纺织学报 ›› 2021, Vol. 42 ›› Issue (07): 129-136.doi: 10.13475/j.fzxb.20200703808

• 染整与化学品 • 上一篇    下一篇

家庭洗涤对免烫棉织物性能的影响

郭恒1,2,3, 黄宏博3, 姚金波1,2, 姜会钰1,2, 夏治刚3, 王运利1,2,3()   

  1. 1.武汉纺织大学 化学与化工学院, 湖北 武汉 430200
    2.武汉纺织大学 生物质纤维和生态染整湖北省重点实验室, 湖北 武汉 430200
    3.武汉纺织大学 纺织新材料与先进加工技术国家重点实验室, 湖北 武汉 430200
  • 收稿日期:2020-07-15 修回日期:2021-04-02 出版日期:2021-07-15 发布日期:2021-07-22
  • 通讯作者: 王运利
  • 作者简介:郭恒(1995—),男,硕士生。主要研究方向为纺织品的功能整理。
  • 基金资助:
    国家重点研发计划项目(2017YFB0309200)

Effect of household washing on properties of anti-creasing cotton fabrics

GUO Heng1,2,3, HUANG Hongbo3, YAO Jinbo1,2, JIANG Huiyu1,2, XIA Zhigang3, WANG Yunli1,2,3()   

  1. 1. College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, Hubei 430200, China
    2. Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing & Finishing, Wuhan Textile University, Wuhan, Hubei 430200, China
    3. State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan, Hubei 430200, China
  • Received:2020-07-15 Revised:2021-04-02 Published:2021-07-15 Online:2021-07-22
  • Contact: WANG Yunli

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摘要：

为探究多元羧酸免烫棉织物在日常洗涤过程中免烫性能的保持情况,实验模拟了日常家庭洗涤的环境,对免烫棉织物在不同的洗涤助剂类型、不同洗涤温度、不同洗涤次数下进行洗涤处理。通过测试对比原免烫织物和不同方式洗涤后免烫棉织物的折皱回复角、断裂强力和化学结构表面形貌等,对免烫棉织物的免烫性能在洗涤过程中的保持能力进行分析。结果表明:经重复洗涤,免烫棉织物的断裂强力和折皱回复角都呈现出不同程度的降低;纤维的表面形貌及微观结构都产生了一定的变化;经80 ℃混合溶液重复洗涤处理50次后的断裂强力下降约26%,折皱回复角降低约50%;对免烫棉织物而言,在家庭洗涤过程中,高温复合重复洗涤对其免烫性能的破坏作用较大。

关键词: 家庭洗涤, 免烫棉织物, 免烫性能, 折皱回复角, 断裂强力, 多元羧酸

Abstract:

In order to study the maintenance of anti-creasing property of polycarboxylic acid anti-creasing treated cotton fabrics in the daily washing process,experiments were carried out to simulate the environment of daily household washing, where the anti-creasing cotton fabrics were washed under different detergent types, different wash-temperatures, and different wash-times. The wrinkle recovery angle, breaking strength and surface morphology of the original and post-washing fabrics were tested and compared, and the anti-creasing property of anti-creasing cotton fabrics during the washing process was analyzed.The results of the study show that after repeated washing, the wrinkle recovery angle and breaking strength of anti-creasing cotton fabrics are reduced, and the surface morphology and microstructure of the fibers demonstrate certain changes. After repeated washing of the mixed solution at 80 ℃ for 50 times, the breaking strength is reduced by about 26%, and the wrinkle recovery angle of the sample is reduced by about 50%. For anti-creasing cotton fabrics in the household washing process, high-temperature composite repeated washing show a greater destructive effect on its anti-creasing property.

Key words: household washing, anti-creasing cotton fabric, anti-creasing property, wrinkle recovery angle, breaking strength, polycarboxylic acid

中图分类号: 

  • TS195.2

表1

标准洗涤溶液配方"

洗涤液类别 洗涤液中助剂种类及质量浓度
次氯酸钠洗涤液 次氯酸钠试剂(0.5 mg/L),十二烷基苯磺酸钠(1 g/L)
蛋白酶洗涤液 蛋白酶(0.05 g/L),十二烷基苯磺酸钠(1 g/L)
脂肪酶洗涤液 脂肪酶(0.05 g/L),十二烷基苯磺酸钠(1 g/L)
复合洗涤液 次氯酸钠(0.5 mg/L),蛋白酶(0.05 g/L),脂肪酶(0.05 g/L),十二烷基苯磺酸钠(1 g/L)

表2

BTCA整理前后棉织物的性能"

织物种类 断裂强力/N 折皱回复角/(°)
原棉织物 231.4 65.4
BTCA免烫棉织物 138.7 130.7

图1

不同条件下多次洗涤后免烫棉织物的折皱回复角"

图2

不同条件下多次洗涤后免烫棉织物的断裂强力"

图3

洗涤前后免烫棉织物的表面形貌"

图4

不同温度下3种溶液洗涤处理50次后免烫棉织物的表面形貌(×1 000)"

图5

80 ℃条件下重复洗涤50次前后免烫棉织物的红外光谱"

图6

80 ℃条件下洗涤50次前后免烫棉织物的XRD图谱"

图7

不同方式洗涤处理免烫棉织物的热重曲线"

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