Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (08): 126-131.doi: 10.13475/j.fzxb.20210401806

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Preparation and decolorization of iron-based metal\|organic framework/activated carbon fiber composites

WANG Jing, LOU Yaya, WANG Chunmei()   

  1. School of Textile and Clothing, Nantong University, Nantong, Jiangsu 226019, China
  • Received:2021-04-07 Revised:2022-05-26 Online:2022-08-15 Published:2022-08-24
  • Contact: WANG Chunmei E-mail:w.cmei@ntu.edu.cn

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Abstract:

In order to improve the reusability of iron-based metal\|organic framework (MOF(Fe)), MOF(Fe)/activated carbon fiber composites (MOF(Fe)/ACF) were prepared by in-situ growth at room temperature using pyromellitic acid, ferrous sulfate and activated carbon fiber (ACF). The structure, morphology and elemental composition of the composites were characterized by Fourier transform infrared spectrometer, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. The decolorization of composites on 50 mg/L Reactive Black KN–B was tested under different conditions, and the mechanism of photocatalytic degradation of dye was discussed. The results showed that the decolorization ratio of composite material on Reactive Black KN–B was 64.7％ after 60 min reaction without hydrogen peroxide and 80.2％ with 0.12 mL/L hydrogen peroxide. Under the condition of 1 000 W xenon lamp illumination, adding 0.12 mL/L hydrogen peroxide and reacting for 60 min, the decolorization ratio of MOF(Fe)/ACF for Reactive Black KN–B became 95.7％, 52.2％ higher than that of the ACF. After five times reuse, the decolorization ratio of MOF(Fe)/ACF could still reach 86.0％.

Key words: metal-organic framework, activated carbon fiber, dye decolorization, photo catalysis, dyeing wastewater, wastewater treatment

CLC Number: 

  • X703.1

Fig.1

FT-IR spectra of ACF, MOF(Fe) and MOF(Fe)/ACF"

Fig.2

SEM images of ACF and MOF(Fe)/ACF (×5 000)"

Fig.3

EDS spectra of ACF and MOF(Fe)/ACF"

Fig.4

XRD patterns of ACF and MOF(Fe)/ACF"

Fig.5

Decolorization ratio of ACF and MOF(Fe)/ACF under dark condition"

Fig.6

Decolorization ratio of ACF and MOFC(Fe)/ACF with hydrogen peroxide added to dye solution under dark condition"

Fig.7

Decolorization ratio of ACF and MOF(Fe)/AFC with hydrogen peroxide added to dye solution under light condition"

Fig.8

Reuse decolorization ratio of MOF(Fe)/ACF"

Fig.9

Effect of different trapping agents on decolorization ratio under light condition"

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