Journal of Textile Research ›› 2019, Vol. 40 ›› Issue (10): 120-126.doi: 10.13475/j.fzxb.20180907707

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Antibacterial durability and wearability of polyester/cotton fabric modified collaboratively by graphene oxide and TiO2/SiO2

GAO Jing(), ZHANG Jun, ZHAO Zeyang, LI Wandi, WANG Jiajun, WANG Lu   

  1. College of Textiles, Donghua University, Shanghai 201620, China
  • Received:2018-09-29 Revised:2019-07-05 Online:2019-10-15 Published:2019-10-23

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Abstract:

In order to solve the low photocatalytic efficiency, weak antibacterial activity and poor endurability of polyester/cotton fabrics modified by TiO2 under visible light, polyester/cotton fabrics were modified by the combination of graphene oxide(GO) and TiO2/SiO2. A field-emission microscope, antibacterial experiments in light and dark condition, color fastness of textiles, tensile fracture and flexural properties tests were adopted to analyze and evaluate micro-morphologies, antimicrobial properties and antibacterial durability, wearability of fabrics before and after the combined modification. The experimental results show that the nanoparticles dispersed uniformly and coated on the fabrics modified by GO and TiO2/SiO2 and the antibacterial rate of composite modified fabrics is over 99% under visible light. After 15 times of washing, the antibacterial rate of the composite modified fabrics is 98.5%. Meanwhile, the process has no significant negative effect on the tensile breaking properties, air permeability and hand feeling of the modified fabric.

Key words: TiO2, SiO2, graphene oxide, combinded modification, polyester/cotton fabric, antimicrobial property, wearability

CLC Number: 

  • TS195.6

Fig.1

FE-SEM images of fabrics. (a) Blank fabric(×200); (b) Fabric modified by TiO2(×200);(c) Fabric modified by TiO2/SiO2/GO (×200);(d) Blank fabric(×5 000);(e)Fabric modified by TiO2(×5 000);(f) Fabric modified by TiO2/SiO2/GO (×5 000)"

Fig.2

Bacterial residues in fabric culture dish"

Fig.3

Bacterial residues in different coated fabric culture dishes. (a)Blank fabric;(b) Fabric modified by TiO2; (c)Fabric modified by TiO2/SiO2/GO"

Tab.1

Antibacterial properties of fabric modified by TiO2/SiO2/GO after washing"

洗涤次数 对大肠埃希菌 对金黄色葡萄球菌
0 100.0 99.8
5 99.5 99.3
10 99.2 99.0
15 99.0 98.5

Tab.2

Breaking strength and breaking elongation before and after illumination"

样品 光照前 可见光照射12 h
断裂
强力/
N		 强力
CV
值/%		 断裂
伸长/
mm		 伸长
CV
值/%		 断裂
强力/
N		 强力
CV
值/%		 断裂
伸长/
mm		 伸长
CV
值/%
未改性织物 780.2 2.7 15.7 5.1 778.3 3.2 15.2 4.2
TiO2改性
织物		 732.1 7.9 13.7 3.5 730.5 6.8 12.8 5.2
TiO2/SiO2/
GO改性
织物		 745.2 5.8 15.0 3.2 738.2 6.5 13.5 3.4

Tab.3

Flexural properties of fabrics 10-2cN·cm·cm-1"

样品 弯曲刚度 弯曲滞后矩
未改性织物 1.78±0.07 2.66±0.28
TiO2改性织物 1.95±0.10 2.59±0.18
TiO2/SiO2/GO
复合改性织物		 1.86±0.04 1.80±0.04

Tab.4

Surface characteristics of fabrics"

样品 SMD/μm MIU MMD
未改性织物 3.315 ± 0.012 0.162 ± 0.004 0.010 ± 0.001
TiO2改性织物 3.638 ± 0.023 0.172 ± 0.008 0.012 ± 0.001
TiO2/SiO2/
GO改性织物		 3.628 ± 0.015 0.176 ± 0.007 0.014 ± 0.002

Fig.4

Whiteness of fabric before and after illumination"

