纺织学报 ›› 2024, Vol. 45 ›› Issue (12): 215-224.doi: 10.13475/j.fzxb.20240203102

• 综合述评 • 上一篇    下一篇

金属-有机框架应用于纤维/织物功能化改性的研究进展

刘微1(), 田振川2, 沈朝阳3, 梅润4   

  1. 1.应急管理部四川消防研究所, 四川 成都 610036
    2.加泰罗尼亚纳米科学与纳米技术研究所巴塞罗那科学技术研究所, 西班牙 巴塞罗那 E-08193
    3.西南科技大学 环境友好能源材料国家重点实验室, 四川 绵阳 621000
    4.四川轻化工大学 材料科学与工程学院,四川 自贡 643000
  • 收稿日期:2024-02-26 修回日期:2024-09-04 出版日期:2024-12-15 发布日期:2024-12-31
  • 作者简介:刘微(1983—),女,副研究员,博士。主要研究方向为多功能织物制备及改性。E-mail:weiliu2014102@126.com。
  • 基金资助:
    国家自然科学基金青年科学基金项目(51803034);应急管理部消防救援局科技计划项目(2022XFCX22)

Research process in metal-organic frameworks used in functional modification of fiber/fabrics

LIU Wei1(), TIAN Zhenchuan2, SHEN Zhaoyang3, MEI Run4   

  1. 1. Sichuan Fire Science Research Institute of Ministry of Emergency Management, Chengdu, Sichuan 610036, China
    2. Catalan Institute of Nanoscience and Nanotechnology (ICN2), The Barcelona Institute of Science and Technology (BIST), Barcelona E-08193, Spain
    3. State Key Laboratory of Environment-Friendly Energy Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China
    4. College of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong, Sichuan 643000, China
  • Received:2024-02-26 Revised:2024-09-04 Published:2024-12-15 Online:2024-12-31

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摘要：

为进一步提升金属-有机框架结构修饰改性制备功能化纤维/织物的实用性与高效性,根据金属-有机框架结构改性纤维/织物的合成工序及改性技术,分类了现阶段金属-有机框架改性纤维/织物的常用制备方法,详细剖析了现有制备方法存在的优势、缺陷和适用范围,并归纳了此类改性纤维/织物在催化、吸附分离、生物医用、能源存储、和传感检测等领域的应用,探讨了其作用机制与局限。此外,针对目前功能化金属-有机框架结构改性纤维/织物制备及应用领域所面临的挑战指出,此类改性纤维/织物的主要研究方向应聚焦于开发出更加经济化、绿色化、简便化的制备方法,同时结合改善局限上述功能化改性纤维/织物应用关键性问题,如耐候性和分离效率等,才能真正实现功能性金属-有机框架结构改性纤维/织物的工业化生产与规模化应用。

关键词: 金属-有机框架, 纺织材料, 催化, 吸附分离, 生物医用, 传感检测, 能源存储

Abstract:

Significance Metal-organic frameworks (MOFs) have garnered extensive attention owing to their highly structural design, large specific surface area, and abundant porosity, which are now recognized as one of the most promising nanomaterials and are favored in many fields such as catalysis, gas storage and separation, energy storage, antibacterial, sensing, drug delivery, and hydrophobicity. Fiber/fabrics modified with MOFs as a matric material can greatly extend the application of MOFs to overcome MOFs poor processability, and create MOFs fiber/fabric composite materials with predetermined functions. In order to further improve the practicability and efficiency of functionalized fiber/fabric modified with MOFs, research process in the preparation and application of these modified fiber/fabrics is reviewed.

