Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (05): 94-98.doi: 10.13475/j.fzxb.20190704206

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Application of berberine in polyacrylonitrile/cellulose acetate composite fiber dyeing

LIU Yanchun1,2, BAI Gang1,2()   

  1. 1. School of Textile and Apparel, Shaoxing University, Shaoxing, Zhejiang 312000, China
    2. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing, Zhejiang 312000, China
  • Received:2019-07-12 Revised:2019-10-04 Online:2020-05-15 Published:2020-06-02
  • Contact: BAI Gang E-mail:gbg2000@21cn.com

RichHTML

3

PDF (PC)

36

Abstract:

In order to widen the application domain of berberine, the physical and chemical properties of berberine were studied. Dyeing of polyacrylonitrile/cellulose acetate composite fibers with berberine was also investigated in this research. The dyeing process of polyacrylonitrile/cellulose acetate composite fiber with berberine was optimized through the use of orthogonal test. The dyeing rate curve and adsorption isotherm were determined, and the antimicrobial activity of dyed samples against Staphylococcus aureus and Escherichia coli was tested. The results indicate that berberine can be dissolved in water, and it has good acid and alkali resistance in the pH range of 3-11 and good thermal stability below 120 ℃. The dyeing adsorption isotherm of berberine on polyacrylonitrile/cellulose acetate composite fiber present Langmuir sorption model. The half dyeing time of berberine is 15.5 minutes, and the percentage of equilibrium dyeing is 97%. The best dyeing condition of berberine is found to be: dyeing temperature is 100 ℃, dyeing time is 40 min, dyeing pH value is 8. After dyeing, the bacteriostatic rate of polyacrylonitrile/cellulose acetate composite fiber to Staphylococcus aureus and Escherichia coli is over 92%.

Key words: berberine, natural dye, polyacrylonitrile/cellulose acetate composite fiber, physical and chemical properties, fiber dyeing, antimicrobial property

CLC Number: 

  • TS193.62

Fig.1

Visible spectrum of berberine"

Tab.1

Effect of pH on stability of berberine"

pH值 λmax/nm 吸光度A
3 420 0.270
5 419 0.271
7 421 0.266
9 420 0.268
11 420 0.263

Tab.2

Effect of temperature on heat-stability of berberine"

温度/℃ λmax/nm 吸光度A
40 419 0.272
60 421 0.269
80 421 0.274
100 419 0.274
120 420 0.272

Fig.2

TG and DTA curves of berberine"

Tab.3

Factors and levels of orthogonal experiments for dyeing"

水平 A B C
染色温度/℃ 保温时间/min pH值
1 40 10 5
2 60 20 7
3 80 30 8
4 100 40 9

Tab.4

Results of orthogonal experiments for dyeing"

试验号 A B C K/S值
1 1 1 1 2.784 2
2 1 2 2 3.345 1
3 1 3 3 4.427 6
4 1 4 4 4.158 1
5 2 1 2 4.791 4
6 2 2 1 5.383 6
7 2 3 4 5.624 4
8 2 4 3 5.916 2
9 3 1 3 5.612 1
10 3 2 4 6.536 2
11 3 3 1 6.335 7
12 3 4 2 6.714 8
13 4 1 4 6.428 6
14 4 2 3 7.165 8
15 4 3 2 6.802 5
16 4 4 1 6.512 9
K1 3.679 4.904 5.254
K2 5.429 5.608 5.413
K3 6.300 5.798 5.780
K4 6.727 5.825 5.687
R 3.048 0.921 0.526

Fig.3

Rate of berberine dyeing curves"

Fig.4

Adsorption isotherm of berberine"

Fig.5

Building-up property curve of berberine"

