Journal of Textile Research ›› 2021, Vol. 42 ›› Issue (09): 112-119.doi: 10.13475/j.fzxb.20201001208

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Effect of cationic modification in hydrophobic system on ink droplet spreading on cotton/polyamide fabrics

LI Chang1, FANG Kuanjun1,2,3,4(), LIU Xiuming1,4, AN Fangfang1, LIANG Yingchao1, LIU Hao1   

  1. 1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
    2. College of Textiles & Clothing, Qingdao University, Qingdao, Shandong 266071, China
    3. State Key Laboratory for Biofibers and Eco-Textiles, Qingdao, Shandong 266071, China
    4. Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao, Shandong 266071, China
  • Received:2020-10-07 Revised:2021-05-08 Online:2021-09-15 Published:2021-09-27
  • Contact: FANG Kuanjun E-mail:13808980221@163.com

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Abstract:

In order to improve the homo-chromaticity, color performance and fixation rate of ink droplets on the surface of cotton/polyamide fabrics, cationic modification of cotton/polyamide fabric was carried out in hydrophobic system using surfactant N,N-bis(2-hydroxyethyl)-dodecanamide (LDEA) to construct. The effect of the mass fraction of the cationic modifier 3-chloro-2-hydroxypropyl trimethylammonium chloride (CHPTAC) and LDEA in the modification system on the modification result of the fabric was explored. The spread area, color performance and fixation rate of the ink droplets on the surface of the modified fabric under different processes were tested. The surface morphology, chemical structure and electrical changes of the modified fabric were analyzed. Results show that cationic modification reduced the spread area of ink droplets on the fabric surface by 30%. Compared with aqueous system, the homo-chromaticity and color performance of the ink droplets on the surface of the fabric after modification in the hydrophobic system are significantly improved. The apparent color strength upgraded to 2.7 and the difference decreased by 41% between cotton and polyamide fibers. The white spot phenomenon on the surface of the ink droplet was eliminated. The modifier were grafted successfully on the surface of cotton and polyamide fibers, and furthermore the distribution could be made more uniform between two fibers in the hydrophobic system compared with aqueous system.

Key words: cotton/polyamide fabric, cationic modification, hydrophobic system, ink drop spread, color performance, ink-jet printing

CLC Number: 

  • TS194.4

Fig.1

Schematic diagram of cationic modification of cotton and polyamide fiber and its chemical reaction with dyes"

Fig.2

Effect of concentration of CHPTAC (a)and LDEA (b)on K/S value of ink droplets on surface of fabric"

Fig.3

Spread of ink droplets on different modified fabrics. (a)Unmodified;(b)GTA modified; (c)GTA/LDEA modified"

Tab.1

Color parameters and dye fixation rates of ink droplets of modified fabrics"

改性体系 织物 颜色参数 K/S值 固色率/%
L* a* b* C* h°
未改性 棉/聚酰胺 70.6 30.9 -7.4 31.8 346.6 0.8 2.2±0.1
聚酰胺 41.3 56.1 -2.9 56.2 357.0 12.2 46.5±0.5
棉 79.2 15.6 -3.9 16.1 345.9 0.3 1.2±0.1
GTA改性 棉/聚酰胺 39.7 55.4 1.5 55.4 1.5 13.4 43.3±0.6
聚酰胺 83.9 8.3 0.5 8.4 3.3 0.1 4.0±0.2
棉 35.4 55.0 2.6 55.0 2.7 19.8 78.7±1.0
GTA/LDEA改性 棉/聚酰胺 39.3 57.7 -0.1 57.7 359.9 16.1 60.5±0.8
聚酰胺 47.9 56.9 -10.4 57.9 349.7 8.8 38.7±0.3
棉 39.0 57.8 -0.9 57.8 359.1 16.9 64.0±1.4

Fig.4

Surface morphology of cotton and polyamide fiber (×5 000). (a)Unmodified cotton fiber; (b)GTA modified cotton fiber; (c)GTA/LDEA modified cotton fiber;(d)Unmodified polyamide fiber; (e)GTA modified polyamide fiber; (f)GTA/LDEA modified polyamide fiber"

Fig.5

FT-IR spectra of cotton fiber"

Fig.6

FT-IR spectra of the polyamide fiber"

Tab.2

Zeta potential on fabric surface"

CHPTAC
质量分数/%		 棉纤维Zeta电位/mV 聚酰胺纤维Zeta电位/mV
GTA改性 GTA/LDEA
改性		 GTA改性 GTA/LDEA
改性
0 -13.2 -13.2 -43.1 -43.1
2 -10.1 -12.3 -39.3 -31.8
4 -4.2 -7.1 -36.8 -22.6
6 4.1 1.4 -29.2 -14.3
8 8.3 4.2 -26.8 -8.6

Tab.3

Color fastnesses of cotton/polyamide fabrics 级"

织物改性体系 耐水洗色牢度 耐摩擦色牢度 耐日晒
色牢度
SC SP CC 干 湿
未改性 4~5 4~5 4~5 4~5 4 3~4
GTA改性 4~5 4~5 4~5 3~4 3 4~5
GTA/LDEA改性 4 4~5 4 4 2~3 4
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