Progress The processing of traditional polymeric fiber materials is to melt-extrude polymer slices and obtain the final product through a series of post-processing processes. However, in the process of combining MOFs nanomaterials with polymer fiber substrates, problems such as nanoparticle agglomeration and embedding are often encountered, which hinters their specific functions. Therefore, various new preparation processes have been developed in recent years to ensure that MOFs are uniformly dispersed on the fiber surface. Based on the synthesis process of fiber/fabric modified with MOFs, these methods can be classified into two categories, i.e., the prefabrication method and in-situ method. The prefabrication method combines the pre-synthesized fiber/fabric with MOFs by blending or post-finishing, while the in-situ method introduces additional nucleation active sites on the surface of inert fiber/fabric and allow MOFs structures to grow on the fiber/fabric surface directly. The microscopic mechanisms and advantages and disadvantages of different preparation methods are analyzed. In addition, the application of new technologies such as sorption-vapor method and fiber-intercepting-particle method in the preparation of fiber/fabric modified with MOFs is briefly described. The aforementioned methods for preparing MOFs fiber/fabric are widely used in various fields. For example, MOFs exhibit catalytic effect similar to that of metal oxidants, which can promote the decomposition of some toxic and harmful compounds. The polarization effect produced by MOFs can be used to adsorb particulate pollutants in the air and heavy metal ions in wastewater. Its high porosity structure and large specific surface make them suitable for drug delivery and the preparation of high-capacity energy storage electrodes. In addition, when MOFs are combined with fiber/fabrics, the contact with the reactants can be increased, thereby improving the reaction efficiency.

Conclusion and Prospect MOFs modified fiber/fabric integrate the advantages of both MOFs and fabrics. The fabric/fiber substrate improves the deficiencies of MOFs stability, mechanical properties and functional durability, and MOFs also endow fiber/fabrics with multifunctionality. In addition, many MOFs can be prepared using low-cost solution methods, offering high cost-effectiveness. At present, however, most of the preparation and application of fiber/fabric modified with MOFs remain in the laboratory, and their industrialization and large-scale promotion are still restricted. At the same time, the preparation method of fiber/fabric modified with MOFs is usually complicated and cumbersome, and the reaction conditions are harsh. The molecular structure of the fabric substrate will be destroyed due to temperature and pressure, causing it to lose its original mechanical properties. The application of fiber/fabric modified with MOFs in many fields is also affected by factors such as preparation process and raw material cost. It will take some time for them to be promoted and applied on a large scale. In addition, there are still some limitations that need to be solved before these fiber/fabric samples can be applied, these including the precise control of pore size of MOFs to improve their separation performance, and improvement of the durability of MOFs modified fiber/fabrics against wear and wash.

Key words: metal-organic framework, textile material, catalyst, absorption and separation, medical application, sensing detection, energy storage

中图分类号: 

  • TQ31

图1

MOFs/聚合物溶液共混静电纺丝三步法示意图"

表2

MOFs常见应用领域及所涉及类型"

