纺织学报 ›› 2020, Vol. 41 ›› Issue (03): 182-187.doi: 10.13475/j.fzxb.20190404806

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二维碳化物在柔性电磁吸波领域的研究进展

张恒宇1,2, 张宪胜3, 肖红2,4(), 施楣梧2   

  1. 1.东华大学 纺织学院, 上海 201620
    2.军事科学院系统工程研究院 军需工程技术研究所, 北京 100010
    3.青岛大学, 山东 青岛 266071
    4.武汉纺织大学, 湖北 武汉 430000
  • 收稿日期:2019-04-16 修回日期:2019-10-12 出版日期:2020-03-15 发布日期:2020-03-27
  • 通讯作者: 肖红
  • 作者简介:张恒宇(1996—),女,硕士生。主要研究方向为电磁屏蔽吸波纺织品的开发。
  • 基金资助:
    国家自然科学基金面上项目(51673211)

Research progress of two-dimensional carbide in field of flexible electromagnetic absorbing

ZHANG Hengyu1,2, ZHANG Xiansheng3, XIAO Hong2,4(), SHI Meiwu2   

  1. 1. College of Textiles, Donghua University, Shanghai 201620, China
    2. Institute of Quartermaster Engineering & Technology, Institute of System Engineering, Academy of Military Science, Beijing 100010, China
    3. Qingdao University, Qingdao, Shandong 266071, China
    4. Wuhan Textile University, Wuhan, Hubei 430000, China
  • Received:2019-04-16 Revised:2019-10-12 Online:2020-03-15 Published:2020-03-27
  • Contact: XIAO Hong

摘要:

针对传统电磁屏蔽材料因反射电磁波导致二次污染,现有吸波材料厚重、易腐蚀、柔韧性差、吸波频带窄等问题,归纳总结了新型二维过渡金属碳/氮化合物(MXene)及其柔性复合材料在吸波领域的应用研究。分析了MXene所具有的本征缺陷、官能团、高导电率、大的比表面积对吸波性能的影响,提炼出MXene及其柔性复合材料的吸波机制。指出MXene及其柔性复合材料可以通过改变化合物结构和形态结构、层层自组装、复合改性等方法,制备以吸收电磁波为主的电磁屏蔽材料,为新一代轻质超薄、柔性宽频、吸收型电磁屏蔽材料的发展及其在便携可穿戴电子设备上的应用提供了研究方向。

关键词: 二维过渡金属碳化物, 二维碳化物, 电磁屏蔽, 吸波, 柔性复合材料

Abstract:

In view of the secondary pollution caused by the reflection of electromagnetic waves by traditional electromagnetic shielding materials and the problems of heavy, corrosive and poor flexibility of existing absorbing materials, this paper summarizes the application research of the new two-dimensional transition metal carbon/nitrogen compound MXene and its flexible composite materials in the field of absorbing microwave. The effects of intrinsic defects, functional groups, high electrical conductivity and large specific surface area on absorbing properties of MXene were analyzed, and the absorbing mechanism of MXene and its flexible composites was extracted. It is pointed out that MXene and its composites can be used as electromagnetic shielding materials mainly based on absorbing electromagnetic waves by changing the structure and morphology of their compounds, layer-by-layer self-assembly and composite modification, which provides a research direction for the development of new generation of lightweight, ultra-thin, flexible broadband, absorbing electromagnetic shielding materials and their applications in portable wearable electronic devices.

Key words: two-dimensional transition metal carbide, two-dimensional carbide, electromagnetic shielding, wave absorpton, flexibility composite material

中图分类号: 

  • G353.11
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