纺织学报 ›› 2022, Vol. 43 ›› Issue (09): 143-148.doi: 10.13475/j.fzxb.20210405906

• 染整与化学品 • 上一篇    下一篇

锦纶织物中氯菊酯含量测试方法比较

程绿竹1, 王宗乾1(), 盛红梅2, 钟辉2, 夏丽萍3   

  1. 1.安徽工程大学 纺织服装学院, 安徽 芜湖 241000
    2.宣城凯欧纺织有限公司, 安徽 宣城 242000
    3.传化智联股份有限公司 化学测试中心, 浙江 杭州 311215
  • 收稿日期:2021-04-21 修回日期:2022-06-20 出版日期:2022-09-15 发布日期:2022-09-26
  • 通讯作者: 王宗乾
  • 作者简介:程绿竹(1996—),女,硕士生。主要研究方向为生态染整技术与功能纺织品。
  • 基金资助:
    安徽省重点研究与开发计划项目(202004a06020055);安徽省高校学科(专业)中青年拔尖人才学术资助项目(gxbjZD2020075);安徽省学术和技术带头人及后备人选学术科研活动资助项目(2020H218);安徽省学术和技术带头人及后备人选学术科研活动资助项目(2021A486);芜湖市科技计划项目(2020yf51)

Comparison of test methods for permethrin content in polyamide fabrics

CHENG Lüzhu1, WANG Zongqian1(), SHENG Hongmei2, ZHONG Hui2, XIA Liping3   

  1. 1. School of Textiles and Garment, Anhui Polytechnic University, Wuhu, Anhui 241000, China
    2. Xuancheng K & O Textile Co., Ltd., Xuancheng, Anhui 242000, China
    3. Chemical Test Center of Transfar Zhilian Co., Ltd., Hangzhou, Zhejiang 311215, China
  • Received:2021-04-21 Revised:2022-06-20 Published:2022-09-15 Online:2022-09-26
  • Contact: WANG Zongqian

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摘要：

为对比研究不同测试方法测试表征纺织品中氯菊酯含量的异同,探寻快速的测试手段,选用氯菊酯驱蚊剂并采用喷雾法对锦纶织物进行整理,分别采用数码显微系统、扫描电子显微镜、傅里叶红外光谱仪、气相色谱仪、X射线光电子能谱仪、紫外-可见-近红外光谱仪对不同质量浓度氯菊酯整理锦纶织物进行测试与表征。结果表明:光学形貌图像、扫描电镜微观形貌图像和红外光谱均可快速表征出经氯菊酯整理后锦纶织物的表面特征,但难以做到精准定量分析;气相色谱、X射线光电子能谱可实现定量分析,但耗时长、成本高;紫外吸收光谱可满足对锦纶织物氯菊酯含量的快速定量分析,测试结果与X射线光电子能谱测试结果有较高拟合度,拟合系数为0.985。

关键词: 氯菊酯, 锦纶织物, 紫外吸收光谱, X射线光电子能谱, 定量分析

Abstract:

In order to study the characteristics of different methods for testing and characterization of permethrin content in textiles, and to explore rapid test methods, permethrin mosquito repellent was used to finish polyamide fabrics by spraying. The polyamide fabrics treated with different concentrations of permethrin were characterized by digital microsystem, scanning electron microscope, Fourier infrared spectrometer, gas chromatography, X-ray photoelectron spectrometer and ultraviolet (UV)/visible/near infrared spectrometer. The results show that the use of optical, scanning electron microscope images and infrared spectroscopy is able to quickly characterize the surface characteristics of polyamide fabrics after permethrin treatment, but it is difficult to achieve accurate quantitative analysis. Gas chromatography and X-ray photoelectron spectroscopy can be used for quantitative analysis, but they are time-consuming with high cost. UV absorption spectrum can meet the rapid quantitative analysis of permethrin content in polyamide fabric, and the test results have a high agreement with the test results of X-ray photoelectron spectroscopy, with a fitting coefficient of 0.985.

Key words: permethrin, polyamide fabric, ultraviolet absorption spectrum, X-ray photoelectron spectroscopy, quantitative analysis

中图分类号: 

  • TS195.5

图1

喷雾法氯菊酯整理锦纶织物示意图"

图2

锦纶织物的光学图像(×500)"

图3

锦纶织物的扫描电镜照片"

图4

锦纶织物的红外光谱曲线"

图5

锦纶织物中氯菊酯峰面积及含量分析"

图6

锦纶织物的X射线光电子能谱图"

图7

氯菊酯整理锦纶织物表面氯原子百分比"

图8

不同质量浓度氯菊酯整理锦纶织物的紫外吸收光谱图"

图9

锦纶中氯原子含量与紫外吸光度值的拟合曲线"

表1

不同测试方法测试氯菊酯含量结果对比"

测试方法 原理 定性 定量 方差/% 单样测试耗时 单次测试所需样品 测试成本
图像法 表面形貌 × ? — 短 极少 高
红外光谱法 红外特征吸收 √ ? — 短 少 适中
气相色谱法 特征吸收和峰面积 √ √ 1.14 长 多 高
X射线光电子能谱法 氯元素特征吸收 √ √ 2.07 长 少 高
紫外光谱法 特征吸收 √ √ 2.25 短 少,对样品无损伤 低
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