Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (01): 102-109.doi: 10.13475/j.fzxb.20180906408

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and far-infrared emission performance of graphene based zirconium/titanium composites modified cotton fabrics

YI Ling, ZHANG He(), FU Xin, LI Wen   

  1. College of Materials and Chemical Engineering, Hunan Institute of Engineering, Xiangtan, Hunan 411104, China
  • Received:2018-09-26 Revised:2019-10-22 Online:2020-01-15 Published:2020-01-14
  • Contact: ZHANG He E-mail:mzhang_he@126.com

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Abstract:

In order to further improve the far-infrared emission characteristics of graphene-based nanocomposites, zirconia/titania/reduced graphene oxide (ZrO2/TiO2-rGO) nanocomposites were prepared by one-step hydrothermal modification of graphene oxide with zirconia/titanium oxide. Cotton fabrics with far-infrared emissivity were prepared by combining ZrO2/TiO2-rGO with the textiles using water-soluble polyurethane as binder. The morphology and internal structure of ZrO2/TiO2-rGO composites were characterized by scanning electron microscopy and Fourier transform infrared spectroscopy, and the far infrared emission properties of modified cotton fabrics were characterized by far infrared emissivity and infrared thermal imaging technology. The results show that at 120 ℃ for 4 reaction hours, the far-infrared emissivity of the treated cotton fabric was about 2.5% higher than that of the untreated cotton fabric when the mass ratio of graphene oxide,titanium dioxide,zirconium oxychloride was 5∶3∶2. This method could effectively reduce the content of graphene and provide good far-infrared emission performance with low cost.

Key words: functional finishing of cotton fabric, hydrothermal, graphene oxide, zirconium/titaniumoxide, composite, water soluble polyurethane, far infrared emission rate

CLC Number: 

  • TQ421.2

Fig.1

Principle of ZrO2/TiO2-rGO composites preparation"

Fig.2

SEM image of graphene oxide (×10 000)"

Fig.3

Infrared spectrogram of graphene oxide"

Fig.4

SEM image of ZrO2/TiO2-rGO composites"

Fig.5

Infrared spectra of ZrO2/TiO2-rGO composites"

Fig.6

Dispersion of composite materials in water under different conditions. (a) At different temperatures (4 h); (b) At different time conditions (120 ℃); (c) Under different proportions of graphene oxide, titanium dioxide and zirconium oxychloride"

Tab.1

Far infrared emission effect of traditional far infrared textiles"

样品 有效成分 有效成分
用量/%		 远红外
发射率/%
丙纶远红外纤维 电气石母粒 8 82
聚酯远红外纤维 TiO2-SiO2-Cr2O3 3 85
棉远红外织物 陶瓷粉 6 86
涤纶/丙纶/锦纶远红外织物 Fe2O3、BeO、SrO、SiO2、CaO、MnO2 8 87
后整理远红外织物 六环石 5 85

Tab.2

Far infrared emissivity of ZrO2/TiO2-rGO composites modified cotton fabric"

样品 远红外发射率/%
未水洗 水洗10次 水洗20次
未处理织物 86.8 86.5 86.5
水性聚氨酯整理织物 86.3 86.4 86.4
ZrO2整理织物 87.7 87.1 86.2
TiO2整理织物 87.2 87.0 86.3
复合材料改性织物(4:3:3) 87.6 87.8 87.5
复合材料改性织物(5:3:2) 89.3 89.5 89.2
复合材料改性织物(6:2:2) 89.0 88.9 88.9
复合材料改性织物(7:2:1) 88.5 88.6 88.3
复合材料改性织物(8:1:1) 88.0 88.2 88.0
GO整理织物 88.2 88.1 88.1

Fig.7

Infrared thermography of untreated cotton fabric and modified cotton fabric. (a)Untreated cotton fabric;(b) Polyurethane finishing cotton fabric; (c)Cotton fabric treated with ZrO2; (d) Cotton fabric treated with TiO2;(e)Composites modified cotton fabric (4:3:3); (f) Composites modified cotton fabric (5:3:2);(g) Composites modified cotton fabric (6:2:2); (h) Composites modified cotton fabric (7:2:1);(i) Composites modified cotton fabric (8:1:1); (j) Cotton fabric treated with GO"

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