Journal of Textile Research ›› 2026, Vol. 47 ›› Issue (03): 166-174.doi: 10.13475/j.fzxb.20250902602

• Safety and Protective Materials • Previous Articles     Next Articles

Research status and development trends in personal thermal protection materials

HOU Lin1,2, SONG Yueyue1, MA Jun1, XU Yanyan1, WU Yikun1, FAN Wei3,4()   

  1. 1 Shaanxi Yuanfeng Prosafe Co., Ltd., Xi'an, Shaanxi 710025, China
    2 College of Bioresources Chemical & Materials Engineering, Shaanxi University of Science & Technology, Xi'an, Shaanxi 710021, China
    3 College of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    4 Key Laboratory of Functional Textile Material and Product, Ministry of Education, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
  • Received:2025-09-06 Revised:2025-12-24 Online:2026-03-15 Published:2026-03-15
  • Contact: FAN Wei E-mail:fanwei@xpu.edu.cn

Abstract:

Significance Individual thermal protection materials are core equipment for ensuring the safety of firefighters, workers in high-risk industries, and military personnel when working in extremely high-temperature environments. Its performance not only affects the survival safety of personnel under extreme conditions, but also directly influences its combat flexibility and continuous combat capability. With the complexity and diversity of high-temperature working environments, conventional thermal protection materials are difficult to meet the actual needs. Based on the principle of thermal protection, this research systematically reviews the research status, performance evaluation methods and application fields of various thermal protection materials, and conducts in-depth discussions on their future development trends and challenges, aiming to provide theoretical support and direction guidance for the research and application of related materials.

Progress Individual thermal protection materials, according to their protection mechanisms, can be classified into three types, heat insulation type, barrier type and reflective type. In order to address the multiple thermal threats such as heat conduction, heat convection and heat radiation coexisting in real fire scenarios, the materials are usually combined in use to construct a multi-layer protection system. In recent years, significant improvement has been made in enhancing the thermal and moisture comfort performance of protection materials by blending intrinsically flame-retardant fibers with modified flame-retardant fibers for spinning. Some researchers have introduced natural fibers to enhance the permeability of fabrics, thereby achieving a coordinated improvement in protective performance and comfort. In addition, the emergence of new thermal protection materials such as phase change materials, aerogels, shape memory materials and biomimetic structures enables individual thermal protection systems to provide excellent thermal protection performance while also being lightweight and comfortable. Deficiencies were identified in the existing performance evaluation systems for individual thermal protection materials. Clarifying the people-clothing-environment interaction is crucial for optimizing material design and balancing thermal protection with comfort. The comprehensive application status analysis shows that only by building a corresponding protection system in accordance with the specific needs of different fields can better protection performance be demonstrated in high-temperature environments such as emergency fire protection, industrial protection, and military operations.

Conclusion and Prospect In the future, research on individual thermal protection materials will be developed in the direction of multi-mode collaborative systems such as intelligence, multi-functionality and greenness. The focus will be on the heat transfer mechanism of the human body-clothing-environment system under the coupling effect of multiple physical fields, laying a theoretical foundation for precise and efficient thermal protection. By introducing cutting-edge technologies such as nanomaterials, aerogels and flexible electronics, materials have been able to achieve dynamic thermal management and monitor the physiological state of the wearer in real time. In terms of performance evaluation, although a multi-dimensional comprehensive evaluation system has been established, it is still necessary to combine the biological response indicators of the human body in extremely complex environments to more realistically simulate the actual usage conditions. Different application scenarios such as fire protection, industry, military, and aerospace have put forward differentiated demands for materials, which will further drive the evolution of material systems towards customization and modularization to meet the diverse actual protection needs. Overall, the core challenge in this field lies in balancing protective performance with wearing comfort and driving the transformation of technology from passive protection to active intelligent protection. The ultimate goal is not only to efficiently resist extreme thermal hazards, but also to significantly enhance the thermal physiological comfort, mobility and overall work efficiency of the wearer, truly realizing the safety protection concept of people-oriented.

