纺织学报 ›› 2019, Vol. 40 ›› Issue (03): 8-12.doi: 10.13475/j.fzxb.20180405305

• 纤维材料 • 上一篇    下一篇

熔融纺聚乳酸/聚丙烯纤维的制备及其性能

李晓川1, 瞿芊芊1, 李旭明1,2()   

  1. 1.绍兴文理学院 纺织服装学院, 浙江 绍兴 312000
    2.绍兴文理学院 浙江省清洁染整技术重点实验室, 浙江 绍兴 312000
  • 收稿日期:2018-04-23 修回日期:2018-11-29 出版日期:2019-03-15 发布日期:2019-03-15
  • 通讯作者: 李旭明
  • 作者简介:李晓川(1996—),男。主要研究方向为生物质纤维。
  • 基金资助:
    浙江省科技厅计划项目(2017C31115)

Preparation and properties of polylactic acid/polypropylene blend fiber by melt spinning

LI Xiaochuan1, QU Qianqian1, LI Xuming1,2()   

  1. 1. College of Textiles and Garments, Shaoxing University, Shaoxing, Zhejiang 312000, China
    2. Zheijiang Province Key Laboratory of Clean Dyeing and Finishing Technology, Shaoxing University,Shaoxing, Zhejiang 312000, China
  • Received:2018-04-23 Revised:2018-11-29 Online:2019-03-15 Published:2019-03-15
  • Contact: LI Xuming

摘要:

为提高聚乳酸(PLA)纤维的力学性能,采用聚丙烯(PP)与聚乳酸(PLA)通过熔融纺丝制备PLA/PP纤维,并借助差示扫描热量仪、热重分析仪、万能材料测试仪、纤维双折射仪对其热学性能、热稳定性、拉伸性能和纤维取向度进行表征。结果表明:PP的引入对PLA的玻璃化转变温度和熔融温度没有显著影响,但促进了PLA的结晶,结晶度提高了585.9%;随着PP质量分数的增加,PLA的热稳定性降低(特别是在初始分解阶段),但其残炭率提高,同时PLA/PP共混纤维的取向度提高,力学性能得到改善;当PP质量分数为20%时,PLA/PP共混纤维的取向度、断裂强度和断裂伸长率分别提高了55.6%,98.2%和44.4%。

关键词: 聚乳酸, 聚丙烯, 熔融共混, 熔融纺丝, 力学性能

Abstract:

In order to enhance the mechanical properties of polylactic acid (PLA) fiber, polypropylene(PP) was melt blended with PLA, then PLA/PP blend fiber was prepared by melt spinning. The thermal property, heat stability, tensile property and orientation degree of the PLA/PP fiber were tested using differential scanning calorimeter, thermal gravimetric analyzer, universal testing machine, fiber birefringence meter, respectively. The results show that the addition of PP has no significant effect on the glass transition temperature and melting temperature of PLA, but the crystallization behavior of PLA is improved, and the degree of crystallinity enhances by 585.9%. With the increasing of PP content, the heat stability of PLA is decreased, especially the initial decomposition temperature is decreased obviously, but the carbon yield is increased. Meanwhile , the degree of orientation and mechanical properties of the PLA/PP fiber are enhanced. When the PP mass fraction is 20%, the orientation degree, breaking strength and elongation at break of the PLA/PP fiber increase 55.6%, 98.2% and 44.4%, respectively.

Key words: polylactic acid, polypropylene, melt blending, melt spinning, mechanical property

中图分类号: 

  • TS102.5

图1

PLA/PP共混物的DSC升温曲线"

表1

PLA/PP共混物的热学性能"

样品
编号
Tg/
Tcc/
Tm/
ΔHcc/
(J·g-1)
ΔHm/
(J·g-1)
χc/
%
0# 63.37 165.99 -3.62 3.89
1# 63.38 97.75 167.62 15.87 -37.46 23.22
2# 63.06 96.59 167.12 14.40 -33.37 20.40
3# 63.73 97.25 167.82 13.18 -32.74 21.03
4# 63.21 96.37 167.06 13.21 -38.02 26.68

图2

PLA/PP共混物的热稳定性曲线"

图3

PLA和PLA/PP共混物的断面扫描电镜照片(×1 000)"

表2

牵伸倍数与PLA/PP共混纤维双折射率间的关系"

样品编号 双折射率
1.5倍牵伸 2.0倍牵伸 2.5倍牵伸
0# 10.6 15.2 19.8
1# 22.5 23.5 26.5
2# 23.1 24.2 30.3
3# 23.8 24.7 30.4
4# 25.2 24.8 30.8

图4

PP质量分数对PLA/PP纤维拉伸性能的影响"

表3

牵伸倍数与PLA/PP共混纤维力学性能间的关系"

牵伸
倍数
断裂强度/
(cN·dtex-1)
断裂
伸长率/%
双折射率
1.5 1.58 30.48 23.8
2.0 1.77 26.97 24.7
2.5 3.29 24.62 30.4
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