应用领域 MOFs类型
催化[42⇓-44] UiO-66-NH2, NH2-MIL-101
吸附分离[46,47,52] ZIF-8, UiO-66-NH2, MIL-53-NH2
生物医用[55,57,58] MOF-199,MOF-74,MOF-5, HKUST-1, MIL-53, ZIF-L, γ-CD-MOFs
能源储存[61⇓-63] Ni-MOF, MIL-53, UiO-66
传感器[32,64,65] MIL-96(Al), Eu-MOF
阻燃[69] ZIF-67
疏水[68] UiO-66
吸声[20] MIL-53(Fe)
[1] YAGHI O M, O'KEEFFE M, OCKWIG N W, et al. Reticular synthesis and the design of new materials[J]. Nature, 2003, 423(6941): 705-714.
[2] YAGHI O M, LI G, LI H. Selective binding and removal of guests in a microporous metal-organic framework[J]. Nature, 1995, 378(6558): 703-706.
[3] LI H, EDDAOUDI M, O'KEEFFE M, et al. Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J]. Nature, 1999, 402(6759): 276-279.
[4] CHUI S S Y, LO S M F, CHARMANT J P H, et al. A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n[J]. Science, 1999, 283(5405): 1148-1150.
[5] TEO W L, ZHOU W, QIAN C, et al. Industrializing metal-organic frameworks: scalable synthetic means and their transformation into functional materials[J]. Materials Today, 2021, 47: 170-186.
[6] MOGHADAM P Z, LI A, WIGGIN S B, et al. Development of a cambridge structural database subset: a collection of metal-organic frameworks for past, present, and future[J]. Chemistry of Materials, 2017, 29(7): 2618-2625.
[7] ISLAMOGLU T, CHEN Z, WASSON M C, et al. Metal-organic frameworks against toxic chemicals[J]. Chemical Reviews, 2020, 120(16): 8130-8160.
[8] LUSTIG W P, MUKHERJEE S, RUDD N D, et al. Metal-organic frameworks: functional luminescent and photonic materials for sensing applications[J]. Chemical Society Reviews, 2017, 46(11): 3242-3285.
[9] DELLA ROCCA J, LIU D, LIN W. Nanoscale metal-organic frameworks for biomedical imaging and drug delivery[J]. Accounts of Chemical Research, 2011, 44(10): 957-968.
[10] TEO W L, LIU J, ZHOU W, et al. Facile preparation of antibacterial MOF-fabric systems for functional protective wearables[J]. SmartMat, 2021, 2(4): 567-578.
[11] YOO D K, WOO H C, JHUNG S H. Ionic salts@metal-organic frameworks: remarkable component to improve performance of fabric filters to remove particulate matters from air[J]. ACS Applied Materials & Interfaces, 2021, 13(19): 23092-23102.
[12] XUE J, WU T, DAI Y, et al. Electrospinning and electrospun nanofibers: methods, materials, and applications[J]. Chemical Reviews, 2019, 119(8): 5298-5415.
[13] LIU Y, LV H, LIU Y, et al. Progresses on electrospun metal-organic frameworks nanofibers and their wastewater treatment applications[J]. Materials Today Chemistry, 2022. DOI: 10.1016/j.mtchem.2022.100974.
[14] DOU Y, ZHANG W, KAISER A. Electrospinning of metal-organic frameworks for energy and environmental applications[J]. Advanced Science, 2020. DOI: 10.1002/advs.201902590.
[15] KAUR H, CHANDEL S S, KARMAKAR A, et al. Mercapto-decorated Zn-based metal-organic framework embedded nanofibrous membrane for oxo-anions treatment in aqueous solution[J]. Chemical Engineering Journal, 2022. DOI: 10.1016/j.cej.2022.136212.
[16] ZHANG C, SHEN L, SHEN J, et al. Anion-sorbent composite separators for high-rate lithium-ion batt-eries[J]. Advanced Materials, 2019. DOI: 10.1002/adma.201808338.
[17] YANG R, ZHENG Y, ZHANG Y, et al. Bipolar metal flexible electrospun fibrous membrane based on metal-organic framework for gradient healing of tendon-to-bone interface regeneration[J]. Advanced Healthcare Materials, 2022. DOI:10.1002/adhm.202200072.
[18] PETERSON G W, LEE D T, BARTON H F, et al. Fibre-based composites from the integration of metal-organic frameworks and polymers[J]. Nature Reviews Materials, 2021, 6(7): 605-621.
[19] NIE X, WU S, MENSAH A, et al. FRET as a novel strategy to enhance the singlet oxygen generation of porphyrinic MOF decorated self-disinfecting fabrics[J]. Chemical Engineering Journal, 2020. DOI: 10.1016/j.cej.2020.125012.
