聚丙烯酸酯浆料废水处理中试研究

doi:10.13475/j.fzxb.20180106106

纺织学报 ›› 2019, Vol. 40 ›› Issue (01): 108-113.doi: 10.13475/j.fzxb.20180106106

聚丙烯酸酯浆料废水处理中试研究

汪风波¹, 王加毅², 孙正³, 马颜雪⁴, 吕迎智³, 张魏峰², 吕艳³, 吕明明³, 陈思雨¹, 李毓陵⁴, 陈小光¹()

1.东华大学环境科学与工程学院, 上海 201620
2.中国长丝织造协会, 北京 100020
3.岜山集团有限公司,山东淄博 255000
4.东华大学纺织学院, 上海 201620

收稿日期:2018-01-30 修回日期:2018-06-06 出版日期:2019-01-15 发布日期:2019-01-18
通讯作者: 陈小光
作者简介:汪风波(1993—),男,硕士生。主要研究方向为废水生物处理过程及设备。
基金资助:
中央高校基本科研业务费专项资金资助项目(2232017A3-10);上海自然科学基金项目(17ZR1400300);岜山集团有限公司产学研资助项目(2017310031000251)

Pilot study on treatment of polyacrylate sizing wastewater

WANG Fengbo¹, WANG Jiayi², SUN Zheng³, MA Yanxue⁴, LÜ Yingzhi³, ZHANG Weifeng², LÜ Yan³, LÜ Mingming³, CHEN Siyu¹, LI Yuling⁴, CHEN Xiaoguang¹()

1. College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China
2. China Filament WeavingAssociation, Beijing 100020, China
3. Bashan Weaving Group Co., Ltd., Zibo, Shandong 255000, China
4. College of Textiles, Donghua University, Shanghai 201620, China

Received:2018-01-30 Revised:2018-06-06 Online:2019-01-15 Published:2019-01-18
Contact: CHEN Xiaoguang

摘要/Abstract

摘要：

针对聚丙烯酸酯浆料废水高浓度难降解以及成分单一等特点,采用基于共代谢的厌氧-好氧专利反应器组合工艺的生物处理方法对其进行中试试验,重点考察反应器的启动运行特征以及反应器的性能。试验结果表明:基于提高聚酯废水占比的启动方式,该系统启动周期约为30 d;在进水化学需氧量(COD)质量浓度为1 600 mg/L时,厌氧段水力停留时间为41.7 h,中温为(35±3)℃;在好氧段溶解氧质量浓度为3.5 mg/L的工况下,该系统对COD平均去除率为95.2%,最终出水各项主要指标均达到纺织染整工业水污染物排放标准,且该系统具有较强的耐负荷冲击能力。

关键词: 浆纱, 聚丙烯酸酯, 浆料废水, 中试试验, 废水处理

Abstract:

In view of the characteristics of polyacrylate wastewater, such as high concentration, hard degradation and single component, a biological treatment method adopting an anaerobic-aerobic reactor based on co-metabolism was studied, focusing on the startup operating of and the performance of the reactor. The results show that the system operating cycle is about 30 d on the basis of increasing the ratio of polyester wastewater. Besides, under the conditions of concentration of chemical oxygen demand (COD) 1 600 mg/L, hydraulic residence time (HRT) of 41.7 h, temperature of (35±3) ℃ and concentration of dissolved orygen (DO) 3.5 mg/L, the average removal rate of COD is 95.2%. The main indexes of the final effluent reaches the water pollutant emission standard of textile dyeing and finishing industry. It is also proved that the system has strong load impact resistance.

Key words: sizing, polyacrylate, sizing wastewater, pilot study, wastewater treatment

中图分类号:

X703

汪风波, 王加毅, 孙正, 马颜雪, 吕迎智, 张魏峰, 吕艳, 吕明明, 陈思雨, 李毓陵, 陈小光. 聚丙烯酸酯浆料废水处理中试研究[J]. 纺织学报, 2019, 40(01): 108-113.

WANG Fengbo, WANG Jiayi, SUN Zheng, MA Yanxue, LÜ Yingzhi, ZHANG Weifeng, LÜ Yan, LÜ Mingming, CHEN Siyu, LI Yuling, CHEN Xiaoguang. Pilot study on treatment of polyacrylate sizing wastewater[J]. Journal of Textile Research, 2019, 40(01): 108-113.

