/cotton fabric and polypyrrole/polyester fabric is sodium anthraquinone-2-sulfonate, considering the highest conductivity, polypyrrole/cotton fabric has higher conductivity. Hydrophobic effect is the best when methyl orange is used as soft template for cotton fabric, and for polyester fabric sodium ligninsul-fonate(LGS) is used as soft template. The friction grade is the best when the LGS is used as the soft template for cotton fabric. For polypyrrole/PET fabric, the friction grade is lower except sodium dodecyl benzene sulfonate and hexadecyl trimethyl ammonium bromide as the soft temperature, and the abrasion resistance is needed to be further improved.

Key words: polypyrrole, soft template, conductivity, contact angle, conductive property, hydrophobic property, polyester fabric, cotton fabric

CLC Number: 

  • TS101.4

Fig.1

SEM images of composite fabrics (×2 500). (a)Cotton(SDBS+CTAB);(b)PET(SDBS+CTAB);(c)Cotton(LGS);(d)PET(LGS);(e)Cotton(AQS); (f)PET(AQS);(g)Cotton(MO);(h)PET(MO)"

Tab.1

K/S value of composite fabric with different soft membrane"

模板名称 聚吡咯/棉织物 聚吡咯/涤纶织物
SDBS+CTAB 30.469 6.691
LGS 30.107 23.972
AQS 40.655 34.113
MO 32.508 18.347

Tab.2

Conductivity of composite fabric with different soft membraneS/cm"

模板名称 聚吡咯/棉织物 聚吡咯/涤纶织物
SDBS+CTAB 22.73 0.09
LGS 17.86 4.17
AQS 104.17 9.40
MO 44.64 1.12

Fig.2

Relationship of K/S value and conductivity. (a) PPy/PET fabric;(b)PPy/cotton fabric"

Tab.3

Contact angle of composite fabric with different soft membrane(°)"

模板名称 聚吡咯/棉织物 聚吡咯/涤纶织物
SDBS+CTAB 12.4 11.9
LGS 92.6 116.0
AQS 41.6 —
MO 109.0 27.0

Tab.4

Friction grade of composite fabrics with different soft membrane"