Key words: individual thermal protection, thermal protection material, performance evaluation, application scenario, fire rescue, functional textile material

CLC Number: 

  • TQ 317

Fig.1

Schematic diagram of heat insulation mechanism of individual thermal protection materials"

Fig.2

Schematic diagram of flame retardant mechanism of individual thermal protection materials"

[1] 杨孟想, 刘让同, 李亮, 等. 机织物的热传递与强热条件下热防护性能[J]. 纺织学报, 2023, 44(11): 74-82.
doi: 10.13475/j.fzxb.20220506901
YANG Mengxiang, LIU Rangtong, LI Liang, et al. Heat transfer and thermal protection properties under strong thermal conditions of woven fabrics[J]. Journal of Textile Research, 2023, 44(11): 74-82.
doi: 10.13475/j.fzxb.20220506901
[2] UDAYRAJ, TALUKDAR P, DAS A, et al. Heat and mass transfer through thermal protective clothing: a review[J]. International Journal of Thermal Sciences, 2016, 106: 32-56.
doi: 10.1016/j.ijthermalsci.2016.03.006
[3] 朱晓荣, 何佳臻, 向攸慧, 等. 热防护服蓄热防护与放热危害双重特性的研究进展[J]. 纺织学报, 2023, 44(1): 228-237.
ZHU Xiaorong, HE Jiazhen, XIANG Youhui, et al. Research progress in dual performance in heat-storage protection and heat-release hazard of thermal protective clothing[J]. Journal of Textile Research, 2023, 44(1): 228-237.
[4] 黄长芬, 李逸飞, 周绪波, 等. 具有孔径梯度的热防护接结三层织物的制备与导湿性能研究[J]. 纺织科学与工程学报, 2025, 42(3): 1-6.
HUANG Changfen, LI Yifei, ZHOU Xubo, et al. Study on the preparation of thermal protective bonded three-layer fabrics with aperture gradient and its moisture transfer performance[J]. Journal of Textile Science and Engineering, 2025, 42(3): 1-6.
[5] MANDAL S, MAZUMDER N U S, AGNEW R J, et al. Characterization and modeling of thermal protective and thermo-physiological comfort performance of polymeric textile materials: a review[J]. Materials, 2021, 14(9): 2397.
doi: 10.3390/ma14092397
[6] LIU B X, LIU X C, ZHAO X F, et al. High-strength, thermal-stable ZrO2 aerogel from polyacetylacetonatozirconium[J]. Chemical Physics Letters, 2019, 715: 109-114.
doi: 10.1016/j.cplett.2018.11.025
[7] 戴佳欣. 热防护服隔热层复合中空结构制备及其性能测评[D]. 上海: 东华大学, 2022.
DAI Jiaxin. Preparation and performance evaluation of insulating layer composite hollow structure for thermal protective clothing[D]. Shanghai: Donghua University, 2022.
[8] ALGHAMDI A, ALHARTHI H, ALAMOUDI A, et al. Effect of needling parameters and manufacturing porosities on the effective thermal conductivity of a 3D carbon-carbon composite[J]. Materials, 2019, 12(22): 3750.
doi: 10.3390/ma12223750
[9] LIU L, LAI D W, WU H, et al. Self-assembling macromolecular flame retardant polyvinyl alcohol films with phytic acid and melamine[J]. Journal of Vinyl and Additive Technology, 2026, 32(1): 28-45.
doi: 10.1002/vnl.v32.1
[10] ZHU F, FENG Q. Preparation, thermal properties and permeabilities of aluminum-coated fabrics destined for thermal radiation protective clothing[J]. Fire and Materials, 2020, 44(6): 844-853.
doi: 10.1002/fam.v44.6
[11] 张玮, 刘姝瑞, 张明宇, 等. 芳纶纤维的发展现状及应用[J]. 纺织科学与工程学报, 2024, 41(1): 86-94.
ZHANG Wei, LIU Shurui, ZHANG Mingyu, et al. Development status and application of aramid fiber[J]. Journal of Textile Science and Engineering, 2024, 41(1): 86-94.
[12] 金钊, 刘一寰, 胡欣, 等. 芳纶的合成与改性[J]. 高分子通报, 2022, 35(3): 8-17.
JIN Zhao, LIU Yihuan, HU Xin, et al. Synthesis and modification of aramid[J]. Polymer Bulletin, 2022, 35(3): 8-17.
[13] 高召阳, 马建华, 李家炜, 等. 阻燃纤维改性方法及其高性能阻燃纤维开发的研究现状[J]. 纺织科学与工程学报, 2023, 40(1): 90-95.
GAO Zhaoyang, MA Jianhua, LI Jiawei, et al. Research status of modification methods of flame retardant fibers and high-performance flame retardant fibers development[J]. Journal of Textile Science & Engineering, 2023, 40(1): 90-95.
[14] YANG G S, PENG K, ZHANG H H, et al. Structure and properties of flame-retardant Lyocell fibers prepared by blending method[J]. Polymer Engineering & Science, 2022, 62(10): 3476-3486.
doi: 10.1002/pen.v62.10
[15] MARCIONI M, ZHAO M X, MADDALENA L, et al. Layer-by-layer-coated cellulose fibers enable the production of porous, flame-retardant, and lightweight materials[J]. ACS Applied Materials & Interfaces, 2023, 15(30): 36811-36821.
[16] ZHENG S M, LI W, CHEN Y Y, et al. Synergistic effect of stereo-complexation and interfacial compatibility in ammonium polyphosphate grafted polylactic acid fibers for simultaneously improved toughness and flame retardancy[J]. International Journal of Biological Macromolecules, 2024, 261: 129943.
doi: 10.1016/j.ijbiomac.2024.129943
[17] SU Y, FAN Y W, MA Y L, et al. Flame-retardant phase change material (PCM) for thermal protective application in firefighting protective clothing[J]. International Journal of Thermal Sciences, 2023, 185: 108075.
doi: 10.1016/j.ijthermalsci.2022.108075
[18] 朱晓荣, 何佳臻, 王敏. 相变材料在热防护服上的应用研究进展[J]. 纺织学报, 2022, 43(4): 194-202.
ZHU Xiaorong, HE Jiazhen, WANG Min. Application research progress in phase change materials for thermal protective clothing[J]. Journal of Textile Research, 2022, 43(4): 194-202.
doi: 10.1177/004051757304300402
[19] LI Y H, ZHAO X G, LI D K, et al. Multifunctional composite phase change materials: preparation, enhanced properties and applications[J]. Composites Part A: Applied Science and Manufacturing, 2024, 185: 108331.
doi: 10.1016/j.compositesa.2024.108331
[20] CHENG Y J, CHENG H L, GAO J, et al. Air-drying for rapid manufacture of flexible aramid nanofiber aerogel fibers with robust mechanical properties and thermal insulation in harsh environments[J]. Small, 2025, 21(7): 2409408.
doi: 10.1002/smll.v21.7
[21] 宫学斌, 刘元军, 赵晓明. 热防护用气凝胶材料的研究进展[J]. 纺织学报, 2022, 43(6): 187-196.
GONG Xuebin, LIU Yuanjun, ZHAO Xiaoming. Research progress of aerogel materials for thermal protection[J]. Journal of Textile Research, 2022, 43(6): 187-196.
[22] 蒋璐璐, 邓梦, 王云仪, 等. 气凝胶材料在消防服中的应用研究进展[J]. 纺织学报, 2021, 42(9): 187-194.
JIANG Lulu, DENG Meng, WANG Yunyi, et al. Research progress on application of aerogel materials in firefighting clothing[J]. Journal of Textile Research, 2021, 42(9): 187-194.
[23] HU Y H, YAN Z F, YANG G, et al. Engineering aramid aerogel fibers with core-shell structure for high-performance thermal protective textiles[J]. Advanced Functional Materials, 2025, 35(47): 2506968.