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参考文献 14

[1]	杨明杰, 武海良, 沈艳琴, 等. 中低温条件下聚乳酸长丝的上浆机制[J]. 纺织学报, 2017,38(3):85-90.
	YANG Mingjie, WU Hailiang, SHEN Yanqin, et al. Sizing of polylactic acid filaments at lower tempera-ture[J]. Journal of Textile Research, 2017,38(3):85-90.
[2]	赵玉芬, 李嘉禄, 宋磊磊, 等. 上浆剂对国产碳化硅纤维表面及其织造性能的影响[J]. 纺织学报, 2017,38(3):78-84.
	ZHAO Yufen, LI Jialu, SONG Leilei, et al. Influence of sizing agent on surface and weaving performance of SiC fibers[J]. Journal of Textile Research, 2017,38(3):78-84.
[3]	汪风波, 陈小光, 马颜雪, 等. 厌氧生物法处理聚丙烯酸酯浆料废水[J]. 中国给水排水, 2017,34(13):115-119.
	WANG Fengbo, CHEN Xiaoguang, MA Yanxue, et al. Treatment of polyacrylate wastewater by anaerobic biological process[J]. China Water & Wastewater, 2017,34(13):115-119.
[4]	陈小光. 一种螺旋对称流厌氧反应器:102583731A[P]. 2012-03-02.
	CHEN Xiaoguang. A spiral symmetry stream anaerobic bioreactor: 102583731A[P]. 2012-03-02.
[5]	DAI R, CHEN X, LUO Y, et al. Inhibitory effect and mechanism of azo dyes on anaerobic methanogenic wastewater treatment: can redox mediator remediate the inhibition?[J]. Water Research, 2016,104:408-417. doi: 10.1016/j.watres.2016.08.046 pmid: 27579869
[6]	CHEN X, DAI R, XIANG X, et al. Shock resistance characteristic of a spiral symmetry stream anaerobic bio-reactor.[J]. Water Science & Technology, 2016,73(4):916. doi: 10.2166/wst.2015.564 pmid: 26901736
[7]	陈小光一种气升式外循环涡流旋强化生物脱氮反应器:104085986A[P]. 2014-10-08.
	CHEN Xiaoguang. Air-lift external circulation vortex enhancement nitrogen removal fluidized bed bioreactor: 104085986A[P]. 2014-10-08.
[8]	胡涛, 陈小光, 王玉, 等. 气升式外循环涡旋强化生物脱氮反应器运行特性[J]. 环境工程学报, 2017,11(5):2723-2730.
	HU Tao, CHEN Xiaoguang, WANG Yu, et al. Operation characteristics of air-lift external circulation vortex enhancement nitrogen removal bioreactor[J]. Chinese Journal of Environmental Engineering, 2017,11(5):2723-2730.
[9]	徐金兰, 黄廷林, 王志盈. 厌氧折流板反应器处理难降解PVA废水[J]. 中国环境科学, 2005,25(1):65-69.
	XU Jinlan, HUANG Tinglin, WANG Zhiying. Anaerobic baffled reactor (ABR) treatment of hardly degraded PVA wastewater[J]. China Environmental Science, 2005,25(1):65-69.
[10]	刘浩, 王军, 奚旦立. 水解酸化/SMBR处理含PVA退浆废水的研究[J]. 中国给水排水, 2007,23(21):98-101.
	LIU Hao, WANG Jun, XI Danli. Study on combined process of hydrolytic acidification and SMBR for treatment of PVA-containing desizing wastewater[J]. China Water & Wastewater, 2007,23(21):98-101.
[11]	王志刚, 段士然, 崔双科, 等. 聚乙烯醇+淀粉模拟退浆废水的小试处理研究[J]. 西安工程大学学报, 2013,27(3):354-358.
	WANG Zhigang, DUAN Shiran, CUI Shuangke, et al. Study on the treatment of simulated desizing wastewater with polyvinyl alcohol and starch[J]. Journal of Xi'an Poletechnic University, 2013,27(3):354-358.
[12]	汪林, 罗轶群, 张炜铭, 等. 高效厌氧反应器处理中药提取废水中试研究[J]. 工业水处理, 2017,37(2):56-59.
	WANG Lin, LUO Yiqun, ZHANG Weiming, et al. Pilot-scale study on the highly efficient anaerobic reactor for the treatment of traditional Chinese medicine extract wastewater[J]. Industrial Water Treatment, 2017,37(2):56-59.
[13]	DONG F, ZHAO Q B, ZHAO J B, et al. Monitoring the re-start-up of an upflow anaerobic sludge blanket (UASB) reactor for the treatment of a soybean processing wastewater[J]. Bioresource Technology, 2010,101(6):1722-1726. doi: 10.1016/j.biortech.2009.10.011 pmid: 19896839
[14]	许敬亮, 高勇生, 陈立伟, 等. 运行负荷对酶制剂废水厌氧颗粒污泥形成的影响[J]. 环境科学学报, 2005,25(3):379-384.
	XU Jingliang, GAO Yongsheng, CHEN Liwei, et al. Effectsof organic load on the formation of anaerobic granular sludge forzymin wastewater treatment[J]. Acta Scientiae Circumstantiae, 2005,25(3):379-384.

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废水种类	COD/ (mg·L^-1)	氨氮质量浓度/ (mg·L^-1)	pH值
生活污水	244.8~310.6	43.28~60.74	7.26~ 8.06
浆料废水	862.8~4 103.2	19.2~91.3	6.76~7.29

项目	COD/ (mg·L^-1)	氨氮质量浓度/ (mg·L^-1)	pH值	B/C
浆料废水	1 610.8	35.8	6.76	0.031
厌氧进水	1 562.1	54.3	6.97	0.156
厌氧出水	921.6	116.3	7.42	0.287

工艺名称	原水类型	进水水力停留时间/h	进水COD/ (mg·L^-1)	COD去除率/%	废水体积/ L	试验类型	参考文献
SSSAB+AFB	浆料废水	41.7	1 600	95.2(41.1+54.1)	1 000	中试	本文
ABR	PVA废水	48	1 200	80	28	小试	[10]
厌氧+SMBR	PVA废水	30	1 000	95(20+75)	360	中试	[11]
水解酸化+好氧	PVA废水	24	1 300	89~95	50	小试	[12]

时期	平均粒径/ mm	平均沉降速度/(m·h^-1)	辅酶F420浓度/ (μmol·g^-1)
启动前	2.62	72.47	—
启动完成	3.46	107.39	0.17

聚丙烯酸酯浆料废水处理中试研究

Pilot study on treatment of polyacrylate sizing wastewater

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