Journal of Textile Research ›› 2020, Vol. 41 ›› Issue (10): 14-19.doi: 10.13475/j.fzxb.20190902506

• Fiber Materials • Previous Articles     Next Articles

One-pot synthesis and characterization of aminated cellulose nanocrystals

LU Linna1,2, LI Yonggui1,2, LU Qilin1,2()   

  1. 1. Fujian Key Laboratory of Novel Functional Textile Fibers and Materials, Minjiang University, Fuzhou, Fujian 350108, China
    2. Clothing and Design Faculty, Minjiang University, Fuzhou, Fujian 350108, China
  • Received:2019-09-06 Revised:2020-07-12 Online:2020-10-15 Published:2020-10-27
  • Contact: LU Qilin E-mail:qilinlu@mju.edu.cn

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Abstract:

In order to realize green preparation of nanocellulose derivatives, ammonium persulfate was used to oxidize bamboo pulp fibers to obtain carboxylated nanocellulose (CNC) under microwave-hydrothermal condition based on mechanical force chemistry. Then condensation reaction between CNC and diethylenetriamine was carried out in the aqueous phase to realize the one-pot synthesis of aminated nanocellulose (ACNC), and its properties were explored. The results show that ACNC is rod-shaped with a diameter of 10-40 nm and a length of 50-300 nm, and the grafting ratio of ACNC is 6.29%. The crystal form of ACNC is still cellulose type I, besides the crystallinity increases from 59% to 79%. The thermal stability of ACNC is not significantly lower than that of bamboo fiber, but it is significantly higher than that of CNC, indicating that the thermal stability of CNC is improved after grafting amino groups. The preparation method is green and efficient, and the obtained cellulose derivatives are expected to play a role in the field of biosolidification and physical property enhancement.

Key words: aminated cellulose nanocrystal, mechanochemistry, ammonium persulfate, microwave-hydrothermal, one-pot

CLC Number: 

  • TS131.9

Fig.1

Amidation reaction of CNC"

Fig.2

FT-IR spectra of bamboo pulp, CNC and ACNC"

Fig.3

Structure of cellulose"

Fig.4

13C NMR spectra of bamboo pulp, CNC and ACNC"

Tab.1

Element contents of CNC and ACNC%"

样品名称 N C H
CNC 0.09 42.45 6.48
ACNC 1.84 42.78 6.65

Fig.5

TEM images of CNC and ACNC"

Fig.6

XRD patterns of bamboo pulp, CNC and ACNC"

Fig.7

TG and DTG curves of bamboo pulp, CNC and ACNC"

Tab.2

Thermodynamic parameters of bamboo pulp, CNC and ACNC"

样品
名称		 初始分解
温度/℃		 最大质量损
失速率/℃		 质量损
失率/%
竹浆粕 338.8 364.2 89.5
CNC 256.5 325.8 64.2
ACNC 310.9 342.2 66.1
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