[20] CHEN J, LI H, ZHU H, et al. Fabrication of flexible acoustic metamaterials by growing metal-organic frameworks on fabrics[J]. Cellulose, 2022, 29(1): 355-365.
[21] JHINJER H S, SINGH A, BHATTACHARYA S, et al. Metal-organic frameworks functionalized smart textiles for adsorptive removal of hazardous aromatic pollutants from ambient air[J]. Journal of Hazardous Materials, 2021. DOI: 10.1016/j.jhazmat.2021.125056.
[22] QIU L, WANG L, ZHANG M, et al. A facile strategy for fabrication of HKUST-1 on a flexible polyethylene nonwoven fabric with a high MOF loading[J]. Microporous and Mesoporous Materials, 2020. DOI: 10.1016/j.micromeso.2019.109723.
[23] GAO Q, HU J, LI R, et al. Preparation and characterization of superhydrophobic organic-inorganic hybrid cotton fabrics via γ-radiation-induced graft polymerization[J]. Carbohydrate Polymers, 2016, 149: 308-316.
[24] THINKOHKAEW K, PIROONPAN T, JIRABORVORNPONGSA N, et al. Radiation induced graft polymerization of fluorinated methacrylate onto polypropylene spunbond nonwoven fabric[J]. Surfaces and Interfaces, 2021. DOI: 10.1016/j.surfin.2021.101125.
[25] NIU Z, XIAO C, MO J, et al. Investigating the influence of metal-organic framework loading on the filtration performance of electrospun nanofiber air filters[J]. ACS Applied Materials & Interfaces, 2022, 14(23): 27096-27106.
[26] LIU Y, WANG R, ZHANG T, et al. Zeolitic imidazolate framework-8 (ZIF-8)-coated In2O3 nanofibers as an efficient sensing material for ppb-level NO2 detection[J]. Journal of Colloid and Interface Science, 2019, 541: 249-257.
[27] ZHOU F, WANG Y, DAI L, et al. Anchoring metal organic frameworks on nanofibers via etching-assisted strategy: toward water-in-oil emulsion separation membranes[J]. Separation and Purification Technology, 2022. DOI: 10.1016/j.seppur.2021.119812.
[28] JIA S Y, JI D X, WANG L M, et al. Metal-organic framework membranes: advances, fabrication, and applications[J]. Small Structures, 2022. DOI: 10.1002/sstr.202100222.
[29] BARTON H F. Metal-organic framework-fiber composites enabled by atomic layer deposition of metal oxides for the degradation of chemical warfare agents and simulants[M]. Raleigh: North Carolina State University, 2020: 13-17.
[30] LEE D T, ZHAO J, OLDHAM C J, et al. UiO-66-NH2 metal-organic framework (MOF) nucleation on TiO2, ZnO, and Al2O3 atomic layer deposition-treated polymer fibers: role of metal oxide on MOF growth and catalytic hydrolysis of chemical warfare agent simu-lants[J]. ACS Applied Materials & Interfaces, 2017, 9(51): 44847-44855.
[31] POMERANTZ N L, ANDERSON E E, DUGAN N P, et al. Air, water vapor, and aerosol transport through textiles with surface functional coatings of metal oxides and metal-organic frameworks[J]. ACS Applied Materials & Interfaces, 2019, 11(27): 24683-24690.
[32] YU Y, PAN D K, QIU S Y, et al. Polyphenylene sulfide paper-based sensor modified by Eu-MOF for efficient detection of Fe3+[J]. Reactive & Functional Polymers, 2021. DOI: 10.1016/j.reactfunctpolym.2021.104954.
[33] CHEN Y, LI S, PEI X, et al. A solvent-free hot-pressing method for preparing metal-organic-framework coatings[J]. Angewandte Chemie International Edition, 2016, 55(10): 3419-3423.
[34] MA X, CHAI Y, LI P, et al. Metal-organic framework films and their potential applications in environmental pollution control[J]. Accounts of Chemical Research, 2019, 52(5): 1461-1470.
[35] ZHANG K, HUO Q, ZHOU Y Y, et al. Textiles/metal-organic frameworks composites as flexible air filters for efficient particulate matter removal[J]. ACS Applied Materials & Interfaces, 2019, 11(19): 17368-17374.