[1] 陈荣圻. 天然染料及其染色[J]. 染整技术, 2018,40(8):1-7.
CHEN Rongqi. Natural dyes and the dyeing[J]. Textile Dyeing and Finishing Journal, 2018,40(8):1-7.
[2] 陆水峰. 天然染料茶色素对棉织物的染色性能研究[J]. 针织工业, 2018,359(12):49-51.
LU Shuifeng. Dyeing properties of tea natural dye on cotton fabric[J]. Knitting Industries, 2018,359(12):49-51.
[3] NIDHAL Salem, KAMEL Msaada, SALEM Elkahoui, et al. Evaluation of antibacterial, antifungal, and antioxidant activities of safflower natural dyes during flowering[J]. BioMed Research International, 2014,2014:1-10.
[4] ARPANA Kamboj. Consumer awareness for natural dyes[J]. Indian Journal of Health & Wellbeing, 2017,8(9):1012-1014.
[5] 刘艳春, 白刚. 蚕丝的红曲红素生态媒染染色[J]. 纺织学报, 2012,33(4):78-81.
LIU Yanchun, BAI Gang. Bioecological mordant dyeing of silk with monascorubrin[J]. Journal of Textile Research, 2012,33(4):78-81.
[6] SHALINI Chandravanshi. Effect of ionic surfactants on the adsorption of quercus infectoria natural dye on cotton fiber: a kinetic study[J]. Journal of Dispersion Science & Technology, 2014,35(10):1427-1433.
[7] PARISA Hasanein, MASUMEH Ghafari-Vahed, IRAJ Khodadadi. Effects of isoquinoline alkaloid berberine on lipid peroxidation, antioxidant defense system, and liver damage induced by lead acetate in rats[J]. Redox Report. 2017,22(1):42-50.
pmid: 26871196
[8] MISTRY Bhupendra, KEUM Young Soo, KIM Doo Hwan. Synjournal, antioxidant and anticancer screenings of berberine-indole conjugates[J]. Research on Chemical Intermediates, 2016,42(4):3241-3256.
[9] ZHOU Yan, LIU Shiqing. Sustained release effects of berberine-loaded chitosan microspheres on in vitro chondrocyte culture[J]. Drug Development & Industrial Pharmacy, 2017,43(10):1703-1714.
doi: 10.1080/03639045.2017.1339076 pmid: 28585864
[10] 严涌, 邓东海, 江大伦. 醋青/改性涤纶/棉织物染色及牢度提升[J]. 印染, 2018,44(18):29-32.
YAN Yong, DENG Donghai, JIANG Dalun. Dyeing and fastness improvement of acetate acrylic/modified polyester/cotton fabric[J]. China Dyeing & Finising, 2018,44(18):29-32.
[1] QIN Yimin. Clinical applications of silver containing alginate wound dressings [J]. Journal of Textile Research, 2020, 41(09): 183-190.
[2] ZHAN Liuxiang, LI Wan, WANG Gaojun, ZHAO Xianli, WANG Ni, LI Yuling. Applied research progress of microwave treatment in protein fiber processing [J]. Journal of Textile Research, 2020, 41(08): 128-134.
[3] LIN Jiameng, WAN Ailan, MIAO Xuhong. Preparation and properties of polypyrrole/silver conductive polyester fabrics [J]. Journal of Textile Research, 2020, 41(03): 113-117.
[4] GAO Jing, ZHANG Jun, ZHAO Zeyang, LI Wandi, WANG Jiajun, WANG Lu. Antibacterial durability and wearability of polyester/cotton fabric modified collaboratively by graphene oxide and TiO2/SiO2 [J]. Journal of Textile Research, 2019, 40(10): 120-126.
[5] . Research progress of microbial pigments used in textile dyeing [J]. JOURNAL OF TEXTILE RESEARCH, 2017, 38(01): 163-168.
[6] . Influence of dye solution pH value on dyeing effects and antibacterial properties of wool fabrics dyed with tea natural dye [J]. JOURNAL OF TEXTILE RESEARCH, 2016, 37(11): 86-91.
[7] . Over dyeing of trssah sild with indigo naturalis and turmeric [J]. JOURNAL OF TEXTILE RESEARCH, 2013, 34(9): 73-0.
[8] . Extraction of berberine dye and its dyeing behavior on nylon 6 fabric [J]. JOURNAL OF TEXTILE RESEARCH, 2012, 33(9): 88-93.
[9] Qin Yimin;CAI Liling;ZHU Changjun. Antimicrobial properties of zinc alginate fibers [J]. JOURNAL OF TEXTILE RESEARCH, 2011, 32(2): 18-20.
[10] . Non-reactive modification of cotton and the application in the dyeing with natural dyes [J]. JOURNAL OF TEXTILE RESEARCH, 2010, 31(8): 86-91.
[11] LI Fengyan;UANG Qiaofen;HONG Caihong;ZHONG Zhili. Natural tea pigment dyeing of cotton fibers with Fe2+ as a mordanting agent [J]. JOURNAL OF TEXTILE RESEARCH, 2010, 31(7): 60-63.
[12] ZHU Changjun;FENG Deming;LU Youyou;QIN Yimin. Effect of acetylation on the properties of chitosan wound dressings [J]. JOURNAL OF TEXTILE RESEARCH, 2008, 29(4): 18-21.
[13] CAO Hongmei;CHENG Wanli. Effect of premordanting on dyeing properties of cotton fabrics dyed with natural dyes [J]. JOURNAL OF TEXTILE RESEARCH, 2008, 29(12): 53-56.
[14] HOU Xiuliang;ZHOU Qicheng;ZHANG Xinlong;WANG Lu;JIA Shunhua;HU Xiaofeng;WANG Shanyuan. Dyeing behavior of natural Flos Sophorae buds dyes and its dyeing process for wool fabrics [J]. JOURNAL OF TEXTILE RESEARCH, 2007, 28(8): 58-62.
[15] QIN Yimin. Preparation methods and properties of silver-contained alginate fibers [J]. JOURNAL OF TEXTILE RESEARCH, 2007, 28(2): 126-128.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备14006648号
Copyright 2021 © Editorial office of Journal of Textile Research
Supported by Beijing Magtech Co.Ltd