阻燃剂对聚氯乙烯/聚酯复合材料性能的影响

doi:10.13475/j.fzxb.20180200705

纺织学报 ›› 2019, Vol. 40 ›› Issue (01): 103-107.doi: 10.13475/j.fzxb.20180200705

阻燃剂对聚氯乙烯/聚酯复合材料性能的影响

赵青华¹^,²(), 毛秦岑², 梅涛¹, 牛应买², 王栋¹^,²^,³

1.武汉纺织大学材料科学与工程学院, 湖北武汉 430200
2.湖北省纺织新材料及其应用重点实验室, 湖北武汉 430200
3.东华大学化学化工与生物工程学院, 上海 201620

收稿日期:2018-02-01 修回日期:2018-10-14 出版日期:2019-01-15 发布日期:2019-01-18
作者简介:赵青华(1984—),男,中级实验师,硕士。主要研究方向为纤维织物复合材料成型与制备。E-mail: zhaoqh108@126.com
基金资助:
国家重点研发计划项目(2016YFC0206101)

Effect of flame retardant on properties of polyvinyl chloride/polyester composites

ZHAO Qinghua¹^,²(), MAO Qincen², MEI Tao¹, NIU Yingmai², WANG Dong¹^,²^,³

1. Material Science and Engineering Institute, Wuhan Textiles University, Wuhan, Hubei 430200, China
2. Hubei New Textile Material & Application Key Laboratory, Wuhan, Hubei 430200, China
3. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China

Received:2018-02-01 Revised:2018-10-14 Online:2019-01-15 Published:2019-01-18

摘要/Abstract

摘要：

为解决聚氯乙烯(PVC)/聚酯(PET)复合材料阻燃性能相对于纯聚氯乙烯、聚酯阻燃性能下降的问题,在聚氯乙烯/环己酮溶液中添加5种不同阻燃机制的阻燃剂,利用自动涂膜机将其涂覆在聚酯机织物上制备得到极限氧指数大于28%可应用于建筑领域的聚氯乙烯/聚酯复合材料。借助极限氧指数测试仪、接触角测试仪、可见光透过率测试仪对PVC/PET复合材料的性能进行表征。结果表明:主要成分为烯丙基苯并三唑的阻燃剂对PVC/PET复合材料有良好的阻燃效果,当PVC涂层中阻燃剂质量分数为10%,涂层厚度为1.35 mm时,其透光率为5%,极限氧指数为30%,可满足建筑膜材料的使用要求。

关键词: 聚氯乙烯/聚酯复合材料, 阻燃性能, 极限氧指数, 透光率

Abstract:

In order to solve the problem that the flame retardant performance of polyvinyl chloride (PVC)/polyester (PET) composites was lower than that of PVC and polyester. The PET fabric-reinforced PVC composites with the limit oxygen index grenter 28% were prepared by adding different retardants in the PVC/cyclohexanone solution, and coating an polyester fabric. The properties of flame retardant, light transmission and self-cleaning of PVC/PET composites were evaluated by a limiting oxygen index tester, a contact angle tester and a visible light transmittance tester, respectively. The results demonstrate that flant redardant maihly contaraing allyl benzotriazole (WSA-105) has good flame-retardant performance for PVC/PET composites. Moreover, the effects of different concentrations of WSA-105 and different thicknesses of PVC coating on limiting oxygen index, contact angle and light transmittance of the PVC/PET fabric composite were studied, and the results indicate that the light transmittance is 5% and the limiting oxygen index is 30% with the flame retardant concentration of 10% and the coating thickness of 1.35 mm for construction membrane materials.

Key words: polyvinyl chloride/polyester composite, flame-retardancy, limit oxygen index, light transmittance

中图分类号:

TS106.5

赵青华, 毛秦岑, 梅涛, 牛应买, 王栋. 阻燃剂对聚氯乙烯/聚酯复合材料性能的影响[J]. 纺织学报, 2019, 40(01): 103-107.

ZHAO Qinghua, MAO Qincen, MEI Tao, NIU Yingmai, WANG Dong. Effect of flame retardant on properties of polyvinyl chloride/polyester composites[J]. Journal of Textile Research, 2019, 40(01): 103-107.

图/表 6

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参考文献 10

[1]	余洁峰, 俞建勇, 王善元. PET机织物增强PVC复合材料成型工艺探讨[J]. 中国纺织大学学报, 1995(4):10-15.
	YU Jiefeng, YU Jianyong, WANG Shanyuan. Discussion on forming process of PET woven fabric reinforced PVC composites[J]. Journal of China Textile University, 1995(4):10-15.
[2]	谈青豹, 王小林. 高压聚乙烯膜复合布的研制[J]. 产业用纺织品, 2002(6):19-21.
	TAN Qingbao, WANG Xiaolin. Development of high pressure polyethylene film composite fabric[J]. Technical Textiles, 2002(6), 19-21.
[3]	皮红, 郭云. PVC阻燃抑烟研究进展[J]. 聚氯乙烯, 2001(4):28-33.
	PI Hong, GUO Yun. Research progress of flame retardant and smoke suppressant of PVC[J]. Polyvinyl Chloride, 2001(4):28-33.
[4]	尹朝露, 李风, 张翔, 等. 无卤阻燃抗静电聚丙烯复合材料的研究[J]. 功能材料, 2015,S1(46):30-34.
	YI Zhaolu, LI Feng, ZHANG Xiang, et al. Study on halogen-free flame retardant and antistatic polypropylene composites[J]. Journal of Functional Materials, 2015,S1(46):30-34.
[5]	马敬红, 龚静华, 杨曙光, 等. 分子内阻燃PET纤维的结构性能[J]. 纺织学报, 2012,33(6):61-64.
	MA Jinghong, GONG Jinghua, YANG Shuguang, et al, Structural properties of flame retardant PET fibers in the molecule[J]. Journal of Textile Research, 2012,33(6):61-64.
[6]	刘日华, 周荣星, 胡红. 涂层工艺对经编多轴向膜结构复合材料性能的影响[J]. 上海纺织科技, 2005(1):61-64.
7	LIU Rihua, ZHOU Rongxing, HU Hong. Effect of coating technology on the properties of multiaxial film structure composites made by warp knitting[J]. Shanghai Textile Technology, 2005(1):61-64.
[7]	张丽芝, 苏玉兰. 产业用多功能涂层织物的开发和应用[J]. 产业用纺织品, 1999(4):6-10.
	ZHANG lizhi, SU Yulan. Development and application of industrial multifunctional coated fabrics[J]. Technical Textiles, 1999 (4):6-10.
[8]	任元林, 张悦, 曾倩, 等. 织物阻燃涂层新工艺的研究进展[J]. 纺织学报, 2017,38(9):168-173.
	REN Yuanlin, ZHANG Yue, ZENG Qian, et al. Research progress on new technology of fabric flame retardant coating[J]. Journal of Textile Research, 2017,38(9):168-173.
[9]	金日光, 华幼卿. 高分子物理[M]. 北京: 化学工业出版社, 1999: 200-207.
	JIN Riguang, HUA Youqing. Polymer Physics[M]. Beijing: Chemical Industry Press, 1999: 200-207
[10]	任国宏, 段予忠. PVC压延制品性能影响因素分析[J]. 塑料开发, 2000,26(4):1454-1456.
	REN Guohong, DUAN Yuzhong, Influencing factors of PVC calendered product performance[J]. Plastic Development, 2000,26(4):1454-1456.

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阻燃剂对聚氯乙烯/聚酯复合材料性能的影响

Effect of flame retardant on properties of polyvinyl chloride/polyester composites

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