模板名称 聚吡咯/棉织物 聚吡咯/涤纶织物
SDBS+CTAB 3 5
LGS 5 1
AQS 1~2 1~2
MO 1 1~2
[1] 崔锦峰, 安进, 裴春娟, 等. 超疏水导电聚吡咯材料的研究进展[J]. 现代化工, 2013,33(9):36-39.
CUI Jinfeng, AN Jin, PEI Chunjuan, et al. Progress of super hydrophobic conductive polypyrrole materials[J]. Modern Chemical Industry, 2013,33(9):36-39.
[2] 王大祥. 硬模板法制备聚吡咯/棉布复合织物柔性电极材料及性能研究[D]. 武汉: 武汉纺织大学, 2016: 8.
WANG Daxiang. Prepared polyprrole/cotton fabric electrode materials and performance research via hard template[D]. Wuhan: Wuhan Textile University, 2016: 8.
[3] AN J, SUN H, CUI J, et al. Surface modification of polypyrrole-coated foam for the capture of organic solvents and oils[J]. Journal of Materials Science, 2014,49(13):4576-4582.
[4] HUANG J, WANG K, WEI Z. Conducting polymer nanowire arrays with enhanced electrochemical performance[J]. Journal of Materials Chemistry, 2010,20(6):1117-1121.
[5] LI M, WEI Z, JIANG L. Polypyrrole nanofiber arrays synthesized by a biphasic electrochemical strategy[J]. Journal of Materials Chemistry, 2008,18(19):1107-1110.
[6] TAN J, ZHANG Z, HE Y, et al. Electrochemical synjournal of conductive, superhydrophobic and adhesive polypyrrole-polydopamine nanowires[J]. Synthetic Metals, 2017,234:86-94.
[7] 陈莹, 王鸿达, 李宥宣. 不同溶剂对聚吡咯/涤纶材料抗凝血性能的影响[J]. 纺织学报, 2018,39(2):132-137.
CHEN Ying, WANG Hongda, LI Youxuan. Influence of different solvents on anticoagulant property of polyprrole/polyester marterials[J]. Journal of Textile Research, 2018,39(2):132-137.
[8] 袁野. 超级电容器用聚吡咯纤维电极材料的制备及性能研究[D]. 武汉: 武汉纺织大学, 2016: 19.
YUAN Ye. Research of polypyrrole-coated flexible fabric as fiber supercapacitor electrode[D]. Wuhan: Wuhan Textile University, 2016: 19.
[9] 李飞, 陶义飞. 聚吡咯纳米纤维材料的制备及表征[J]. 离子交换与吸附, 2017(2):179-186.
LI Fei, TAO Yifei. Preparation and characterization of polypyrrole nono fiber[J]. Ion Exchange and Adsorption, 2017(2):179-186.
[10] WU J S, GU D W, HHANG D, et al. Chemical in situ polymerization of polypyrrole nanoparticles on the hydrophilic/hydrophobic surface of SiO2 substrates[J]. Synjournal and Reactivity in Inorganic and Metal-Organic Chemistry, 2012,42(8):1064-1070.
[11] 周存, 何雅僖. 超疏水导电聚酯织物的制备及其性能[J]. 纺织学报, 2018,39(8):88-94.
ZHOU Cun, HE Yaxi. Preparation and characterization of super hydrophobic conductive polyester fabrics[J]. Journal of Textile Research, 2018,39(8):88-94.
[1] WANG Bo, FAN Lihua, YUAN Yun, YIN Yunjie, WANG Chaoxia. Preparation and electric storage performance of stretchable polypyrrole / cotton knitted fabric [J]. Journal of Textile Research, 2020, 41(10): 101-106.
[2] LI Liang, LIU Jingfang, HU Zedong, GENG Changjun, LIU Rangtong. Graphene oxide loading on polyester fabrics and antistatic properties [J]. Journal of Textile Research, 2020, 41(09): 102-107.
[3] PANG Yali, MENG Jiayi, LI Xin, ZHANG Qun, CHEN Yankun. Preparation of graphene fibers by wet spinning and fiber characterization [J]. Journal of Textile Research, 2020, 41(09): 1-7.
[4] LIU Guojin, SHI Feng, CHEN Xinxiang, ZHANG Guoqing, ZHOU Lan. Preparation of polyurethane / phase change wax functional finishing agents for heat storage and temperature regulation and their applications on cotton fabrics [J]. Journal of Textile Research, 2020, 41(07): 129-134.
[5] CHENG Shijie, WANG Chenyang, ZHANG Hongwei, ZUO Danying. Effect of boron nitrogen doped carbon dots on ultraviolet-protection of cotton fabrics [J]. Journal of Textile Research, 2020, 41(06): 93-98.
[6] ZHOU Qingqing, CHEN Jiayi, QI Zhenming, CHEN Weijian, SHAO Jianzhong. Preparation and characterization of flame retardant and antibacterial cotton fabric [J]. Journal of Textile Research, 2020, 41(05): 112-120.
[7] LIU Guojin, HAN Pengshuai, CHAI Liqin, WU Yu, LI Hui, GAO Yafang, ZHOU Lan. Preparation and stability of self-crosslinking P(St-NMA) photonic crystals with structural colors on polyester fabrics [J]. Journal of Textile Research, 2020, 41(05): 99-104.
[8] HU Chengye, MIAO Runwu, HAN Xiao, HONG Jianhan, GIL Ignacio. Effect of polyvinyl alcohol on durability of polyaniline conductive layer on poly(p-phenylene terephthamide) yarn surface [J]. Journal of Textile Research, 2020, 41(04): 91-97.
[9] WANG Xiaofei, WAN Ailan. Preparation of polypyrrole / silver conductive polyester fabric by ultraviolet exposure [J]. Journal of Textile Research, 2020, 41(04): 112-116.
[10] TAN Lin, SHI Yidong, ZHOU Wenya. Study on enhancement of hydrophobicity treatment of cotton fabrics using silica sol [J]. Journal of Textile Research, 2020, 41(04): 106-111.
[11] WEI Tengxiang, LI Min, PENG Hongyun, FU Shaohai. Relationship between open-width mercerization condition and loop structure of weft plain-knitted cotton fabrics [J]. Journal of Textile Research, 2020, 41(04): 98-105.
[12] ZHAO Bing, HUANG Xiaocui, QI Ning, ZHONG Zhou, CHE Mingguo, GE Liangliang. Research progress of antibacterial cotton fabric treated with silver nanoparticles based on covalent bond [J]. Journal of Textile Research, 2020, 41(03): 188-196.
[13] LIN Jiameng, WAN Ailan, MIAO Xuhong. Preparation and properties of polypyrrole / silver conductive polyester fabrics [J]. Journal of Textile Research, 2020, 41(03): 113-117.
[14] DING Fang, REN Xuehong. Flame-retardant finishing of polyester fabrics by grafting phosphorus-nitrogen compounds [J]. Journal of Textile Research, 2020, 41(03): 100-105.
[15] GAO Simeng, WANG Hongbo, DU Jinmei, WANG Wencong. Synthesis of polybetaine antibacterial agent and its applications in cotton textiles finishing [J]. Journal of Textile Research, 2020, 41(02): 89-94.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd