Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (03): 113-117.doi: 10.13475/j.fzxb.20190301105

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and properties of polypyrrole/silver conductive polyester fabrics

LIN Jiameng, WAN Ailan, MIAO Xuhong()   

  1. Engineering Research Center for Knitting Technology, Ministry of Education, Jiangnan University, Wuxi, Jiangsu 214122, China
  • Received:2019-03-01 Revised:2019-11-07 Online:2020-03-15 Published:2020-03-27
  • Contact: MIAO Xuhong E-mail:miaoxuhong@163.com

Abstract:

In order to expand the application of polypyrrole/silver (PPy/Ag) conductive polyester fabrics, PPy/Ag conductive polyester fabrics were prepared by one-pot method with silver nitrate as oxidant under the condition of plasma pretreatment. The conductive fabrics were characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. The square resistance of conductive fabrics was measured by resistometer and the bacteriostatic effect was tested by agar plate method. The results show that the PPy/Ag conductive polyester fabrics prepared in this study have good conductivity, and have obvious inhibitory effect on Escherichia coli and Staphylococcus aureus. The conductivity of such fabrics is positively correlated with the number of times of plasma pretreatment to polyester fabrics, and the square resistance of conductive fabrics reaches the minimum value of 0.22 kΩ/□ when the number of plasma pretreatment is 4.

Key words: conductive fabric, polypyrrole, silver nanoparticles, plasma pretreatment, polyester, conductivity, antimicrobial property

CLC Number: 

  • TS195.2

Tab.1

Samples and treatment methods"

试样编号 处理条件
0# 未处理的涤纶织物
0-1# 等离子体预处理
1# 吡咯氧化聚合+Ag+还原
2# 等离子体处理2次+吡咯氧化聚合+Ag+还原
3# 等离子体处理3次+吡咯氧化聚合+Ag+还原
4# 等离子体处理4次+吡咯氧化聚合+Ag+还原
5# 等离子体处理5次+吡咯氧化聚合+Ag+还原

Tab.2

Sample square resistance and CV值"

试样编号 方阻/(kΩ·□-1) CV值/%
1# 3.94 10.3
2# 1.98 3.9
3# 1.08 2.7
4# 0.22 3.1
5# 0.24 3.7

Fig.1

SEM images of specimens (×5 000)"

Fig.2

Infrared spectrogram of samples"

Fig.3

XRD pattern of samples"

Tab.3

Evaluation of bacteriostasis effect of samples"

试样
编号
试样下面细菌
繁殖情况
抑菌带宽度/mm 评价
大肠杆菌 金黄色葡萄球菌
0# 大量 0 0 没有效果
1# 轻微 >1 >1 效果较好
2# 轻微 >1 >1 效果较好
3# 轻微 >1 >1 效果较好
4# 轻微 >1 >1 效果较好
5# 轻微 >1 >1 效果较好

Fig.4

Bacteriostasis test result"

[1] SAHA S, SARKAR J, ACHARYA Y, et al. Production of silver nanoparticles by a phytopathogenic fungus bipolaris nodulosa and its antimicrobial activity[J]. Digest Journal of Nanomaterials & Biostructures, 2010,5(4):887-895.
[2] AJAY SINGH, ZAKARIA SALMI, NIRAV JOSHI, et al. Photo-induced synjournal of polypyrrole-silver nanocomposite films on N-(3-trimethoxysilylpropyl) pyrrole-modified biaxially oriented polyethylene flexible substrates[J]. RSC Advances, 2013,16(3):6-23.
[3] SUN J, YAO L, GAO Z, et al. Surface modification of PET films by atmospheric pressure plasma-induced acrylic acid inverse emulsion graft[J]. Surface and Coatings Technology, 2010,204(24):4101-4106.
[4] KELLER M, RITTER A, REIMANN P, et al. Comparative study of plasma-induced and wet-chemical cleaning of synthetic fibers[J]. Surface and Coatings Technology, 2005,200(4):1045-1050
[5] MEHMOOD T, KAYNAK A, DAI X J, et al. Study of oxygen plasma pre-treatment of polyester fabric for improved polypyrrole adhesion[J]. Materials Chemistry and Physics, 2014,143(2):668-675.
[6] ATTIA M F, AZIB T, SALMI Z, et al. One-step UV-induced modification of cellulose fabrics by polypyrrole/silver nanocomposite films[J]. Journal of Colloid & Interface Science, 2013,393(1):130-137.
[7] JLASSI K, SINGH A, ASWAL D K, et al. Novel, ternary clay/polypyrrole/silver hybrid materials through in situ photopolymerization[J]. Colloid Surf A: Physicochem Eng Asp, 2013,439(Special SI):193-199.
[8] GASHTI M P, GHEHI S T, AREKHLOO S V, et al. Electromagnetic shielding response of UV-induced polypyrrole/silver coated wool[J]. Fibers and Polymers, 2015,16(3):585-592.
[9] 董猛, 田俊莹. 聚吡咯/银导电涤纶织物的开发[J]. 印染, 2015(22):1-4.
DONG Meng, TIAN Junying. Development of polypyrrole/silver conductive polyester fabric[J]. China Dyeing & Finishing, 2015 (22):1-4.
[10] BABU K F, DHANDAPANI P, MARUTHAMUTHU S, et al. One pot synjournal of polypyrrole silver nanocomposite on cotton fabrics for multifunctional property[J]. Carbohydrate Polymers, 2012,90(4):1557-1563.
pmid: 22944416
[11] 张江茹. 聚吡咯基纳米复合粒子的合成、表征及应用研究[D]. 北京:北京化工大学, 2012: 1-16.
ZHANG Jiangru. Study on synthesis,characterization and application of polypyrrole-based nanocomposite particles[D]. Beijing:Beijing University of Chemical Technology, 2012: 1-16.
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