[36] TURETSKY D, ALZATE-SÁNCHEZ D M, WASSON M C, et al. Hot press synthesis of MOF/textile composites for nerve agent detoxification[J]. ACS Materials Letters, 2022, 4(8): 1511-1515.
[37] MORGAN S E, WILLIS M L, PETERSON G W, et al. Green MOF-fabrics: benign, scalable sorption-vapor synthesis of catalytic composites to protect against phosphorus-based toxins[J]. ACS Sustainable Chemistry & Engineering, 2022, 10(8): 2699-2707.
[38] LI W, ZHANG Y, YU Z, et al. In situ growth of a stable metal-organic framework (MOF) on flexible fabric via a layer-by-layer strategy for versatile applications[J]. ACS Nano, 2022, 16(9): 14779-14791.
[39] LI A, XIONG J, LIU Y, et al. Fiber-intercepting-particle structured MOF fabrics for simultaneous solar vapor generation and organic pollutant adsorption[J]. Chemical Engineering Journal, 2022. DOI: 10.1016/j.cej.2021.131365.
[40] KIM K, TSAY O G, ATWOOD D A, et al. Destruction and detection of chemical warfare agents[J]. Chemical Reviews, 2011, 111(9): 5345-5403.
[41] KIRLIKOVALI K O, CHEN Z, ISLAMOGLU T, et al. Zirconium-based metal-organic frameworks for the catalytic hydrolysis of organophosphorus nerve agents[J]. ACS Applied Materials & Interfaces, 2020, 12(13): 14702-14720.
[42] LEE D T, DAI Z, PETERSON G W, et al. Highly breathable chemically protective MOF-fiber cata-lysts[J]. Advanced Functional Materials, 2022. DOI: 10.1002/adfm.202108004.
[43] BAI X J, CHEN D, LI Y N, et al. Two-dimensional MOF-derived nanoporous Cu/Cu2O networks as catalytic membrane reactor for the continuous reduction of p-nitrophenol[J]. Journal of Membrane Science, 2019, 582: 30-36.
[44] HASSAN H M A, ALHUMAIMESS M S, KAMEL M M, et al. Electrospinning NH2-MIL-101/PAN nanofiber mats: a promising catalyst with lewis acidic and basic bifunctional sites for organic transformation reactions[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022. DOI: 10.1016/j.colsurfa.2022.128659.
[45] YOO D K, WOO H C, JHUNG S H. Removal of particulate matter with metal-organic framework-incorporated materials[J]. Coordination Chemistry Reviews, 2020. DOI: 10.1016/j.ccr.2020.213477.
[46] ZHANG Y, YUAN S, FENG X, et al. Preparation of nanofibrous metal-organic framework filters for efficient air pollution control[J]. Journal of the American Chemical Society, 2016, 138(18): 5785-5788.
[47] LI Y, YUAN D, GENG Q, et al. MOF-embedded bifunctional composite nanofiber membranes with a tunable hierarchical structure for high-efficiency PM0.3 purification and oil/water separation[J]. ACS Applied Materials & Interfaces, 2021, 13(33): 39831-39843.
[48] ZHAO F, SU C, YANG W, et al. In-situ growth of UiO-66-NH2 onto polyacrylamide-grafted nonwoven fabric for highly efficient Pb (II) removal[J]. Applied Surface Science, 2020. DOI: 10.1016/j.apsusc.2020.146862.
[49] POURNARA A D, MOISIADIS E, GOUMA V, et al. Cotton fabric decorated by a Zr4+ MOF for selective As (V) and Se (IV) removal from aqueous media[J]. Journal of Environmental Chemical Engineering, 2022. DOI: 10.1016/j.jece.2022.107705.
[50] ABDELHAMEED R M, EMAM H E, ROCHA J, et al. Cu-BTC metal-organic framework natural fabric composites for fuel purification[J]. Fuel Processing Technology, 2017, 159: 306-312.
[51] ABDELHAMEED R M, EL-DEIB H R, EL-DARS F M, et al. Applicable strategy for removing liquid fuel nitrogenated contaminants using MIL-53-NH2@natural fabric composites[J]. Industrial & Engineering Chemistry Research, 2018, 57(44): 15054-15065.
[52] EMAM H E, AHMED H B, EL-DEIB H R, et al. Non-invasive route for desulfurization of fuel using infrared-assisted MIL-53 (Al)-NH2 containing fabric [J]. Journal of Colloid and Interface Science, 2019, 556: 193-205.
[53] LÓPEZ-R M, BARRIOS Y, PEREZ L D, et al. Metal-organic framework (MOFs) tethered to cotton fibers display antimicrobial activity against relevant nosocomial bacteria[J]. Inorganica Chimica Acta, 2022. DOI: 10.1016/j.ica.2022.120955.