doi: 10.1002/adfm.v35.47
[24] MA N N, LU Y H, HE J Z, et al. Application of shape memory materials in protective clothing: a review[J]. The Journal of the Textile Institute, 2019, 110(6): 950-958.
doi: 10.1080/00405000.2018.1532783
[25] HU R X, ZHANG F H, LUO L, et al. Reconfigurable high-temperature thermal protection shape memory aerogel based on phthalonitrile resin with facile template method[J]. Carbon, 2025, 242: 120378.
doi: 10.1016/j.carbon.2025.120378
[26] ZHANG J S, WANG Y, WU J P, et al. STF-filled biomimetic variable stiffness hierarchic porous material with impact resistance, thermal insulation, and sensing[J]. Chemical Engineering Journal, 2023, 477: 146939.
doi: 10.1016/j.cej.2023.146939
[27] WU M R, SHAO Z Y, ZHAO N F, et al. Biomimetic, knittable aerogel fiber for thermal insulation textile[J]. Science, 2023, 382(6677): 1379-1383.
doi: 10.1126/science.adj8013
[28] 屈斐, 权国明, 林娜, 等. 国内外阻燃、热防护类纺织品标准对比与分析[J]. 中国个体防护装备, 2021(2): 34-38.
QU Fei, QUAN Guoming, LIN Na, et al. Flame retardant, thermal protection textiles standards at home and abroad of contrast and analysis[J]. China Personal Protective Equipment, 2021(2): 34-38.
[29] PSIKUTA A, SHERIF F, MERT E, et al. Clothing air gaps in various postures in firefighters' work[J]. International Journal of Biometeorology, 2023, 67(1): 121-131.
doi: 10.1007/s00484-022-02391-2 pmid: 36323952
[30] 翟丽娜, 李俊. 服装热防护性能测评技术的发展过程及现状[J]. 纺织学报, 2015, 36(7): 162-168.
ZHAI Lina, LI Jun. Development and current status on performance test and evaluation of thermal protective clothing[J]. Journal of Textile Research, 2015, 36(7): 162-168.
[31] 李姗姗, 李文川, 唐孔科, 等. 基于燃烧假人的阻燃服装热防护性能[J]. 印染, 2025, 51(3): 68-71.
LI Shanshan, LI Wenchuan, TANG Kongke, et al. Thermal protective performance of flame retardant clothing based on a flame manikin[J]. China Dyeing and Finishing, 2025, 51(3): 68-71.
[32] SU Y, WANG Y Y, LI J. Evaluation method for thermal protection of firefighters' clothing in high-temperature and high-humidity condition: a review[J]. International Journal of Clothing Science and Technology, 2016, 28(4): 429-448.
doi: 10.1108/IJCST-10-2015-0107
[33] PHELPS H, SIDHU H. A mathematical model for heat transfer in fire fighting suits containing phase change materials[J]. Fire Safety Journal, 2015, 74: 43-47.
doi: 10.1016/j.firesaf.2015.04.007
[34] 李永海, 钱志敏, 闫金刚, 等. 灭火防护服轻量化设计与表征[J]. 毛纺科技, 2025, 53(3): 80-85.
LI Yonghai, QIAN Zhimin, YAN Jingang, et al. Research on lightweight of fire protection clothing[J]. Wool Textile Journal, 2025, 53(3): 80-85.
[35] LI Z M, WANG S, GONG L P, et al. Bioinspired flame-retardant and impact-resistant aramid composites via nacre-mimetic self-assembly for firefighting applications (adv. mater. 42/2025)[J]. Advanced Materials, 2025, 37(42): e70841.
doi: 10.1002/adma.v37.42
[36] 邹亮, 吴银. 热防护服装的分类应用及创新发展[J]. 中国个体防护装备, 2024(6): 33-35.
ZOU Liang, WU Yin. Classification, application, and innovative development of thermal protective clothing[J]. China Personal Protective Equipment, 2024(6): 33-35.