[1] 罗敏. 纳米技术在纺织中的应用[J]. 化工新型材料, 2001,29(7):29-30.
LUO Min. Application of nano-technology in textile[J]. New Chemical Materials, 2001,29(7):29-30.
[2] 邓桦, 张纪梅, 李秀明, 等. 纳米二氧化钛多功能织物整理剂的制备与性能[J]. 纺织学报, 2006,27(3):92-94.
DENG Hua, ZHANG Jimei, LI Xiuming, et al. Man-ufacture and property of multi-functional nano-titanium dioxide finishing agents for fabric[J]. Journal of Textile Research, 2006,27(3):92-94.
doi: 10.1177/004051755702700202
[3] 么丹阳, 巫晓华, 毛雪峰, 等. 银纳米颗粒/二氧化钛/醋酸纤维素复合纤维的制备及其性能[J]. 纺织学报, 2016,37(4):15-20.
YAO Danyang, WU Xiaohua, MAO Xuefeng, et al. Preparation and characterization of silver nanopar- ticles/TiO2/cellulose acetate composite nanofibers[J]. Journal of Textile Research, 2016,37(4):15-20.
[4] 冯静, 杜英英, 邢彦军. 钨杂二氧化钛负载棉织物的微波法制备及光催化性能[J]. 纺织学报, 2014,35(7):88-93.
FENG Jing, DU Yingying, XING Yanjun. Microwave-assisted low temperature in-situ synjournal and coating of Tungsten-doped TiO2 onto cotton fabric and photocatalytic performance of coated fabric[J]. Journal of Textile Research, 2014,35(7):88-93.
doi: 10.1177/004051756503500114
[5] 吴海培, 高晓红, 方婧, 等. 二氧化钛/还原氧化石墨烯复合材料的制备及其光催化降解脱色性能[J]. 纺织学报, 2018,39(12):78-83.
WU Haipei, GAO Xiaohong, FANG Jing, et al. Preparation and photocatalytic degradation decoloring of TiO2/reduced graphene oxide composites[J]. Journal of Textile Research, 2018,39(12):78-83.
doi: 10.1177/004051756903900112
[6] CHEN J R, QIU F X, XU W Z, et al. Recent progress in enhancing photocatalytic efficiency of TiO2-based materials[J]. Applied Catalysis A: General, 2015,495:131-140.
doi: 10.1016/j.apcata.2015.02.013
[7] 谭奇. TiO2及其石墨烯基复合材料的制备与应用研究[D]. 长沙:湖南大学, 2017: 38.
TAN Qi. Study on the preparation and application of TiO2 and its graphene-based composite[D]. Changsha: Hunan University, 2017: 38.
[8] 贾佳. 纳米洋葱碳/二氧化钛/二氧化硅复合材料的制备及其光催化性能的研究[D]. 太原:太原理工大学, 2018: 34.
JIA Jia. Study on the preparation and photocatalytic properties of carbon nano onions/titanium dioxide/silicon dioxide nanocomposites[D]. Taiyuan:Taiyuan University of Technology, 2018: 34.
[9] PAKDEL E, DAOUD W A, SEYEDIN S. Tunable photocatalytic selectivity of TiO2/SiO2 nanocomposites: effect of silica and isolation approach[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018,552:130-141.
doi: 10.1016/j.colsurfa.2018.04.070
[10] PANWAR K, JASSAL M, AGRAWAL A K. TiO2-SiO2 Janus particles for photocatalytic self-cleaning of cotton fabric[J]. Cellulose, 2018,25(4):2711-2720.
doi: 10.1007/s10570-018-1698-2
[11] LU Y, ZHANG X, CHU Y C, et al. Cu2O nanocrystals/TiO2 microspheres film on a rotating disk containing long-afterglow phosphor for enhanced round-the-clock photocatalysis[J]. Applied Catalysis B: Environmental, 2018,224:239-248.
doi: 10.1016/j.apcatb.2017.10.054
[12] RAMAMOORTHY V, KANNAN K, THIRIPURANTH AGAN S. MA photocatalytic degradation of textile rea- ctive dyes-a comparative study using nano silver decorated titania-silica composite photocatalysts[J]. Journal of Nanoscience and Nanotechnology, 2018,18(4):2921-2930.
doi: 10.1166/jnn.2018.14304 pmid: 29442975
[13] KHAN H, JIANG Z R, BERK D. Molybdenum doped graphene/TiO2 hybrid photocatalyst for UV/visible pho- tocatalytic applications[J]. Solar Energy, 2018,162:420-430.
doi: 10.1016/j.solener.2018.01.055
[14] KARIMI L, YAZDANSHENAS M E, KHAJAVI R, et al. Functional finishing of cotton fabrics using graphene oxide nanosheets decorated with titanium dioxide nano-particles[J]. Journal of The Textile Institute, 2016,107(9):1122-1134.
doi: 10.1080/00405000.2015.1093311
[15] 李洋, 梁莹, 刘洋, 等. 二氧化钛-氧化石墨烯复合物去除水中有机污染物的性能研究[J]. 水资源与水工程学报, 2018,29(4):103-109.
LI Yang, LIANG Ying, LIU Yang, et al. Performance of TiO2-GO composites on removing organic pollutants in water[J]. Journal of Water Resources & Water Enginee-ring, 2018,29(4):103-109.
[16] 吴珂琦, 王旭东, 张亚. 纳米二氧化钛/氧化石墨烯的制备及对水中污染物的去除性能研究[J]. 化学世界, 2018,59(2):120-128.
WU Keqi, WANG Xudong, ZHANG Ya. Studies on preparation and elimination properties of TiO2/graphene oxide composites[J]. Chemical World, 2018,59(2):120-128.
[17] QI K H, CHEN X Q, LIU Y Y, et al. Facile preparation of anatase/SiO2 spherical nanocomposites and their application in self-cleaning textiles[J]. Journal of Materials Chemistry, 2007,17(33):3504-3508.
doi: 10.1039/b702887c
[18] 张联盟, 黄学辉, 宋晓岚. 材料科学基础[M]. 2 版. 武汉: 武汉理工大学出版社, 2008: 57.
ZHANG Lianmeng, HUANG Xuehui, SONG Xiaolan. Fundamentals of Materials Science[M].2nd ed. Wuhan: Wuhan University of Technology Press, 2008: 57.
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