[54] WYSZOGRODZKA G, MARSZAŁEK B, GIL B, et al. Metal-organic frameworks: mechanisms of antibacterial action and potential applications[J]. Drug Discovery Today, 2016, 21(6): 1009-1018.
[55] EMAM H E, DARWESH O M, ABDELHAMEED R M. In-growth metal organic framework/synthetic hybrids as antimicrobial fabrics and its toxicity[J]. Colloids and Surfaces B: Biointerfaces, 2018, 165: 219-228.
[56] ZHU Y, MAO K, RONG J, et al. Fabrication of titanium incorporation into zeolitic imidazolate framework-L on fabric carrier for visible-light driven photocatalytic antibacterial activity[J]. Optical Materials, 2022. DOI: 10.1016/j.optmat.2022.112085.
[57] NOORIAN S A, HEMMATINEJAD N, NAVARRO J A. BioMOF@cellulose fabric composites for bioactive molecule delivery[J]. Journal of Inorganic Biochemistry, 2019. DOI: 10.1016/j.jinorgbio.2019.110818.
[58] ZHANG B, CHEN H, HU Q, et al. CelluMOFs: Green, facile, and flexible metal-organic frameworks for versatile applications[J]. Advanced Functional Materials, 2021. DOI: 10.1002/adfm.202105395.
[59] AJDARI F B, KOWSARI E, SHAHRAK M N, et al. A review on the field patents and recent developments over the application of metal organic frameworks (MOFs) in supercapacitors[J]. Coordination Chemistry Reviews, 2020. DOI: 10.1016/j.ccr.2020.213441.
[60] CHERUSSERI J, PANDEY D, KUMAR K S, et al. Flexible supercapacitor electrodes using metal-organic frameworks[J]. Nanoscale, 2020, 12(34): 17649-17662.
[61] CHENG C, XU J, GAO W, et al. Preparation of flexible supercapacitor with RGO/Ni-MOF film on Ni-coated polyester fabric[J]. Electrochimica Acta, 2019, 318: 23-31.
[62] BARAKZEHI M, MONTAZER M, SHARIF F, et al. MOF-modified polyester fabric coated with reduced graphene oxide/polypyrrole as electrode for flexible supercapacitors[J]. Electrochimica Acta, 2020. DOI: 10.1016/j.electacta.2020.135743.
[63] QI K, HOU R, ZAMAN S, et al. Construction of metal-organic framework/conductive polymer hybrid for all-solid-state fabric supercapacitor[J]. ACS Applied Materials & Interfaces, 2018, 10(21): 18021-18028.
[64] RAUF S, VIJJAPU M T, ANDREÉS M A, et al. Highly selective metal-organic framework textile humidity sensor[J]. ACS Applied Materials & Interfaces, 2020, 12(26): 29999-30006.
[65] JAYABABU N, KIM D. Co/Zn bimetal organic framework elliptical nanosheets on flexible conductive fabric for energy harvesting and environmental monitoring via triboelectricity[J]. Nano Energy, 2021. DOI: 10.1016/j.nanoen.2021.106355.
[66] LI J, YUAN X, WU Y N, et al. From powder to cloth: facile fabrication of dense MOF-76 (Tb) coating onto natural silk fiber for feasible detection of copper ions[J]. Chemical Engineering Journal, 2018, 350: 637-644.
[67] EVANGELOU D, POURNARA A, TZIASIOU C, et al. Robust Al3+ MOF with selective As (V) sorption and efficient luminescence sensing properties toward Cr (VI)[J]. Inorganic Chemistry, 2022, 61(4): 2017-2030.
[68] DALAPATI R, NANDI S, GOGOI C, et al. Metal-organic framework (MOF) derived recyclable, superhydrophobic composite of cotton fabrics for the facile removal of oil spills[J]. ACS Applied Materials & Interfaces, 2021, 13(7): 8563-8573.
[69] WANG X, LIU C, MENG D, et al. Surface integration of polyelectrolyte and zeolitic imidazolate framework-67 for multifunctional poly (lactic acid) non-woven fabrics[J]. Applied Surface Science, 2021. DOI: 10.1016/j.apsusc.2021.151039.
[70] WANG X, WANG W, WANG S, et al. Self-intumescent polyelectrolyte for flame retardant poly(lactic acid) nonwovens[J]. Journal of Cleaner Production, 2021. DOI: 10.1016/j.jclepro.2020.124497.
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