[37] 徐炎炎, 蔡普宁, 权国明, 等. 焊接防护面料的研究现状与开发方向[J]. 棉纺织技术, 2022, 50(12): 19-22.
XU Yanyan, CAI Puning, QUAN Guoming, et al. Development status and development direction of welding protective fabric[J]. Cotton Textile Technology, 2022, 50(12): 19-22.
[38] 李世雄, 权国明, 徐炎炎, 等. 高密度焊接服面料织造技术实践与优化[J]. 合成纤维, 2024, 53(12): 13-16, 23.
LI Shixiong, QUAN Guoming, XU Yanyan, et al. Practice and optimization of weaving technology for high-density welded clothing fabrics[J]. Synthetic Fiber in China, 2024, 53(12): 13-16, 23.
[39] 刘琳, 李世雄, 蔡普宁, 等. 防熔融金属飞溅织物的防护机理及影响因素探讨[J]. 棉纺织技术, 2024, 52(12): 45-50.
LIU Lin, LI Shixiong, CAI Puning, et al. Discussion on protection principle and influence factor of molten metal splash protection fabric[J]. Cotton Textile Technology, 2024, 52(12): 45-50.
[40] 刘婉婉, 韩敏, 孙启龙, 等. 熔融金属防护面料的开发[J]. 纺织报告, 2024, 43(7): 11-13.
LIU Wanwan, HAN Min, SUN Qilong, et al. Development of molten metal protective fabrics[J]. Textile Reports, 2024, 43(7): 11-13.
[41] 刘慧慧, 唐孔科, 韩玉洁, 等. 防电弧服产品认证概述及建议[J]. 产业用纺织品, 2025, 43(1): 49-53.
LIU Huihui, TANG Kongke, HAN Yujie, et al. Overview and suggestions of product certification for arc flash protective clothing[J]. Technical Textiles, 2025, 43(1): 49-53.
[42] MA C, DUAN X Y, YUE P C, et al. Comparative analysis of polyimide and aramid fabrics as arc protective materials[J]. Textile Research Journal, 2023, 93(15/16): 3736-3752.
doi: 10.1177/00405175231158819
[43] SMITH D L, VEST N A, RODRIGUEZ-MELENDEZ D, et al. Bio-sourced intumescent nanocoating[J]. Advanced Engineering Materials, 2023, 25(4): 2200911.
doi: 10.1002/adem.v25.4
[44] WANG X K, WANG Z, ZHANG J Y, et al. Carboxylated cellulose nanofibers aerogels with enhanced flame retardancy and thermal insulation for intelligent fire warning systems[J]. Industrial Crops and Products, 2025, 235: 121703.
doi: 10.1016/j.indcrop.2025.121703
[45] XU D, CHEN Z, LIU Y C, et al. Hump-inspired hierarchical fabric for personal thermal protection and thermal comfort management[J]. Advanced Functional Materials, 2023, 33(10): 2212626.
doi: 10.1002/adfm.v33.10
[46] ATTIA N F, ZAKRIA A M, NOUR M A, et al. Rational strategy for construction of multifunctional coatings for achieving high fire safety, antibacterial, UV protection and electrical conductivity functions of textile fabrics[J]. Materials Today Sustainability, 2023, 23: 100450.
doi: 10.1016/j.mtsust.2023.100450
[47] CHAI J L, WANG G L, WANG G Z, et al. Porous and conductive fiber woven textile for multi-functional protection, personal warmth, and intelligent motion/temperature perception[J]. Advanced Functional Materials, 2025, 35(10): 2416428.
doi: 10.1002/adfm.v35.10
[48] SADROLODABAEE P, DE LA FUENTE A, ARDANUY M, et al. Mechanical performance of aged cement-based matrices reinforced with recycled aramid textile nonwoven fabric: comparison with other FRCMs[J]. Case Studies in Construction Materials, 2024, 20: e02994.
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